Patents Assigned to BASF Lacke & Farben AG
  • Patent number: 5780541
    Abstract: The invention relates to nonaqueous paints which comprise(A) a hydroxyl group-containing synthetic resin or a mixture of hydroxyl group-containing synthetic resins(B) an amino resin or a mixture of amino resins(C) a blocked polyisocyanate or a mixture of blocked polyisocyanates, and(D) a pigment or a mixture of pigments, and are characterized in that component (C) contains both isocyanate groups blocked with a blocking agent (I) and isocyanate groups blocked with a blocking agent (II), in which contextthe blocking agent (I) is a dialkyl malonate or a mixture of dialkyl malonates,the blocking agent (II) is a blocking agent which is different from (I) and contains active methylene groups, or is an oxime, or is a mixture of these blocking agents, andthe ratio of equivalents between the isocyanate groups blocked with (I) and the isocyanate groups blocked with (II) is between 1.0:1.0 and 9.0:1.0.
    Type: Grant
    Filed: February 20, 1996
    Date of Patent: July 14, 1998
    Assignee: BASF Lacke + Farben, AG
    Inventors: Peter Mayenfels, Georg Wigger, Fritz Bartol, Ulrike Rockrath, Ulrich Poth
  • Patent number: 5767188
    Abstract: Water-based primer composition made up of (A) a water-compatibilised modified polyolefin type resin, which is a modified polyolefin resin modified with an .alpha.,.beta.-unsaturated carboxylic acid, of a saponification value of 10-60 mg KOH/g, a number average molecular mass of 4000-30,000 and a degree of chlorination of 0-30 wt %, water-compatibilised by means of an amine compound, and if necessary additionally by a surfactant, (B) a water-compatibilised acrylic resin of a glass transition temperature of -50.degree. to 20.degree. C., and (C) a water-compatibilised polyurethane resin of a break elongation of 200-600%, and if necessary an additional curing agent, in which the contents of the different components are (A) 25-70 wt %, the sum of (B) and (C) 30-75 wt %, and the ratio by weight of (B)/(C) 100/0-50/50.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: June 16, 1998
    Assignee: BASF Lacke +Farben, AG
    Inventors: Joshimasa Kamikuri, Ulrich Hermann, Kazuyoshi Furuuchi, Toshihiko Nakamishi
  • Patent number: 5763546
    Abstract: The invention relates to copolymers containing on average 1.25 to 30 functional groups per molecule and a number average molecular weight of 1500 to 6000, which copolymers can be prepared by free-radical solution polymerization at 130.degree. to 200.degree. C. from 5 to 25% by weight of vinyl ester, 10 to 50% by weight of vinyl aromatic, 10 to 40% by weight of functional, monomers and, if desired further monomers, in which the vinyl ester is initially introduced and the remaining monomers are metered in for all monomers over a monomer addition period which is of the same length in the following manner: The amount of acrylate monomers added per unit of time remains constant. The amount of vinyl aromatic added over the first third of the monomer addition period is 15 to 30% by weight, the amount added over the second third is 25 to 40% by weight, and the amount added over the last third is 35 to 60% by weight, each relative to the total amount of vinyl aromatic.
    Type: Grant
    Filed: August 7, 1992
    Date of Patent: June 9, 1998
    Assignee: BASF Lacke+Farben, AG
    Inventors: Werner-Alfons Jung, Peter Hoffmann
  • Patent number: 5763004
    Abstract: Also disclosed is an appliance for introducing sealing compound into lug caps, the appliance containing a turntable for accommodating the cap, and an injection unit, the injection unit containing a nozzle block, which has annularly arranged injection nozzles, and a delivery device for the sealing compound, the turntable and the nozzle block being arranged so as to be centered and the nozzle block being rotatable in the same direction as the turntable.The invention also relates to a process for introducing sealing compound into lug caps and to the use of the appliance for injecting sealing compound into lug caps.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: June 9, 1998
    Assignee: BASF Lacke + Farben, AG
    Inventor: Erwin Hammen
  • Patent number: 5759372
    Abstract: The invention relates to aqueous electrodeposition coating materials comprising cathodically depositable synthetic resins and further comprising a reaction product (A) and a polymerization initiator (B) which forms free radicals, wherein the cathodically depositable synthetic resin is different from the reaction product (A), and the reaction product (A) is prepared by reacting(a) a polyisocyanate or a mixture of polyisocyanates with(b) an organic compound which contains both at least one ethylenically unsaturated double bond and at least one active hydrogen atom per molecule, or a mixture of such organic compounds, and(c) an organic compound which contains both at least one active hydrogen atom and at least one tertiary amino group and/or at least one ketimine and/or at least one aldimine group per molecule, or a mixture of such organic compounds, and if desired(d) an organic compound which is different from (b) and (c) and contains at least one active hydrogen atom per molecule, or a mixture of such organic
