Abstract: The end group content of polyamide in the solid state may be reduced by treating the polyamide with gas-phase acid, anhydride, or amine. Stain- or dye-resistant polyamide fibers can be made by reducing the number of amino end groups. Reduction in the number of carboxylic end groups reduces the rate of regeneration of starting monomers during extrusion.
Type:
Application
Filed:
December 18, 2000
Publication date:
February 14, 2002
Applicant:
BASF Corporation
Inventors:
Otto M. Ilg, Harry Y. Hu, Scott R. Brank
Abstract: Use of ascorbic acid derivatives of the formula I
where the variables independently of one another have the following meanings:
R1 is hydrogen, C1-C20-acyl, C1-Cl2-alkoxycarbonyl, C1-C12-alkyl,
R2 is hydrogen, C1-C20-acyl, C1-Cl2-alkoxycarbonyl, C1-C12-alkyl,
where R1 and R2, together with the oxygen atoms to which they are bonded and the carbon atoms bonded to the oxygen atoms, can form an unsubstituted or substituted heterocycle,
R3 is hydrogen or a cation selected from the group consisting of NH4+, alkali metal and alkaline earth metal cations,
R4 is C1-C12-alkoxycarbonyl,
for cosmetic and pharmaceutical preparations is described.
Type:
Grant
Filed:
November 5, 1998
Date of Patent:
February 12, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Harald Streicher, Bernd Ostersehlt, Horst Westenfelder
Abstract: A molding material as based on from 60 to 98% by weight of a hard matrix A comprising polymerized or copolymerized units of at least one vinylaromatic monomer or at least one vinylaromatic monomer and at least one polar comonomer and from 2 to 40% by weight, the percentages in each case being based on the molding material comprising A and B, of a soft phase B formed from a hydrogenated or unhydrogenated block copolymer prepared by anionic polymerization and comprising a vinylaromatic monomer V and a diene D, having at least one random or quasi-random block (V/D) of vinylaromatic monomer and diene and containing from 10 to 80% by weight, based on the soft phase B, of occlusions of matrix material (a) formed during the polymerization of the hard matrix A in the presence of the block rubber, and said molding material is used for the production of films, sheets or moldings.
Type:
Grant
Filed:
December 23, 1997
Date of Patent:
February 12, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Loth, Konrad Knoll, Hermann Gausepohl
Abstract: The process comprises reacting 2-, 3- or 4-pentenenitrile or mixtures thereof with carbon monoxide and a hydroxyl compound in the presence of a catalyst system comprising (i) a palladium(II) compound, (ii) a bidentate diphosphine ligand and (iii) an anion source. Novel catalyst systems containing diphosphine ligands of the bis(phosphinomethyl)amine type are also described.
Type:
Grant
Filed:
February 26, 2001
Date of Patent:
February 12, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael Slany, Martin Schäfer, Michael Schulz
Abstract: Cationic azo dyes of the general formula I
where R1, R2, R3, A1, A2, B1, B2, An⊖, n and K have the meaning given in the specification are prepared and used for the dyeing and printing of natural or synthetic substrates and mixtures thereof.
Abstract: The &bgr;-hydroxy carbamate, ethylenically unsaturated monomer of the invention can be polymerized as a homopolymer or copolymerized with other monomers. The polymerization can be carried out in an aqueous medium. The &bgr;-hydroxy carbamate monomer is polymerized to form water-soluble homopolymers or, if polymerized as a mixture with one or more comonomers, copolymers that are soluble, emulsifiable, or dispersible in water. The &bgr;-hydroxy carbamate monomer can be used as a replacement monomer for acrylamide.
Abstract: Disclosed is a cis-bridged metal complex of the formula (I)
where R5 is an electron-withdrawing radical, and catalyst systems based on these complexes for copolymerizing carbon monoxide and olefinically unsaturated compounds.
Type:
Grant
Filed:
September 18, 2000
Date of Patent:
February 12, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Joachim Queisser, Michael Slany, Ansgar Schäfer, Michael Schulz
Abstract: A process for the coproduction of 6-aminocapronitrile and hexamethylenediamine starting from adiponitrile by
a) hydrogenating adiponitrile in the presence of a catalyst comprising an element of the eighth transition group as catalytically active component, to obtain a mixture comprising 6-aminocapronitrile, hexamethylenediamine, adiponitrile and high boilers,
b) distillatively removing hexamethylenediamine from the mixture comprising 6-aminocapronitrile, hexamethylenediamine, adiponitrile and high boilers, and either
c1) distillatively removing 6-aminocapronitrile, and then
d1) distillatively removing adiponitrile, or
c2) simultaneously distillatively removing 6-aminocapronitrile and adiponitrile into separate fractions is characterized by base of column temperatures below 185° C. in steps d1) or c2).
Type:
Grant
Filed:
January 2, 2001
Date of Patent:
February 12, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Hermann Luyken, Frank Ohlbach, Andreas Ansmann, Peter Bassler, Rolf Fischer, Johann-Peter Melder, Martin Merger, Alwin Rehfinger, Guido Voit, Günther Achhammer
Abstract: In a process for preparing C2-oxygenates by reaction of CO and H2 over a rhodium-containing supported catalyst, the catalyst comprises, based on the total weight,
from 0.01 to 10% by weight of rhodium,
from 0.001 to 10% by weight of zirconium,
from 0.01 to 5% by weight of iridium,
from 0.01 to 10% by weight of at least one metal selected from among copper, cobalt, nickel, manganese, iron, ruthenium and molybdenum,
from 0.01 to 10% by weight of at least one alkali metal or alkaline earth metal selected from among lithium, sodium, potassium, rubidium, magnesium and calcium,
on an inert support.
