Abstract: The invention relates to a process for the production of two-coat finishes, in which a pigmented aqueous basecoat is applied, the basecoat obtained is coated over with a clearcoat, and basecoat and clearcoat are baked together. The process according to the invention is distinguished in that the aqueous basecoat contains a polyacrylate resin which has been prepared using furfuryl acrylate and/or furfuryl methacrylate.
Type:
Grant
Filed:
December 9, 1994
Date of Patent:
November 24, 1998
Assignee:
BASF Lacke+Farben, AG
Inventors:
Heinz Peter Rink, Bernhard Lettmann, Achim Gast
Abstract: Thermoplastic molding materials containA) from 50 to 99% by weight, based on the total weight of the molding material, of a toughened polymer,B) from 1 to 20% by weight, based on the total weight of the molding material, of a blend ofB.sub.1) a copolymer comprising polymerized units which are derived from a polymerizable carboxylic acid or derivatives thereof andB.sub.2) a polyamide,C) from 0 to 40% by weight of a fibrous or particulate filler or of a mixture thereof andD) from 0 to 20% by weight of conventional additives and processing assistants.
Type:
Grant
Filed:
May 6, 1997
Date of Patent:
November 17, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Graham Edmund Mc Kee, Jurgen Koch, Wolfgang Fischer, Axel Gottschalk, Norbert Guntherberg, Bernhard Rosenau
Abstract: Provided herein is a plant growth regulator formulation comprising a plant growth regulator dispersed in polyvinyl alcohol ("PVA") particles having a mean diameter greater than 1 micron. The present invention also includes an emulsion containing an aqueous dispersion of PVA encapsulated plant growth regulator particles wherein said particles have a mean diameter greater than 1 micron. The above formulations are useful in methods of improving a plant growth factor in a plant.
Abstract: There is now provided a method for making a polyisocyanate based rigid closed cell foam by reacting an organic isocyanate and a polyol composition containing a polyol having polyester linkages and a number average molecular weight of 400 or more, and at least about 8 php of a silicone-containing surfactant polymer, in the presence of an aliphatic or cycloaliphatic C.sub.4 -C.sub.7 hydrocarbon blowing agent. Either mixed into the polyol composition at the time of foaming, mixed into an isocyanate, or both, is an aliphatic or cycloaliphatic C.sub.4 -C.sub.7 hydrocarbon.
Abstract: Expandable ABS resin beads containing a volatile blowing agent are disclosed which have an internal-water content of 5% by weight or lower and, when expanded in an expansion ratio of 30, give expanded beads each having a non-expanded surface layer having a thickness of not more than 50 .mu.m. A process for producing the expandable ABS resin beads is also disclosed which comprises dispersing ABS resin beads into an aqueous medium in a closed vessel and impregnating a volatile blowing agent into the ABS resin beads, said aqueous medium containing an electrolyte at least during the impregnation of the volatile blowing agent, with the concentration of the electrolyte in the aqueous medium being from 0.01 to 2 mol/l. The expandable resin beads are capable of giving an expanded molded article excellent in chemical resistance and toughness and especially in surface appearance and heat resistance.
Type:
Grant
Filed:
September 21, 1995
Date of Patent:
November 17, 1998
Assignee:
Mitsubishi Chemical BASF Company, Limited
Abstract: The stabilizer mixture comprises(a) one or more chroman derivatives of the formula I ##STR1## where R.sup.1 is ##STR2## in which Z is C.sub.7 - to C.sub.30 -alkyl, --CH.sub.2 CH.sub.2 --S--(C.sub.1 - to C.sub.30 -alkyl) or ##STR3## and (b) an inert organic solvent for the chroman derivatives I from the group consisting of aliphatic, cycloaliphatic or aromatic hydrocarbons or halogenated hydrocarbons, silicone oils and vegetable and animal fats,where components (a) and (b) are in a weight ratio of from 99:1 to 1:99.
