Abstract: Disclosed are processes for the preparation of copper containing molecular sieves with the CHA structure wherein the copper is exchanged into the Na+-form of the Chabazite, using a liquid copper solution wherein the concentration of copper is in the range of about 0.001 to about 0.4 molar. Also described are copper containing molecular sieves with the CHA structure, catalysts incorporating molecular sieves, systems and methods for their use.
Type:
Grant
Filed:
December 16, 2010
Date of Patent:
October 23, 2012
Assignee:
BASF Corporation
Inventors:
Tilman W. Beutel, Ivor Bull, Ahmad Moini, Michael Breen, Martin Dieterle, Saeed Alerasool, Xinsheng Liu, Wenyong Lin, Barbara Slawski, Ulrich Mueller
Abstract: The invention relates to a process for producing a catalyst comprising a metal of the platinum group and a second metal selected from among the metals of the platinum group or the transition metals, in which a catalyst comprising the metal of the platinum group is mixed with a complex comprising the second metal to give a dry powder in a first step and the powder is subsequently heat treated to form a compound between the metal of the platinum group and the second metal. The invention further relates to the use of the catalyst produced according to the invention.
Type:
Grant
Filed:
November 6, 2008
Date of Patent:
October 23, 2012
Assignee:
BASF SE
Inventors:
Stefan Kotrel, Gerhard Cox, Ekkehard Schwab, Alexander Panchenko
Abstract: The invention relates to a process for producing rigid polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups in the presence of c) blowing agents, wherein at least one graft polyol b1) which can be prepared by in-situ polymerization of olefinically unsaturated monomers in a polyether alcohol b1i), where the polyether alcohol b1i) has a functionality of from 2 to 4 and a hydroxyl number in the range from 100 to 250 mg KOH/g, its polyether chain comprises propylene oxide and up to 20% by weight, based on the polyether alcohol b1i), of ethylene oxide, and acrylonitrile and styrene in a weight ratio of acrylonitrile:styrene of from >1:1 to 4:1 are used as olefinically unsaturated monomers, is used as compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b), and the reaction is carried out in the presence of at least one compound b1ii) which has at least one olefinic double bond an
Type:
Grant
Filed:
September 6, 2007
Date of Patent:
October 23, 2012
Assignee:
BASF Aktiengesellschaft
Inventors:
Andreas Emge, Daniel Freidank, Holger Seifert
Abstract: Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of at least one thermoplastic polymer, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 40% by weight of a halogen-free flame retardant, selected from the group of the phosphorus-containing or nitrogen-containing compounds, or of the P—N condensates, or a mixture of these, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.
Type:
Grant
Filed:
October 6, 2005
Date of Patent:
October 23, 2012
Assignee:
BASF SE
Inventors:
Jochen Engelmann, Bernd Bruchmann, Andreas Eipper, Jean-Francois Stumbe, Carsten Weiss, Dietrich Scherzer, Michaela Liese, Mark Volkel
Abstract: Processes for the continuous fractional distillation of a mixture containing morpholine (MO), monoaminodiglycol (ADG), ammonia and water from a reaction of diethylene glycol (DEG) with ammonia, the process including: (i) separating off ammonia from the mixture at a top of a first distillation column K10; (ii) feeding a bottom fraction from K10 to a second distillation column K20, in which water and an organic product are separated off at the top at a temperature at the top in the range from 45 to 198° C. and a pressure in the range from 0.
Type:
Grant
Filed:
September 12, 2007
Date of Patent:
October 23, 2012
Assignee:
BASF SE
Inventors:
Helmut Schmidtke, Oliver Buβmann, Ralph Versch, Udo Rheude, Uwe Leyk, Manfred Julius, Martin Rudloff, Erhard Henkes
Abstract: Disclosed are processes for the preparation of copper containing molecular sieves with the CHA structure having a silica to alumina mole ratio greater than about 10, wherein the copper exchange step is conducted via wet state exchanged and prior to the coating step and wherein in the copper exchange step a liquid copper solution is used wherein the concentration of copper is in the range of about 0.001 to about 0.25 molar using copper acetate and/or an ammoniacal solution of copper ions as copper source. Catalysts made by the processes, catalyst systems and methods of treating exhaust gas with the molecular sieves and catalysts are also disclosed.