    Type: Grant
    Filed: December 19, 1995
    Date of Patent: June 2, 1998
    Assignee: BASF Lacke + Farben AG
    Inventors: Hardy Reuter, Gunther Ott, Walter Jouck
  • Patent number: 5759630
    Abstract: The present invention relates to a process for the production of textured coatings on plastics surfaces using coating compositions based on hydroxyl group-containing binders and polyisocyanates, and using pulverulent texturing agents.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: June 2, 1998
    Assignee: BASF Lacke + Farben, AG
    Inventors: Annegret Vosskuhl, Bernhard Rubbert
  • Patent number: 5759631
    Abstract: Coating composition comprising(A) at least one hydroxyl group-containing polyacrylate resin obtained by polymerizing(a) from 5 to 80% by weight of a cycloaliphatic ester of methacrylic acid and/or acrylic acid, or a mixture of such monomers,(b) from 10 to 50% by weight of a hydroxyl group-containing alkyl ester of methacrylic acid and/or acrylic acid, or mixtures of such monomers,(c) from 0 to 25% by weight of a hydroxyl group-containing, ethylenically unsaturated monomer, different from (a) and (b), or a mixture of such monomers,(d) from 5 to 80% by weight of an aliphatic ester of methacrylic and/or acrylic acid, different from (a)-(c), or a mixture of such monomers,(e) from 0 to 40% by weight of an aromatic vinyl hydrocarbon, different from (a)-(d), or a mixture of such monomers, and(f) from 0 to 40% by weight of an additional ethylenically unsaturated monomer, different from (a)-(e), or a mixture of such monomers,and(B) at least one crosslinking agent.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: June 2, 1998
    Assignee: BASF Lacke+Farben AG
    Inventors: Heinz-Peter Rink, Michael Brunnemann
  • Patent number: 5753726
    Abstract: Epoxy resins for preparing water-dispersible binders for cathodic electrodeposition coating materials, the epoxy resin being preparable by reacting a) polyepoxides having at least one glycidyl group per molecule b) and, optionally, up to 60% by weight, based on the overall epoxy resin reaction product, of aliphatic and/or alicyclic hydroxy compounds having preferably two or on average less than two hydroxyl groups per molecule and a molecular weight of less than 9000 g/mol, c) in the presence of a catalyst consisting of neutral metal salts, such as alkali metal salts and alkaline earth metal salts, zinc salts and nickel salts of tetrafluoroboric, tetrachloroboric, hexafluoro- antimonic,hexachloroantimonic,hexafluorophosphoric, perchlorate and periodic acid, and d) adding a deactivating agent which prevents the epoxy groups reacting further or effectively reduces the rate of such reaction as soon as the phenolic hydroxyl groups have already substantially reacted and at least 0.
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: May 19, 1998
    Assignee: BASF Lacke + Farben, AG
    Inventors: Hardy Reuter, Walter Jouck, Gunther Ott
  • Patent number: 5739214
    Abstract: The present invention relates to radiation-curable coating compositions comprising(A) from 20 to 50% by weight of at least one prepolymer containing at least two ethylenically unsaturated double bonds,(B) from 20 to 60% by weight of at least one cationically curing epoxy resin,(C) from 10 to 30% by weight of at least one ketonic and/or ketone-formaldehyde resin,(D) from 5 to 40% by weight of at least one reactive diluent, and(E) from 5 to 10% by weight of a mixture of at least one cationic polymerization initiator and at least one free-radical polymerization initiator,the sum of the proportions by weight of components A to E being in each case 100% by weight.
    Type: Grant
    Filed: June 21, 1996
    Date of Patent: April 14, 1998
    Assignee: BASF Lacke + Farben, AG
    Inventor: Stephan Schunck
  • Patent number: 5736193
    Abstract: The present invention relates to solderable wire-coating compositions based on hydroxyl group-containing polyesters, blocked polyisocyanates, organic solvents and catalysts, which are characterized in that they containA) from 7 to 25% by weight of hydroxyl group-containing polyesters,B) from 55 to 70% by weight of a fully blocked aromatic diisocyanate adduct or of a plurality of fully blocked aromatic diisocyanate adducts,C) from 0.1 to 3% by weight of catalysts,D) from 1 to 8% by weight of a polyol or of a plurality of polyols, andE) from 1 to 36.9% by weight of an alkylene carbonate or of a plurality of alkylene carbonates,the total weight of the wire-coating compositions in each case being 100% by weight.The present invention also relates to a process for the continuous coating of wires using the solderable wire-coating compositions described.