Abstract: An aqueous solution of free hydroxylamine is prepared by a process in which the solution obtained by treating a hydroxylammonium salt with a base is separated into an aqueous hydroxylamine solution and a salt fraction by treatment with water or steam at .ltoreq.80.degree.0 C. The novel process can be carried out in a simple and gentle manner and on a large industrial scale. Owing to the low thermal load, the low concentration of hydroxylamine and the short residence time in the process, the risk of decomposition is minimized.
Type:
Grant
Filed:
July 29, 1996
Date of Patent:
November 17, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Otto Watzenberger, Hans-Michael Schneider, Bernd Leutner, Albrecht Wilhelm Friederang
Abstract: Describes a deinking agent composition and a method for deinking wastepaper printed with electrostatic ink or mixtures thereof with wastepaper printed with impact ink in which a combination of nonionic surfactants are added to an alkaline slurry of paper fibers. The surfactants are a first nonionic surfactant represented by the formula:R--Ph--(OC.sub.2 H.sub.4).sub.m --(OC.sub.3 H.sub.6).sub.n --(OC.sub.4 H.sub.8).sub.p --R.sup.1and a second nonionic surfactant represented by R.sup.5 --C.sub.6 H.sub.4 O--(C.sub.2 H.sub.4 O).sub.t --H, block copolymers of ethylene oxide and propylene oxide or mixtures of such second nonionic surfactants. R is an aliphatic hydrocarbon group containing from 8 to 10 carbon atoms, Ph is phenylene, R.sup.1 is chloro or phenoxy, R.sup.5 is C.sub.8 -C.sub.13 alkyl, the sum of m, n, and p is a number between 1 and 10, and t is a number between 1 and 9. The deinking agent composition also contains optional nonpolar solvent(s).
Type:
Grant
Filed:
October 1, 1996
Date of Patent:
November 17, 1998
Assignee:
BASF Corporation
Inventors:
Chin Li, Kevin Hipolit, Bhima R. Vijayendran
Abstract: A process for preparing colored melamine-formaldehyde condensation products by:(A) dispersing a mixture consisting essentially of(a) a substituted melamine of the formula I ##STR1## where X.sup.1, X.sup.2 and X.sup.3 are each as disclosed hereinafter, and (b) if desired, formaldehyde or formaldehyde-donating compounds in a molar ratio of formaldehyde to melamines I within the range from 40:1 to 0,(c) a pigment or dye, and mixing(d) if desired, phenol, unsubstituted or substituted.by intensive stirring until there are no longer any pigment agglomerates .gtoreq.1 .mu.m,and then(B) admixing the mixture prepared in (A) with melamine and if desired with further phenol, substituted melamine I and formaldehyde or formaldehyde-donating compounds, and condensing.
Abstract: In the preparation of a rubber-modified molding material, in a first stage, a first mixture (A) contains at least one alkyl acrylate or methacrylate (a) of the formula (I) ##STR1## where R.sup.1 is hydrogen or methyl and R.sup.2 is alkyl of 1 to 32 carbon atoms, if required a first monomer (b) having two or more double bonds and, if required, also a second monomer (c) or a plurality thereof is polymerized, preferably with free radicals, to give a rubber (B), in a second stage, a third monomer (d) or a plurality thereof is added to the resulting rubber (B) to form a second mixture (C), whereby the rubber (B) is dissolved or swollen in the third monomer (d), with or with the addition of a solvent, and in a third stage, the second mixture (C) formed is polymerized with free radicals to give the rubber-modified molding material (D), and the mixture is reacted at >120.degree. C., during or after this polymerization, with a compound (e) which contains at least two peroxy groups.
Type:
Grant
Filed:
May 12, 1997
Date of Patent:
November 17, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Graham Edmund McKee, Rainer Moors, Walter Heckmann, Harald Larbig, Bernhard Rosenau
Abstract: Finely divided mixtures of 97-10% by weight of at least one amphiphilic polymer whose softening point is above 35.degree. C., and 3-90% by weight of at least one inorganic solid with a particle size not exceeding 500 .mu.m are prepared by heating the two components to a temperature which is above the softening point of the polymer, mixing the components, dispersing the melt and rapidly cooling to a temperature at which virtually no inhomogeneity occurs and, where appropriate, further comminuting the particles at temperatures below 50.degree. C. to a particle size of from 50 .mu.m to 5 mm, and are used as additive to detergents.
