Abstract: The present invention relates to a process for preparing an isocyanate, comprising hydrogenating a mixture (Gi) comprising an amine in the presence of a hydrogenation catalyst comprising copper to obtain a mixture (Gii) comprising the amine, and reacting the mixture (Gii) with phosgene to obtain a mixture (Giii) comprising the isocyanate. The present invention further relates to the isocyanate preparable by this process.
Type:
Grant
Filed:
November 18, 2009
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Daniel Breuninger, Johannes Adam, Heiner Schelling, Eckhard Stroefer, Markus Kraemer, Matthias Eiermann, Kai Thiele, Michael Zoellinger, Rolf Pinkos
Abstract: The present invention relates to a process for preparing neopentyl glycol (NPG) by continuously hydrogenating hydroxypivalaldehyde (HPA) with hydrogen, in the liquid phase, in the presence of a hydrogenation catalyst, in a hydrogenation reactor (5), by combining an HPA-comprising stream (1) with an NPG-comprising stream (2) to give a hydrogenation feed (4) and introducing the hydrogenation feed (4) into the hydrogenation reactor (5) and additionally supplying at least one pH regulator (3) selected from the group consisting of tertiary amine, an inorganic base, an inorganic acid and an organic acid to the HPA-comprising stream (1) or the NPG-comprising stream (2) or the hydrogenation feed (4), in order to establish a pH of 7.0 to 9.
Type:
Grant
Filed:
May 11, 2011
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Michael Steiniger, Maria Guixa Guardia, Kai Stehmeier
Abstract: A reactor in the form of a cylinder or prism wherein the interior of the reactor is divided by a cylindrical or prismatic gastight housing G which is arranged in the longitudinal direction of the reactor into an inner region having one or more catalytically active zones, in which in each case a packing composed of monoliths stacked on top of one another, next to one another and behind one another and before each catalytically active zone in each case a mixing zone having solid internals are provided, and an outer region B arranged coaxially to the inner region A, wherein the inner region A is insulated from the outer region B of the reactor by means of a microporous high-performance insulation material having a thermal conductivity 1 at temperatures up to 700° C. of less than 0.05 W/m*K is proposed.
Type:
Grant
Filed:
August 1, 2012
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Gerhard Olbert, Ulrike Wegerle, Grigorios Kolios, Carlos Tellaeche Herranz, Reinhold Höchst, Andrea Gienger, Roland Bauer
Abstract: The present invention relates to pyridazine compounds of formulae I or II and the salts and N-oxides thereof, wherein the substituents have the meanings as defined in the description, a method for controlling invertebrate pests, to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material, comprising at least one compound according to the present invention, to a method for treating or protecting an animal from infestation or infection by parasites and to an agricultural composition containing at least one compound according to the present invention.
Type:
Grant
Filed:
March 21, 2011
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Ronan Le Vezouet, Sebastian Soergel, Christian Defieber, Steffen Gross, Karsten Koerber, Douglas D. Anspaugh, Deborah L. Culbertson
Abstract: The present invention provides a process for producing moldings, the curing of the mold being carried out using a blend comprising one or more epoxy resins and a mixture, the curing component a) being used within the mixture in the range from 0.3 to 0.9 amine equivalent per equivalent of epoxide of the epoxy resin used, and the hardener component b) being a compound of the formula I.
Type:
Grant
Filed:
July 17, 2009
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Lars Wittenbecher, Michael Henningsen, Gregor Daun, Dieter Flick, Joerg-Peter Geisler, Juergen Schillgalies, Erhard Jacobi
Abstract: The present invention relates to an integrated method for producing cellulose and at least one low-molecular-weight reusable material, in which a starting material containing lignocellulose is provided and subjected to a decomposition with a processing medium. A fraction enriched with cellulose and a fraction depleted of cellulose is then isolated from the decomposition material, the depleted fraction of cellulose being subjected to a treatment during which at least one low-molecular-weight reusable material is obtained.
