Abstract: A process for isomerizing olefinically unsaturated alcohols over supported noble metal catalysts with a support based on carbon in an oxygenous atmosphere.
Type:
Grant
Filed:
February 27, 2009
Date of Patent:
September 11, 2012
Assignee:
BASF SE
Inventors:
Michael Limbach, Joaquim Henrique Teles, Radwan Abdallah, Torsten Mäurer, Thorsten Johann, Manuel Danz
Abstract: The present invention relates to a process for gas-phase oxidation, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed through two or more catalyst zones. Furthermore, the present invention relates to a catalyst system for gas-phase reaction using a preliminary zone.
Type:
Grant
Filed:
December 12, 2007
Date of Patent:
September 11, 2012
Assignee:
BASF SE
Inventors:
Hagen Wilmer, Jürgen Zühlke, Thomas Lautensack, Hans-Martin Allmann, Frank Rosowski, Cornelia Dobner
Abstract: A phosphate-free detergent formulation for machine dishwashing, having from 1 to 20% by weight of a mixture of from 5 to 95% by weight of hydrophobically modified polycarboxylates I formed from 20 to 80 mol % of at least one monoethylenically unsaturated C3-C10-mono- or -dicarboxylic acid or anhydrides thereof, from 0 to 80 mol % of at least one monomer of the general formula (I) in which R1, R2 and R3 are each independently H, CH3 or C2H5, and R4 is a linear, branched or cyclic radical having from 1 to 6 carbon atoms or an aromatic radical having from 6 to 12 carbon atoms, and from 0 to 20 mol % of at least one further monomer, from 5 to 95% by weight of hydrophilically modified polycarboxylates II, where the sum of a1) and a2) adds up to 100% by weight.
Type:
Grant
Filed:
October 10, 2008
Date of Patent:
September 11, 2012
Assignee:
BASF SE
Inventors:
Heike Weber, Roland Ettl, Juergen Tropsch
Abstract: Thermoplastic molding compositions comprising A) from 10 to 99.99% by weight of at least one thermoplastic polyester B) from 0.01 to 50% by weight of a highly branched or hyperbranched polyester of AxBy type where x is at least 1.1 and y is at least 2.1 C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.
Type:
Grant
Filed:
February 2, 2005
Date of Patent:
September 11, 2012
Assignee:
BASF Aktiengesellschaft
Inventors:
Andreas Eipper, Bernd Bruchmann, Dietrich Scherzer, Jean-Francois Stumbe, Carsten Weiss, Freddy Gruber
Abstract: A process for redissociating Michael adducts which are present in a liquid F with a proportion by weight of ?10% by weight and have been formed in the preparation of acrylic acid or esters thereof in a redissociating apparatus which comprises a pump P, a separating column K with separating internals and a circulation heat exchanger UW, wherein, for the purpose of supplying the cleavage energy, the pump P sucks in bottoms liquid from the bottom space of the separating column K and, via the circulation heat exchanger UW, continually recycles it into the bottom space above the level of the bottoms liquid, and wherein the pump P is a radial circulation pump with an open impeller.
Type:
Grant
Filed:
December 9, 2009
Date of Patent:
September 11, 2012
Assignee:
BASF SE
Inventors:
Volker Schliephake, Thorsten Friese, Klaus Bott, Michael Blechschmitt, Till Blum, Klaus Joachim Mueller-Engel
Abstract: Helical tube evaporators are used to concentrate aqueous extract solutions from the extraction of polyamides based on polyamide 6. A process for preparing polyamides based on polyamide 6 comprises the stages of b) monophasic or biphasic reaction of aqueous extract solutions from the extraction of polyamides based on polyamide 6, which may be enriched with caprolactam, aminocapronitrile, aminocaproic acid or mixtures thereof, in a prereactor at pressures in the range from 5 to 40 bar and temperatures in the range from 150 to 300° C., the gaseous phase formed being removable from the liquid phase in the case of the biphasic reaction, c) discharge of the reaction mixture from stage b) through a helical tube evaporator at a temperature in the range from 220 to 300° C. with pressure reduction to about atmospheric pressure and removal of a gaseous phase to obtain a liquid phase, d) further reaction of the liquid phase from stage c) at temperatures in the range from 240 to 300° C.