Abstract: A polyester polyol composition comprising a phthalic anhydride-initiated polyester polyol, a C4-C6 hydrocarbon blowing agent, and an alkylene oxide modified silicone glycol compatibilizing agent having an HLB of from about 5 to about 8 is disclosed. The blowing agent is soluble in the polyol composition, thereby reducing the risks associated with such blowing agents in processes for making rigid polymer foam articles and providing rigid foams having good dimensional stability and improved insulation properties. An alkylene oxide and isocyanate modified silicone glycol compatibilizing agent is also disclosed.
Type:
Grant
Filed:
August 7, 2001
Date of Patent:
February 12, 2002
Assignee:
BASF Corporation
Inventors:
David D. Peters, Robert E. Riley, Jimmy L. Patterson, Anthony G. Schaefer
Abstract: There is provided a process for the recovery of essentially enantiomerically pure D-tartaric acid from aqueous and organic waste streams generated in the resolution of racemic 2-amino-2,3-dimethylbutyronitrile via the formation and isolation of a crystalline monobasic tartrate salt.
The recovered optically pure D-tartaric acid may be efficiently recycled to provide a sustainable resolution of racemic 2-amino-2,3-dimethylbutyronitrile.
Abstract: Fungicidal mixtures comprise as active components
a) an amide compound of the formula I
A—CO—NR1R2 I
in which A, R1 and R2 are as defined in the description, and
b) compounds of the formula II, their N-oxide or one of their salts
where the substituents R12 to R18 are as defined in the description,
and/or
c) compounds of the formula III
where the substituents X1 to X5 and R19 to R22 are as defined in the description,
in a synergistically effective amount.
Type:
Grant
Filed:
June 13, 2000
Date of Patent:
February 12, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Klaus Schelberger, Maria Scherer, Karl Eicken, Manfred Hampel, Eberhard Ammermann, Gisela Lorenz, Siegfried Strathmann
Abstract: Process for producing butyrolactones of the general formula I
where R1 and R2 are each hydrogen, alkyl, hydroxyalkyl, substituted or unsubstituted aryl or substituted or unsubstituted trialkylsilyl, by reacting alkynes of the general formula II
where R1 and R2 are each as defined above, with carbon monoxide and water in the presence of a rhodium catalyst under pressures from 20 to 300 bar and hydrogenating the unhydrogenated 2(5H)-furanone intermediates comprises
a) reacting the carbonylation reaction mixture with hydrogen at from 150 to 250° C. and from 100 to 300 bar,
b) removing the precipitated catalyst and returning it into the carbonylation reaction, and
c) subjecting the catalyst-free reaction mixture to a distillation to recover the butyrolactone.
Abstract: Multicomponent superabsorbent fibers are disclosed. The multicomponent fibers comprise at least one acidic water-absorbing resin and at least one basic water-absorbing resin. Each fiber contains at least one microdomain of the acidic resin in contact with, or in close proximity to, at least one microdomain of the basic resin. Blends of multicomponent superabsorbent fibers with particles of a second water-absorbing resin also are disclosed. Articles containing the multicomponent superabsorbent fibers also are disclosed.
Type:
Application
Filed:
May 17, 2001
Publication date:
February 7, 2002
Applicant:
BASF Aktiengesellschaft
Inventors:
Samantha J. Evans, John A. Henderson, Michael A. Mitchell, Anthony S. Tomlin
Abstract: There is provided a process for the prepartion of 2,2-dimethyl-5-(4-chlorobenzyl)cyclopentanone.
a key intermediate in the production of the antifungal agent metconazole.
Abstract: A process for preparing bis(oxime) monoethers of the formula I,
where:
R1 is unsbustituted C1-C4-alkyl or C2-C4-alkenyl-, C2-C4-alkynyl- or phenyl-substituted methyl;
R2,R4 independently of one another are hydrogen or methyl;
R3,R5 independently of one another are hydrogen or C1-C4-alkyl, trifluoromethyl or phenyl,
and intermediates which are obtainable by this process are described.
Type:
Grant
Filed:
May 3, 2001
Date of Patent:
February 5, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Wassilios Grammenos, Hubert Sauter, Andreas Gypser, Herbert Bayer, Norbert Götz, Roland Götz
Abstract: Fungicidal mixture comprises
a) a carbamate of the formula I,
in which X is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl and C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, or a salt or adduct thereof, and
b) a 4,5-benzo-1-thia-2,3-diazole of the formula II
in which R′ is CN, CO2H, CO2—C1-C4-alkyl or CO—S—C1-C4-alkyl, or a salt or adduct thereof,
in a synergistically effective amount.
Type:
Grant
Filed:
December 1, 1999
Date of Patent:
February 5, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Klaus Schelberger, Reinhold Saur, Hubert Sauter, Bernd Müller, Erich Birner, Joachim Leyendecker, Eberhard Ammermann, Gisela Lorenz, Siegfried Strathmann
Abstract: Cyclohexene is prepared by partial hydrogenation of benzene with hydrogen in the presence of water and ruthenium catalyst at elevated temperature and superatmospheric pressure by a continuous process in which benzene is introduced in gaseous form and the resulting cyclohexene is discharged in gaseous form and the catalyst is present in solution or suspension in a liquid, aqueous phase.
Abstract: The present invention relates to a method of producing at cast one coating film on at least one area of a substrate surface, which comprises at least the following steps in the following order:
a) initiating at least one crosslinking reaction in at least one reactive coating formulation;
b) applying said at least one reactive coating formulation before the onset of said at least one crosslinking reaction on said at least one area of said substrate surface.
Type:
Grant
Filed:
November 4, 1999
Date of Patent:
February 5, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Schrof, Reinhold Schwalm, Erich Beck, Uwe Meisenburg