    Type: Grant
    Filed: September 5, 1995
    Date of Patent: April 7, 1998
    Assignee: BASF Lacke +Farben, AG
    Inventors: Michael Schink, Klaus Wilhelm Lienert, Joachim Runge, Silvia Hentschel
  • Patent number: 5728283
    Abstract: The invention relates to aqueous eletrocoating ?sic! compositions containing cathodically depositable synthetic resins, which electrocoating compositions are characterized in that they contain polymer microparticles which have a particle size of 0.01 to 10 .mu.m and are preparable by reacting(a) a polyisocyanate or a mixture of polyisocyanates with(b) an organic compound containing not only at least one ethylenically unsaturated double bond but also at least one active hydrogen atom per molecule or a mixture of such organic compounds and(c) an organic compound containing not only at least one active hydrogen atom but also at least one tertiary amino group and/or at least one ketimine group and/or at least one aldimine group per molecule or a mixture of such organic compounds and, if desired,(d) an organic compound other than (b) and (c) containing at least one active hydrogen atom per molecule or a mixture of such organic compounds.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: March 17, 1998
    Assignee: BASF Lacke + Farben, AG
    Inventors: Hardy Reuter, Gunther Ott, Walter Jouck
  • Patent number: 5716678
    Abstract: A process is disclosed for producing a double-layered covering lacquer by using a transparent covering lacquer containing a hydroxyl group-containing polyacrylate resin produced by polymerizing (a) 10 to 51% by weight 4-hydroxy-n-butylacrylate or 4-hydroxy-n-butylmethacrylate or a mixture of 4-hydroxy-n-butylacrylate and 4-hydroxy-n-butylmethacrylate; (b) 0 to 36% by weight of a hydroxyl group-containing ester of acrylic acid different from (a) or a hydroxyl group-containing ester of methacrylic acid or a mixture of such monomers; (c) 28 to 85% by weight of an aliphatic or cycloaliphatic ester of methacrylic acid different from (a) and (b) with at least 4 C atoms in the alcohol residue or a mixture of such monomers; (d) 0 to 3% by weight of an ethylenically unsaturated carboxylic acid or a mixture of ethylenically unsaturated carboxylic acids and (e) 0 to 20% by weight of an ethylenically unsaturated monomer different from (a), (b), (c) and (d) or a mixture of such monomers, into a polyacrylate resin with a h
    Type: Grant
    Filed: November 17, 1995
    Date of Patent: February 10, 1998
    Assignee: BASF Lacke + Farben, AG
    Inventors: Ulrike Rockrath, Georg Wigger, Fritz Bartol, Peter Betz, Wilfried Stubbe, Angelika Bartelt
  • Patent number: 5714264
    Abstract: The present invention relates to an aqueous powder coating dispersion based on epoxy resins and phenolic curing agents or carboxyl-containing polyesters for the coating of packaging containers, which dispersion consists of a solid, pulverulent component I and an aqueous component II, component I being a powder coating which containsA) at least one epoxy resin having an epoxide equivalent weight of from 300 to 5500 andB) at least one curing agent having more than one phenolic hydroxyl group per molecule and a hydroxyl equivalent weight, based on phenolic OH groups, of from 100 to 500, preferably from 200 to 300, orC) at least one polyester having an acid number of from 25 to 120 mg of KOH/g and an OH number >10 mg of KOH/g, andD) at least one epoxy resin having an epoxide equivalent weight of from 400 to 3000, and component II being the aqueous component of the dispersion which contains at least one nonionic or anionic thickener.
    Type: Grant
    Filed: October 18, 1995
    Date of Patent: February 3, 1998
    Assignee: BASF Lacke & Farben, AG
    Inventors: Lawrence Sacharski, Peter D. Clark, Joachim Woltering
  • Patent number: 5709909
    Abstract: Disclosed is a filler paste comprising polyurethane resin, chlorinated polyolefin, filler and/or extender, and organic solvents. The filler paste may also include physically drying binders, pigments, and/or rheological additives. Also disclosed is a basecoat containing the filler paste. The basecoat containing the filler paste may be applied directly to polyolefin substrates. After a flash-off period, a basecoat that does not contain the filler paste may be applied on top of the first basecoat layer. After a flash-off period for the second basecoat layer, a clearcoat may be applied and subsequently the applied layers may be cured together, with heating.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: January 20, 1998
    Assignee: BASF Lacke & Farben, AG
    Inventors: Frank Leibfarth, Hans Josef Oslowski, Doris Maria Bohm, Andreas Gobel
  • Patent number: 5693205
    Abstract: The invention relates to a cathodic electro-dipping process, which comprises a procedure in which the electro-dipping primer used contains an adduct containing urethane groups which is obtainable by reacting with one another a polyester-polyol or polyether-polyol, a polyisocyanate and a compound which contains a hydroxyl group and at least one ketimine group in the molecule.