Abstract: A process for the preparation of polyalkenylsuccinimide products, in particular polyisobutenylsuccinimide products, is proposed, in which a polyalkene is reacted with a maleic acid, maleic anhydride or a functional derivative thereof to give a polyalkenylsuccinic anhydride and the polyalkenylsuccinic anhydride is then reacted with an oligoamine or polyamine, the polyalkenylsuccinic anhydride either (a) first being reacted with an alcohol or phenol and, without isolation of the reaction product, then with the oligoamine or polyamine, or (b) the polyalkenylsuccinic anhydride being reacted with the oligoamine or polyamine in the presence of an alcohol or phenol and (c) if desired, the alcohol or the phenol then being removed. Novel polyalkenylsuccinimide products, in particular polyisobutenylsuccinimide products, and fuel additives are also proposed.
Type:
Grant
Filed:
May 14, 2002
Date of Patent:
September 11, 2012
Assignee:
BASF Aktiengesellschaft
Inventors:
Stephan Hueffer, Peter Schwab, Klaus Fischer, Thomas Berg, Helmut Mach
Abstract: The invention provides promoter polynucleotides that are root-preferred and/or induced by parasitic nematodes. The promoter polynucleotides of the invention are useful for controlling expression of nucleic acids of interest in plant roots.
Abstract: A process for preparing urethane-containing (meth)acrylic esters (U) by reacting a urethane-containing alcohol (A) with a (meth)acrylic ester of a saturated alcohol (G) in the presence of at least one polymerization inhibitor (P) with an enzyme (E) as a catalyst in a reactor, wherein the (meth)acrylic ester of a saturated alcohol (G) and the urethane-containing alcohol (A) are passed continuously through at least one fixed bed reactor filled with an immobilized enzyme (E) as a catalyst.
Abstract: A massive body, e.g., a tablet, for producing a thickened solution of chlorine dioxide when the massive body is added to liquid water is disclosed. The massive body comprises a metal chlorite, an acid source and a thickener (incorporated directly into the massive body or added as a component separate from the massive body) and optionally a source of free halogen. The concentration of free chlorine in the solution will be: (a) less than the concentration of chlorine dioxide in said solution on a weight basis and the ratio of the concentration of chlorine dioxide to the sum of the concentrations of chlorine dioxide and chlorite anion in said solution is at least 0.25:1 by weight; or (b) equal to or greater than the concentration of chlorine dioxide in said solution on a weight basis and the ratio of the concentration of chlorine dioxide to the sum of the concentrations of chlorine dioxide and chlorite anion in said solution is at least 0.50:1 by weight.
Type:
Grant
Filed:
March 5, 2011
Date of Patent:
September 11, 2012
Assignee:
BASF SE
Inventors:
Barry K Speronello, Gerald S. Koermer, Appadurai Thangaraj, Ahmad Moini
Abstract: The present invention relates to a process for the sulfinylation of a pyrazole derivative, characterized in that 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-1H-pyrazole-3-carbonitrile (II) is reacted with a sulfinylating agent selected from trifluoromethylsulfinic acid, trifluoromethylsulfinic acid anhydride, and a trifluoromethylsulfinate alkaline or alkaline earth metal salt and mixtures of the acid and/or the salt(s), in the presence of at least one amine acid complex wherein the amine(s) are selected from tertiary amines and the acid(s) are selected from hydrofluoric, hydrochloric, hydrobromic and hydroiodic acid and sulfonic acid derivatives, and with the addition of a halogenating agent.
Type:
Grant
Filed:
November 5, 2007
Date of Patent:
September 11, 2012
Assignee:
BASF SE
Inventors:
Martin Sukopp, Oliver Kuhn, Carsten Gröning, Michael Keil, Jon J. Longlet
Abstract: The instant invention relates to novel benzotriazole UV-absorbers having a long wavelength shifted absorption spectrum with significant absorbance up to 410-420 nm. Further aspects of the invention are a process for their preparation, a UV stabilized composition containing the new UV-absorbers and the use of the new compounds as UV-light stabilizers for organic materials.