Type:
Grant
Filed:
May 16, 1997
Date of Patent:
November 10, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans-Ulrich Jager, Dieter Boeckh, Ulrich Brockel, Frank Muller, Gunnar Schornick
Abstract: Disazo dyes of the formula ##STR1## where the ring A may be benzofused,X is hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, halogen, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl or hydroxysulfonyl,R.sup.2 is hydrogen, C.sub.1 -C.sub.4 -alkyl, halogen, carboxyl or C.sub.1 -C.sub.4 -alkoxycarbonyl, or R.sup.1 and R.sup.2 together are a radical of the formula L--NZ--CO, where L is methylene or carbonyl and Z is substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or substituted or unsubstituted phenyl, andR.sup.3 is hydrogen, C.sub.1 -C.sub.4 -alkyl, hydroxyl, C.sub.1 -C.sub.4 -alkoxy, phenoxy, C.sub.1 -C.sub.4 -alkanoyloxy or benzoyloxy,are useful for dyeing natural or synthetic substrates.
Abstract: Impact-resistant thermoplastic molding materials containA) from 10 to 99.5% by weight of a thermoplastic polymer selected from the group consisting of the polyoxymethylenes, polyolefins, polyesters, polycarbonates, polystyrene, ABS, ASA, SAN, polyamides or poly(meth)acrylates or mixtures thereof,B) from 0.5 to 80% by weight of a thermoplastic polyurethane,C) from 0 to 50% by weight of a fibrous or particulate filler andD) from 0 to 30% by weight of conventional additives and processing assistants,the thermoplastic polyurethane B) containing from 0.05 to 10% by weight, based on B), of a carbodiimide: ##STR1## where R is identical or different and is selected from the group consisting of --NCO--, --NHCONHR.sup.1 --, --NHCONR.sup.1 R.sup.2 -- and --NHCOOR.sup.3 -- radicals, whereR.sup.1 and R.sup.2 are identical or different and are an alkyl, cycloalkyl or aralkyl radical andR.sup.3 is R.sup.1 or an alkoxypolyoxyalkylene radical andn is an integer from 0 to 10.
Abstract: Isoxazol-4-ylbenzoyl derivatives of the formula I ##STR1## where the substituents have the meanings described in the specification; and agriculturally customary salts thereof.
Type:
Grant
Filed:
August 22, 1997
Date of Patent:
November 10, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Von Deyn, Regina Luise Hill, Uwe Kardorff, Stefan Engel, Martina Otten, Marcus Vossen, Peter Plath, Harald Rang, Albrecht Harreus, Franz Rohl, Helmut Walter, Karl-Otto Westphalen, Ulf Misslitz
Abstract: Thermoplastic molding materials which contain from 0.1 to 10% by weight of a compound of a polyvalent metal are suitable for the production of dull moldings having high impact strength.
Abstract: The method of the invention provides for improvement of a plant growth factor by applying an ethylene inhibitor plant growth regulator to a plant, such as cotton or soybean, at a low rate. Specific plant growth regulators include compounds covered by the general formula: ##STR1## where R1 and R2 independently of one another are C1-C6-alkyl, n is 2 or 3 and R3 is hydrogen or C1-C6 alkyl. Specific compounds employed by the method of the invention include {?(isopropylidene)-amino!oxy}-acetic acid-2-(methoxy)-2-oxoethyl ester, {?(isopropylidene)-amino!oxy}-acetic acid-2-(hexyloxy)-2-oxoethyl ester, {{cyclohexylidene)-amino!oxy}-acetic acid-2-(isopropyloxy)-2-oxoethyl ester, ?((isopropylidene)amino!oxy acetic acid and aminooxyacetic acid.