    Type: Grant
    Filed: January 24, 1992
    Date of Patent: December 2, 1997
    Assignee: BASF Lacke + Farben, AG
    Inventors: David J. Santure, Gunther Ott, Udo Reiter, Ulrich Heimann, Hans-Josef Oslowski
  • Patent number: 5691419
    Abstract: A coating agent comprises a binding agentcontaining at least one acrylate copolymer (A) with carboxyl groups and/or at least one acrylate copolymer (B) with epoxide groups, the acrylate copolymers (A) and (B) being obtained by solution polymerization using less than 5% by weight based on the total weight of monomers of one or more polysiloxane macromonomers a.sub.1 having a number-average molecular weight of 1000 to 40,000 and on average 0.5 to 2.5 ethylenically unsaturated double bonds per molecule; and one or more epoxy resins.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: November 25, 1997
    Assignee: BASF Lacke + Farben, AG
    Inventors: Stephan Engelke, Michael Brunnemann, Olaf Rotter, Andreas Holst
  • Patent number: 5686531
    Abstract: A coating agent comprises a binding agent containing at least one acrylate copolymer (A) with carboxyl groups and/or at least one acrylate copolymer (B) with epoxide groups, the acrylate copolymers (A) and (B) being obtained by solution polymerization using less than 5% by weight based on the total weight of monomers of one or more polysiloxane macromonomers a.sub.1 having a number-average molecular weight of 1000 to 40,000 and on average 0.5 to 2.5 ethylenically unsaturated double bonds per molecule; one or more addition and/or condensation resins with carboxyl groups; and one or more epoxy resins.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: November 11, 1997
    Assignee: BASF Lacke + Farben, AG
    Inventors: Stephan Engelke, Michael Brunnemann, Olaf Rotter, Andreas Holst
  • Patent number: 5683745
    Abstract: The invention relates to a process for producing a multicoat refinish, in which a metallic basecoat is sprayed on the prepared damage site and the adjacent regions of the old finish, so that it is opaque (hiding) in the region of the damage site and gradually runs out in the region of the old finish. Finally, a clearcoat is applied to the basecoat and, if desired, to the adjacent regions of the old finish.The process is characterized in that1. during the application of the basecoat composition to the adjacent regions of the old finish, the spraygun is inclined diagonally to the damage site, and2. during the application of the basecoat composition, a normal or only slightly reduced (3.0-4.5 bar) spraygun pressure is used.
    Type: Grant
    Filed: March 6, 1996
    Date of Patent: November 4, 1997
    Assignee: BASF Lacke + Farben, AG
    Inventors: Hermann Liedtke, Werner Kraus, Bernd Mayer
  • Patent number: 5684078
    Abstract: The present invention relates to water-dilutable emulsion polymers prepared by multistep emulsion polymerization. To this end,(a1) 0.5 to 5.0% by weight of ethylenically unsaturated monomers containing carboxyl groups, and(a2) from 0.5 to 2.5% by weight of olefinically unsaturated carboxamides,where a total of from 1.0 to 8.0% by weight of hydrophilic ionic and hydrophilic nonionic olefinically unsaturated monomers are employed, and(b) from 92.0 to 99.0% by weight of further ethylenically unsaturated monomers containing no further functional groups,are polymerized in the first step of the emulsion polymerization, where the total amount of monomers in the first step is 100% by weight, and exclusively olefinically unsaturated monomers containing no further functional groups are polymerized in the second step of the emulsion polymerization, and the weight ratio between the monomers polymerized in the first step and the monomers polymerized in the second step is from 30-80%:20-70% by weight.
    Type: Grant
    Filed: March 28, 1995
    Date of Patent: November 4, 1997
    Assignee: BASF Lacke +Farben, AG
    Inventors: Arthur Pfaffenschlager, Antonio Manoel Marques Pereira, Wilson Marques Canabrava
  • Patent number: 5670600
    Abstract: The present invention relates to an aqueous two-component polyurethane coating composition comprisingA) a water-dilutable polyacrylate resin (A) having an OH number of from 40 to 200 mg of KOH/g, an acid number of from 20 to 100 mg of KOH/g and a glass transition temperature of from -40.degree. C. to +60.degree. C., andB) a polyisocyanate component as crosslinking agent,characterized in that the water-dilutable acrylate resin is obtainable by solution polymerization, in the presence of a polymerization initiator, of at least one monomer which is free of carboxyl groups, at least one monomer which contains hydroxyl groups, at least one vinyl ester of .alpha.-branched monocarboxylic acids having 5 to 18 carbon atoms per molecule and/or at least one reaction product of acrylic acid and/or methacrylic acid with the glycidyl ester of .alpha.
    Type: Grant
    Filed: December 20, 1995
    Date of Patent: September 23, 1997
    Assignee: BASF Lacke + Farben, AG
    Inventors: Egbert Nienhaus, Bernd Mayer, Uwe Meisenburg