Type:
Grant
Filed:
December 16, 2010
Date of Patent:
October 23, 2012
Assignee:
BASF Corporation
Inventors:
Tilman W. Beutel, Ivor Bull, Ahmad Moini, Michael Breen, Martin Dieterle, Saeed Alerasool, Barbara Slawski
Abstract: The present invention relates to a process for preparing 1,2-propanediol, in which a glycerol-containing stream, especially a stream obtained on the industrial scale in the production of biodiesel, is subjected to a hydrogenation in an at least three-stage reactor cascade.
Type:
Grant
Filed:
August 29, 2008
Date of Patent:
October 23, 2012
Assignee:
BASF SE
Inventors:
Jochem Henkelmann, Roman Prochazka, Oliver Bey, Stephan Maurer, Jochen Steiner, Heiko Urtel, Gerhard Theis, Peter Wahl
Abstract: The invention relates to a process for producing an energy-absorbing component composed of profile elements, made of a polymer material, which are open on one side, respectively orientated in opposite directions, and connected to one another on at least one side as a single piece to give a linearly continuous structure. The process involves (a) closure of a mold comprising at least two mold-section profiles, which can be moved in opposite directions and respectively have protruding regions and recessed regions such that, in a closed condition, the protruding regions of oppositely arranged profiles intermesh; (b) injection of the polymer material into a mold; and (c) opening of the mold, by moving the mold-section profiles apart in an opposite direction, and removing the energy-absorbing component.
Type:
Application
Filed:
April 10, 2012
Publication date:
October 18, 2012
Applicant:
BASF SE
Inventors:
Andreas Wuest, Marco Gross, Helge Weiler
Abstract: Processes for producing aqueous dispersions of aliphatic polycarbonates are described herein. A solution of the aliphatic polycarbonate in at least one aprotic, organic solvent comprising at least 50% by volume ethyl acetate based on the total amount of the organic solvent is provided. The aliphatic polycarbonate solution is emulsified in an aqueous emulsification medium in the presence of at least one surface-active substance to produce an aqueous emulsion of the aliphatic polycarbonate solution. The apriotic, organic solvent is removed from the emulsion by vaporization.
Type:
Application
Filed:
April 13, 2012
Publication date:
October 18, 2012
Applicant:
BASF SE
Inventors:
JULIEN COURTOIS, Martin Schneele, Willi Riegel, Hubertus Kröner
Abstract: The present invention relates to a process for preparing aminopolycarboxylates proceeding from an amino acid which, in a first process step is reacted with ethylene oxide to give an intermediate mixture comprising the corresponding dialkanolamine, and then the intermediate mixture, in a second process step is converted catalytically using a base to the corresponding aminopolycarboxylate, wherein the amino acid, before the reaction with ethylene oxide in the first process step, is supplied to a partial neutralization with 0.70 to 0.99 equivalent of base per acid group, or, in the first process step, an amino acid which has already been partly neutralized with 0.70 to 0.99 equivalent of base per acid group is used.
Type:
Application
Filed:
March 26, 2012
Publication date:
October 18, 2012
Applicant:
BASF SE
Inventors:
Robert Baumann, Markus Christian Biel, Axel Franzke, Thomas Heidenfelder, Paul Klingelhoefer, Alfred Oftring
Abstract: The present invention relates to a process for producing polymer-containing coatings for surfaces by in situ precipitation of calcium carbonate. The invention is additionally directed to the polymer-containing coating as such and to surfaces to which such polymer-containing coatings have been applied. The polymer-containing coatings preferably have antibacterial action.
Type:
Application
Filed:
November 26, 2010
Publication date:
October 18, 2012
Applicant:
BASF SE
Inventors:
Sabrina Montero Pancera, Robert Wengeler
Abstract: A process for producing a rigid polyurethane foam by reacting an organic polyisocyanate with a polyol component containing a compound with at least two hydrogen atoms which are reactive toward isocyanate groups in the presence of a blowing agent, a catalyst, and optionally auxiliaries and additives, wherein the polyol component contains, by weight: 20 to 60 parts of a polyether alcohol having a functionality of 3.5 to 5.5 and a hydroxyl number of from 400 to 550 mg KOH/g; 1 to 20 parts of a polyether alcohol based on an aliphatic amine and having a functionality of 3.5 to 4.5 and a hydroxyl number of 450 to 900 mg KOH/g; 10 to 30 parts of a polyether alcohol and/or aromatic polyester alcohol having functionalities of 1.5 to 3 and a hydroxyl number of from 150 to 450 mg KOH/g; and optionally 1 to 5 parts of water.