Abstract: Mixtures of liquid-crystalline compounds comprising at least two different substances of the formula I ##STR1## where Z.sup.1 and Z.sup.2, independently of one another, are polymerizable groups,Y.sup.1 and Y.sup.2, independently of one another, are each a direct bond, --O--, --COO--, --OCO-- or --S--,A.sup.1 and A.sup.2, independently of one another, are spacers, andR.sup.1, R.sup.2 and R.sup.3 are conventional substituents,and novel compounds of the above formula where at least two of Z.sup.1, Z.sup.2, Y.sup.1, Y.sup.2, A.sup.1 and A.sup.2 are not identical, are described. The novel mixtures and compounds are suitable, inter alia, as base material for color-effect materials and piezomaterials, preferably in chirally doped form.
Type:
Grant
Filed:
August 23, 1996
Date of Patent:
November 10, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Karl Siemensmeyer, Karl-Heinz Etzbach, Paul Delavier, Frank Meyer
Abstract: Methods of continuously producing sequential lengths of different additive-containing melt-spun filaments include continuously supplying a melt-spinnable polymeric host material to orifices of a spinneret and controllably dosing at least one dispersible additive concentrate system containing a pigment in a liquid nonaqueous polymeric carrier to the melt flow of polymeric host material upstream of the spinneret orifices. In such a manner, a first polymeric mixture of the dispersible additive concentrate system and the polymeric host material is obtained which achieves an additive attribute. During a first time interval, the first mixture is extruded through the spinneret orifices; and thereafter, during a second subsequent time interval, the dosing of the at least one dispersible additive is changed so as to form a second mixture having a second additive attribute different from the first additive attribute while continuously supplying the melt flow of polymeric host material to the spinneret orifices.
Type:
Grant
Filed:
March 3, 1997
Date of Patent:
November 10, 1998
Assignee:
BASF Corporation
Inventors:
Frank R. Jones, Stanley A. McIntosh, Gary W. Shore, Karl H. Buchanan, David B. Ledford, Wayne S. Stanko, G. Daniel Gasperson, Charles F. Helms, Jr.
Abstract: Synthetic filaments include a nonaqueous additive system having dispersant-coated pigments physically dispersed in a liquid nonaqueous polymeric carrier. The additive system is most preferably in the form of a particulate paste which can be added in metered amounts (dosed) to a melt flow of the polymeric host material prior to being spun into filaments. By providing a number of additive systems having a number of different additive attributes, and controllably dosing one or more into the melt flow of polymeric material, melt-spun filaments having different additive attributes may be produced on a continuous basis (i.e., without shutting down the spinning operation). The filaments may be included in yarns which are formed into carpet structures.
Type:
Grant
Filed:
March 3, 1997
Date of Patent:
November 10, 1998
Assignee:
BASF Corporation
Inventors:
Frank R. Jones, Stanley A. McIntosh, Gary A. Shore, Karl H. Buchanan, David B. Ledford, Wayne S. Stanko, G. Daniel Gasperson, Charles F. Helms, Jr.
Abstract: The present invention relates to an aqueous multicomponent polyurethane coating composition comprisingA) a water-dilutable polyaddition resin (A1) and/or polycondensation resin (A2) containing hydroxyl and carboxylate groups and having an OH number of from 40 to 200 mg of KOH/g, preferably from 60 to 140 mg of KOH/g, an acid number of from 15 to 100 mg of KOH/g, preferably from 25 to 50 mg of KOH/g, and a glass transition temperature of from -40.degree. C. to +60.degree. C., preferably from -20.degree. C. to +40.degree. C.,B) a polyisocyanate component (B) as crosslinking agent andC) at least one additive,characterized in that it contains as additive a carbodiimide component (C) which has a content of carbodiimide groups --N.dbd.C.dbd.N-- of from 2 to 30% by weight, on average at least 0.
Type:
Grant
Filed:
November 4, 1996
Date of Patent:
November 10, 1998
Assignee:
BASF Lacke + Farben, AG
Inventors:
Uwe Meisenburg, Egbert Nienhaus, Rolf Seidemann, Bernd Mayer, Anthony J. Tye