Abstract: An improved and substantially contamination free electro-immersion finish is provided on an electrically conductive substrate such as a motor vehicle body. An immersion tank holds an aqueous liquid containing an electrophoretically precipitable resin. The substrate to be coated is immersed in the liquid and transported through the tank. The bath liquid in the lower region of the tank is circulated parallel to the direction of transport of the substrate. The bath liquid in the upper region is circulated opposite to the direction of transport of the substrate. The bath liquid may be recirculated by removing the liquid from the tank at the end of the tank where the substrate is removed from the tank. The bath liquid may be purified by filter units prior to being returned to the tank. A separator, such as a cyclone separator, may be disposed in the liquid recirculation conduit ahead of the filtration units.

Abstract: This application discloses water-dispersible binders which are based on modified epoxide/amine adducts and are the reaction products ofA. polyepoxides having an epoxide equivalent greater than 1 and a mean molecular weight M.sub.n of 140 to 5,000 withB. diphenylolalkanoate esters andC. amines.

Abstract: A coating composition, in particular for producing the transparent topcoat of a multilayer coating. The coating composition contains as binders two acrylic polymers, A and B, as well as aliphatic and/or cycloaliphatic polyisocyanates. Acrylic polymer A has a molecular weight of 800 to 4,000, a hydroxyl number of 80 to 180 and a glass transition temperature of below -10.degree. C. Acrylic polymer B has a molecular weight of 3,000 to 10,000, a hydroxyl number of 40 to 120 and a glass transition temperature of -10.degree. C. to +10.degree. C. Whereas in acrylic polymer A the proportion of acrylic acid esters predominates, polymer B contains methacrylic acid esters as predominant monomer components.

Abstract: The invention relates to a heat-hardenable binder mixture which comprises(A) an organic nonacidic resin having a hydroxyl group content of at least 0.2 equivalent in 100 g of resin and having a molecular weight of at least 850, and(B) a crosslinking agent based on an organic compound which contains at least 2 carbalkoxymethyl ester groups per molecule.

Abstract: A water-dilutable coating agent for preparing the base layer of a multilayer coating. The coating agent contains pigments and optionally flow-control agents, thixotroping agents, fillers, organic solvents and other customary auxiliaries.

Abstract: The invention relates to binders for cathodically depositable coating compositions for the electrocoating lacquering process using cationic synthetic resins, which binders have been obtained by polymerizing (A) 5 to 95% by weight of ethylenically unsaturated polymerizable monomers in the presence of (B) 95 to 5% by weight of a cationic synthetic resin in an aqueous phase, the total amount of the components (A) and (B) being 100%. Esters of acrylic acid and/or methacrylic acid are preferable for use as component (A). The invention also relates to a process for preparing the binders and to their use for cathodically depositable electrocoating lacquers.

Abstract: The invention relates to water-dispersible binders for cationic electrocoating finishes, which are obtained by reaction of(A) epoxy resins containing low molecular weight aromatic groups and having an epoxide equivalent weight of less than 375 with(B) aliphatic and/or alicyclic polyfunctional alcohols or carboxylic acids having a number average molecular weight of less than 350, further reaction of the product of (A) and (B) with(C) a polyfunctional alcohol having a molecular weight of more than 350, addition at the epoxide groups taking place so that the reaction products of (A) and (B) contain an amount of aromatic groups of from 10 to 45% by weight, calculated as phenylene groups, and further modification of the resulting intermediate with(D) primary and/or secondary amines or ammonium salts in order to achieve the required water-dispersibility.

Abstract: The invention relates to a synthetic resin based on an acrylate copolymer containing epoxide groups and having a number average molecular weight of 1,000 to 30,000. The acrylate copolymer comprises (a) 20 to 90% by weight of an alkyl acrylate having 1 to 18 carbon atoms in the alkyl radical and/or a methacrylate having 1 to 20 carbon atoms in the alkyl radical, (b) 5 to 40% by weight of a hydroxyalkyl acrylate and/or methacrylate and (c) 5 to 40% by weight of glycidyl acrylate and/or methacrylate and/or one other olefinically unsaturated, polymerizable compound carrying an epoxide group, the total amount of components a, b and c being 100%. The hydroxyl groups of the acrylate copolymer have been reacted before or after the copolymerization was carried out at least partially with a partially blocked diisocyanate and/or polyisocyanate.

Abstract: The invention relates to a self-crosslinking heat-curable binder, in particular for electrocoating finishes, based on an organic synthetic resin which contains primary and/or secondary hydroxyl groups, esterified carboxyl groups and quaternary ammonium groups and can be diluted with water as a result of partial or complete neutralization with acids. The esterified carboxyl groups are activated in the alcohol component by a substituent which has a negative inductive effect.

Abstract: The invention relates to a synthetic resin based on an acrylate copolymer containing epoxide groups and having a number average molecular weight of 1,000 to 30,000. The acrylate copolymer comprises (a) 20 to 90% by weight of an alkyl acrylate having 1 to 18 carbon atoms in the alkyl radical and/or a methacrylate having 1 to 20 carbon atoms in the alkyl radical, (b) 5 to 40% by weight of a hydroxyalkyl acrylate and/or methacrylate and (c) 5 to 40% by weight of glycidyl acrylate and/or methacrylate and/or one other olefinically unsaturated, polymerizable compound carrying an epoxide group, the total amount of components a, b and c being 100%. The hydroxyl groups of the acrylate copolymer have been reacted before or after the copolymerization was carried out at least partially with a partially blocked diisocyanate and/or polyisocyanate.