Type:
Grant
Filed:
September 7, 2009
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Otto Machhammer, Jochem Henkelmann, Wolfgang Rohde, Mario Emmeluth, Sonja Giesa
Abstract: Processes for preparing 4-chlorobenzenesulfonic acid from 2-chlorobenzenesulfonic acid and/or 3-chlorobenzenesulfonic acid, which processes include the conversion of 2-chlorobenzenesulfonic acid and/or 3-chlorobenzenesulfonic acid to 4-chlorobenzenesulfonic acid in the presence of sulfuric acid at a temperature of 100 to 300° C.; as well as processes for preparing 4,4?-dichlorodiphenyl sulfone, which include such described processes for preparing 4-chlorobenzenesulfonic acid.
Type:
Grant
Filed:
March 7, 2011
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Patrick Deck, Heiner Schelling, Florian Garlichs
Abstract: A catalyst complex composed of boron trifluoride and a cocatalyst mixture of 10 to 90% by weight of a monohydric primary C1- to C20-alcohol and 90 to 10% by weight of a monohydric secondary C3- to C20-alcohol, where the molar ratio of boron trifluoride to the sum of all alcohols is 2:1 to 1:10. This catalyst complex is used in the preparation of high-reactivity isobutene homopolymers having a number-average molecular weight of 300 to 50 000, using, as the feedstock, a C4 hydrocarbon mixture comprising at least 20% by weight of isobutene and a total of at least 10% by weight of other C4 olefins.
Type:
Grant
Filed:
February 15, 2013
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Thomas Wettling, Stefan Hirsch, Markus Brym, Markus Weis
Abstract: The present invention relates to a new method of preparing halogenated styrene compounds of formula (VIII) which are precursors in the process of synthesis of substituted isoxazoline compounds of formula (I) wherein R1 to R5, R8 and R9 are described as in the description. The present invention relates further to the synthesis of compounds of formula (I) starting from acetophenones. The desired styrenes of formula are prepared from the appropriate substituted acetophenone. Asides bromo anilines react with formoxime. Obtained oximes undergo a cycloaddition with the styrenes and give isoxazolines. Compounds of formula (I) can then be prepared in a palladium catalyzed carbonylative amination reaction of the isoxazolines.
Type:
Grant
Filed:
April 29, 2010
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Michael Rack, Karsten Koerber, Florian Kaiser
Abstract: Provided are methods for maintaining the ratio of the oxime to equilibrium modifier concentration in solvent extraction circuits, said solvents essentially consisting of at least one ketoxime and/or aldoxime; at least one equilibrium modifier; and at least one diluent.
Type:
Grant
Filed:
July 17, 2012
Date of Patent:
October 7, 2014
Assignee:
BASF Corporation
Inventors:
Michael Virnig, Jack Bender, Nathan C. Emmerich
Abstract: The present invention relates to a process for preparing substituted 2-nitrobiphenyls and to specific 2-nitrobiphenyls. The invention further relates to a process for preparing 2-aminobiphenyls from such 2-nitrobiphenyls and to a process for preparing (het)arylamides of such 2-aminobiphenyls.
Type:
Grant
Filed:
March 8, 2010
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Alexander Korte, Jan Klaas Lohmann, Thomas Grote, Klaus Ebel, Thomas Zierke, Horst Mayer, Ralf Wazulek
Abstract: The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution in a surrounding heated gas phase and flowing the gas cocurrent through the polymerization chamber, which comprises coating the water-absorbing polymer particles with at least one sulfinic acid, sulfonic acid and/or salts thereof.
Type:
Grant
Filed:
March 9, 2011
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Norbert Herfert, Thomas Daniel, Rainer Dobrawa
Abstract: The present invention relates to an electronic device comprising at least one dielectric layer, said dielectric layer comprising a crosslinked organic compound based on at least one compound which is radically crosslinkable and a method of making the electronic device.
Abstract: The invention relates to a process for operating a mixing kneader, comprising one or more shafts on whose surfaces are disposed kneading bars and which are surrounded by a casing, comprising the following steps: (a) supplying reactants at an addition site in the mixing kneader, (b) converting the reactants in an exothermic reaction, the reaction at first forming a coherent kneadable intermediate, (c) tearing and dividing the coherent kneadable intermediate to form a product, the exothermic reaction optionally continuing during the tearing and division, (d) withdrawing the product at a withdrawal site in the mixing kneader, wherein at least one of the shafts and/or the casing is heated to a temperature above 20° C. during the operation of the mixing kneader.