Type:
Application
Filed:
April 3, 2012
Publication date:
October 18, 2012
Applicant:
BASF SE
Inventors:
Zeljko Tomovic, Olaf Jacobmeier, Gunnar Kampf
Abstract: The present invention relates to a stable mixture comprising surface-modified particles which are obtained by reacting metal oxide or semimetal oxide particles with at least one compound selected from among silicon-comprising compounds bearing at least one metaloxy radical and optionally further alkoxy and/or hydroxy radical(s) and at least one solvent, at least one surface-active substance or a mixture thereof, a process for producing the mixture, the use of these particles in systems in which they are brought into contact with at least one solvent, where the mass ratio of solvent to modified particle is greater than 500, and also the use of these particles in agglomeration-deagglomeration cycles.
Type:
Application
Filed:
March 29, 2012
Publication date:
October 18, 2012
Applicants:
BASF CORPORATION, BASF SE
Inventors:
Stephan DEUERLEIN, Imme Domke, Alexej Michailovski, Reinhold Rieger, Piyada Charoensirisomboon, David F. Blackwood, Christian Eichholz, Robert Bayer, Dennis Lösch, Igor Shishkov
Abstract: The present invention relates generally to the field of molecular biology and concerns a method for enhancing various economically important yield-related traits in plants. More specifically, the present invention concerns a method for enhancing yield-related traits in plants by modulating expression in a plant of a nucleic acid encoding a CLC-like (Chloride Channel-like) polypeptide, or an OsBURP-like (BURP-domain containing protein) polypeptide, or an AP2/ERF polypeptide or a protein fusion comprising a TPS (trehalose-6-phosphate synthase) and a TPP (trehalose-6-phosphate phosphatase) polypeptide or modulating one or more nucleic acid encoding a TPS and a TPP enzyme, whether comprised in the same or in separate molecules. The present invention also concerns plants having modulated expression of a nucleic acids and constructs comprising them, useful in performing the methods of the invention.
Type:
Application
Filed:
October 14, 2010
Publication date:
October 18, 2012
Applicants:
Crop Functional Genomics Center, BASF Plant Science Company GmbH
Inventors:
Ana Isabel Sanz Molinero, Steven Vandenabeele, Christophe Reuzeau, Yang Do Choi, Ju Kon Kim
Abstract: The present invention relates to a method for producing granules comprising a pesticide, comprising the spraying-on of a pesticide-containing spray liquid in the region of a near-circular gas/material stream of a spouted-bed apparatus onto the particle surface of the material, and the drying and granulation in the gas stream. Furthermore, the invention relates to granules comprising a pesticide, obtainable by said method, where the granules have a roundness of at least 0.85.
Type:
Application
Filed:
October 25, 2010
Publication date:
October 18, 2012
Applicant:
BASF SE
Inventors:
Stefan Blei, Karl-Heinrich Schneider, Hans-Michael Fricke, Albert Werner
Abstract: The invention relates to a process for producing a catalyst for the oxidation of ethylene to ethylene oxide, which comprises a) providing a support which comprises alumina and has been impregnated with silver or with a silver-comprising compound and has a temperature T0; and b) heating the impregnated support from the temperature T0 to a temperature T1 at a heating rate of at least 30 K/min, and also the catalyst itself which can be obtained by this process.
Abstract: The present invention relates to a process for producing baked goods which is characterized in that a mixture of at least one baking raising agent and at least one substance selected from the group consisting of asparaginase, sulfites, bisulfites, metabisulfites and chlorides is used in the production of the baked goods dough. In addition, the present invention relates to a mixture of at least one baking raising agent and at least one substance selected from the group consisting of asparaginase, sulfites, bisulfites, metabisulfites and chlorides. In addition, the present invention relates to the use of sulfites and metabisulfites for decreasing acrylamide in foods.
Abstract: Oxidation-sensitive, low-peroxide polymer contained in a sealed, protective-gas-filled packaging form, comprising, per kilogram of polymer solid, at least one inorganic phosphorus compound in amounts such that the total phosphorus content is 2*10?5 to 0.02 mol, and methods for stabilizing oxidation-sensitive polymer against peroxide formation, wherein, during or after the polymerization, at least one inorganic phosphorus compound is added in one or more portions in amounts such that the total phosphorus content per kilogram of polymer solid content of the finished polymer is 2*10?5 to 0.02 mol, and the polymer treated in such a way is placed into a protective-gas filled, sealed packaging form, and also use of these polymers.