Abstract: Plastisols useful for automobile undercoatings, anti-noise compositions, adhesives, sealing compositions and coatings for untreated, pretreated, phosphated, primed and prelacquered metal bases are improved by the addition of coke dust and coal dust fillers. The carbon dust fillers have a particle size of about 0.5 to 1000 microns and they are used in a concentration of about 9 to 90% by weight based on the total weight of plastisol and carbon dust. The carbon dust filled plastisols have a specific gravity of about 1.1 to 1.3.

Abstract: The heat-hardenable binder mixture based on organic resins comprises an organic resin having primary and/or secondary and, if appropriate, also additional tertiary amino groups and a cross-linking agent based on an organic compound containing at least 2 carbalkoxymethyl groups. The binder mixture can additionally contain pigments, fillers, cross-linking catalysts, corrosion inhibitors and further finish auxiliaries. The binder mixture is used in a process for preparing coatings by applying a coating agent in the form of a film to a substrate and subsequently hardening the film by baking.

Abstract: A process for coating an electrically conductive substrate, connected as the cathode, with a cationic coating agent from an electrocoating bath and subsequently hardening the coating, is characterized in that an aqueous dispersion made from:A. cationic, synthetic resins which have been protonated with acids, contain basic groups and are in a dissolved or dispersed form andB. dispersed, finely divided, ionic plasticsis used as the cationic coating agent.

Abstract: The invention relates to aqueous dispersions based on a polyurethane synthetic resin which has been obtained by reacting a hydroxyl-containing unsaturated polyester with a diisocyanate and reacting the product with a dihydroxycarboxylic acid, dihydroxysulfonic acid, diaminocarboxylic acid or diaminosulfonic acid, neutralizing the intermediate product with a tertiary amine and transferring it into an aqueous phase, and then reacting the terminal isocyanate groups with a primary and/or secondary diamine, as a chain-lengthening agent. The dispersions contain hydrolyzed shellac as second binder component. They produce coatings having excellent solvent resistance and excellent adhesion, even to difficult substrates.

Abstract: The invention relates to a self-crosslinking heatcurable binder, in particular for electropaints, which is based on an organic synthetic resin which contains primary and/or secondary and, if desired, also tertiary amino groups and esterified carboxyl groups and is water-dilutable due to partial or complete neutralization with acids. The esterified carboxyl groups are activated in the alcohol component by a substituent which induces a negative inductive effect.

Abstract: A water-dilutable coating agent for preparing the base layer of a multilayer coating. The coating agent contains pigments and optionally flow-control agents, thixotroping agents, fillers, organic solvents and other customary auxiliaries.

Abstract: Dispersions of finely divided synthetic resins in plasticizers, optionally with pigments, fillers and further auxiliaries, contain 0.01 to 30% by weight, relative to the total weight of synthetic resin and plasticizer, of an isocyanate-free reaction product of a monoamine, if appropriate combined with a polyamine compound, with a monoisocyanate and/or polyisocyanate or a polyamine compound with a monoisocyanate, if appropriate combined with a polyisocyanate.

Abstract: An aqueous dispersion based on an acid-protonized reaction product from(a) Mannich bases free from epoxide groups, from(a.sub.1) condensed phenols free from ether groups with at least two aromatic rings and with at least two phenolic hydroxyl groups and/or(a.sub.2) condensed phenols, containing ether groups, with at least two aromatic rings and at least one phenolic hydroxyl group(a.sub.3) secondary amines with at least one hydroxyalkyl group, possible in a mixture with(a.sub.4) secondary dialkylamines or dialkoxyalkylamines without free hydroxyl groups,(a.sub.5) formaldehyde or compounds splitting off formaldehyde, with(b) epoxide resins, aliphatic hydroxyl groups from (a) and/or (b) being converted at least in part into urethane groups possibly by reaction with partly blocked isocyanates,containing furthermore fine-particulates non-ionic plastics in dispersed form. The dispersion and/or the fine-particulate plastics furthermore may contain pigments and/or fillers.

Abstract: A process and apparatus for the preparation of aqueous synthetic resin dispersions by using water to precipitate the synthetic resins from their solutions in water-miscible solvents. The solutions may contain pigments, extenders, and additives. The precipitated solids are separated off and dispersed uniformly in an aqueous medium. The precipitation of the synthetic resins is carried out in the presence of inert grinding bodies.

Abstract: The invention is related to unsaturated homo- and/or copolymerizable linear polyesters which are prepared from diols and at least one unsaturated dicarboxylic acid or its derivatives capable of forming esters. The polyesters contain as component (A) a diol with end-position hydroxyl groups and an average molecular weight of 700 to 1200; as component (B) one or more unsaturated dicarboxylic acids; and as component (C) a linear diol with 2 to 6 carbon atoms. The equivalent ratio of A:B is from about 0.8:1 to 1.2:1 and the equivalent ratio of C:(A+B) is from about 0.5:1 to 1:1.