Type:
Grant
Filed:
May 6, 2013
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Oskar Stephan, Monte Peterson, Karl J. Possemiers, Steven Lippens
Abstract: A process for mineral oil production, especially Winsor type III microemulsion flooding, in which an aqueous surfactant formulation which comprises at least one alkylpolyalkoxysulfate comprising propoxy groups, and at least one further surfactant differing therefrom is used, is forced through injection wells into a mineral oil deposit and crude oil is removed from the deposit through production wells. The alkylpolyalkoxysulfate comprising propoxy groups is prepared in this case by sulfating an alkoxylated alcohol, the alkoxylated alcohol being prepared by alkoxylating an alcohol using double metal cyanide catalysts or double hydroxide clays.
Type:
Grant
Filed:
October 13, 2010
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Christian Bittner, Günter Oetter, Jack Tinsley, Christian Spindler, Gabriela Alvarez Jürgenson, Sophie Vogel
Abstract: The invention relates to an apparatus for pest control comprising a hollow station (150) forming at least one entrance (160, 165) for the pests to be controlled and a harborage area inside the station; a reservoir for water (100) providing access to water from the inside of said hollow station (150); and a contact pesticide (170) for the pests to be controlled, said contact pesticide (170) being provided inside said hollow station (150) in such a way that pests which enter the hollow station (150) through said at least one entrance (160, 165) to come to the reservoir for water (100) or the harborage area come into contact with said contact pesticide (170).
Abstract: The invention relates to a process for preparing primary amines by alcohol amination of alcohols with ammonia with the elimination of water, where the alcohol amination is carried out under homogeneous catalysis in the presence of at least one complex catalyst which comprises ruthenium and at least one at least bidental donor ligand, but no anionic ligands.
Type:
Grant
Filed:
July 23, 2013
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Mathias Schelwies, Marion Brinks, Thomas Schaub, Johann-Peter Melder, Rocco Paciello, Martin Merger
Abstract: The present invention is directed to a method for coating a sheet-like cellulose containing material by applying a composition comprising at least one glucan (G), which has a ?(beta)-1,3-glycosidically linked main chain and at least one side group having a ?(beta)-1,6-glycosidic bond to the main chain, particularly Schizophyllan, and at least one solvent (S), particularly a ionic liquid, on the surface of the sheet-like material.
Type:
Grant
Filed:
March 28, 2012
Date of Patent:
October 7, 2014
Assignees:
Wintershall Holding GmbH, BASF SE
Inventors:
Mari Granström, Stephan Freyer, Rajan Hollmann, Julia Kristiane Schmidt, Alois Kindler
Abstract: The present invention is concerned with means and methods for allowing tissue specific and, in particular, seed specific expression of genes. The present invention, accordingly, relates to a polynucleotide comprising an expression control sequence which allows seed specific expression of a nucleic acid of interest being operatively linked thereto. Moreover, the present invention contemplates vectors, host cells, non-human transgenic organisms comprising the aforementioned polynucleotide as well as methods and uses of such a polynucleotide.
Abstract: Hyperbranched polycarbonates having stabilizing groups, prepared by reaction of (a) at least one compound having at least three alcoholic hydroxyl groups per molecule with (b) at least one reagent of the general formula I (c) and at least one reagent of the general formula X3-(A1)m-X4, where the variables are defined as follows: X1, X2 are identical or different and are selected from among halogen, C1-C10-alkoxy, C6-C10-aryloxy and O—C(?O)-halogen, X3 is a functional group selected from among OH, SH, NH2, NH—C1-C4-alkyl, iso-cyanate, epoxy, COOH, COOR12, C(?O)—O—C(?O), C(?O)—Cl, R12 is C1-C4-alkyl or C6-C10-aryl, A1 is a spacer or a single bond, m is zero or one. X4 is a group selected from among phenol groups, benzophenones, aromatic amines and nitrogen-comprising heterocycles, in each case substituted or unsubstituted.
Type:
Grant
Filed:
September 9, 2011
Date of Patent:
October 7, 2014
Assignee:
BASF SE
Inventors:
Bernd Bruchmann, Jens Aβmann, Claudius Schwittay, Harald Schäfer