Type:
Grant
Filed:
June 18, 2007
Date of Patent:
September 11, 2012
Assignee:
BASF SE
Inventors:
Katharina Fritzsche, Markus Grob, Adalbert Braig, Ilona Marion Kienzle, Gérard Daniel Georges Vilain
Abstract: The invention relates to methods for producing sulfonamides of formula I, wherein the variables have the designations cited in the description, by reacting m-nitro-benzoic acid chlorides of formula II with aminosulfons of formula III, under the influence of B equivalents of base IV. Said method is characterized in that, during step a) the aminosulfon of formula III is reacted with B1 equivalents of base IV, and during step b), the reaction mixture resulting from step a) is reacted with m-nitro-benzoic acid chlorides of formula II and B2 equivalents of base IV; B, B1 and B2 having the designations cited in the description.
Type:
Grant
Filed:
November 23, 2006
Date of Patent:
September 11, 2012
Assignee:
BASF SE
Inventors:
Thomas Schmidt, Joachim Gebhardt, Sandra Löhr, Michael Keil, Jan Hendrik Wevers, Michael Rack, Guido Mayer, Axel Pleschke
Abstract: The present invention provides a process for producing microcapsules. The microcapsules have an effect-substance-containing capsule core and a polymer-containing capsule covering. The capsule covering is formed by enzyme-catalyzed polymerization of monomers which are present in an inverse miniemulsion, as well as microcapsules and dispersions. The present invention also provides for using the microcapsules and microcapsule dispersions as components in colorants, cosmetics, pharmaceuticals, crop protection agents, fertilizers, and additives for foods or animal feed.
Type:
Grant
Filed:
April 18, 2008
Date of Patent:
September 11, 2012
Assignee:
BASF SE
Inventors:
Rainer Dyllick-Brenzinger, Yvonne Dieckmann, Dietmar Haering, Bernhard Sturm, Michael Schroers, Harald Keller
Abstract: The present invention is directed to compositions comprising a cellulose reactive functionalized polyvinylamine first adduct, compositions comprising combinations of the cellulose reactive functionalized polyvinylamine first adduct and cellulose reactive functionalized polyvinylamide second adduct, methods for preparing first adduct and second adduct blends and finally methods of increasing the wet or dry strength of paper by incorporation into the paper furnish or coating a paper or board with said adducts.
Abstract: The present invention relates to carboxyl-containing polymers having higher storage stability and improved processability in the form of powders, pellets or granules and to their use in laundry detergents and cleaners, and also in further fields of use.
Abstract: The invention relates to foam comprising hollow microbeads and intended for sound absorption, comprising from 40 to 85% by weight of open-cell polymer foam and from 15 to 60% by weight of hollow microbeads with flexible external layer, where the D50 value of the hollow microbeads is at least 70 ?m and at most 250 ?m, based on the total weight of polymer foam and hollow microbeads, and also to a process for producing the same, comprising the following steps: I) impregnation of an open-cell polymer foam with a liquid dispersion comprising expandable hollow microbeads, II) if appropriate, pressing/compression and/or drying of the polymer foam, and Ill) heat-treatment of the impregnated polymer foam at a temperature above the expansion temperature and below the decomposition temperature of the expandable hollow microbeads, for the expansion of the hollow microbeads.
Abstract: The present invention provides a compound of formula The compound of formula (1) is suitable for use as semiconducting material, in particular in electronic devices.
Type:
Application
Filed:
March 5, 2012
Publication date:
September 6, 2012
Applicant:
BASF SE
Inventors:
Helmut Reichelt, Thomas Geßner, Klaus Müllen, Chen Li, Glauco Battagliarin
Abstract: The present invention relates to dye transfer inhibiting polymers in powder, pellet and granule form, having higher storage stability and improved processability and to their application in laundry detergents and cleaners, in textile auxiliaries, and also further applications in cosmetics.
Abstract: The invention relates to a composite element comprising a) a core made of a foam or of a porous material, b) an outer layer applied to the core a), and, c) a foil c) made of a thermoplastic and differing from the outer layer b).
Type:
Application
Filed:
March 2, 2012
Publication date:
September 6, 2012
Applicant:
BASF SE
Inventors:
Markus SCHÜTTE, Frank FECHNER, Manfred GENZ