Abstract: Process for preparing an aqueous polymer dispersion by polymerization of at least one olefinically unsaturated compound in an aqueous medium in the presence of at least one dispersant and a solid polymerization catalyst.
Type:
Grant
Filed:
May 6, 2004
Date of Patent:
December 9, 2008
Assignee:
BASF Aktiengesellschaft
Inventors:
Markus Schmid, Mubarik Mahmood Chowdhry, Peter Preishuber-Pfluegl, Xavier Sava, Ekkehard Lindner, Mahmoud Sunjuk, Peter Wegner
Abstract: The invention relates to a process for preparing polymethylol compounds of the formula (I) where the radicals R are each, independently of one another, a further methylol group or an alkyl group having from 1 to 22 carbon atoms or an aryl or aralkyl group having from 6 to 22 carbon atoms, by condensation of aldehydes having from 2 to 24 carbon atoms with formaldehyde in an aldol reaction using tertiary amines as catalyst to form alkanals of the formula (II) where the radicals R each independently have one of the abovementioned meanings, and subsequent hydrogenation of the latter. The particular inventive feature of this process is that the aldol reaction is carried out using an aqueous formaldehyde solution having a formic acid content of <150 ppm and preferably <100 ppm. In this way of carrying out the process, the formation of by-products can advantageously be prevented in a targeted manner and the yield of the desired polymethylol compound can thereby be increased.
Type:
Grant
Filed:
April 30, 2007
Date of Patent:
December 9, 2008
Assignee:
BASF Aktiengesellschaft
Inventors:
Timan Sirch, Michael Steiniger, Steffen Maas, Stefan Rittinger, Stephan Schlitter, Maria Guixa, Todd C. Spengeman, Jeffrey T. Andress
Abstract: A multimetal oxide of the formula I, Aga-cQbMcV2Od*e H2O,??I where a is from 0.3 to 1.9, Q is an element selected from among P, As, Sb and/or Bi, is from 0 to 0.3, M is a metal selected from among Nb, Ce, W, Mn, Ta, Pd, Pt, Ru and/or Rh, c is from 0.001 to 0.5, with the proviso that (a-c)?0.1, d is a number which is determined by the valence and abundance of the elements other than oxygen in the formula I and e is from 0 to 20, and also precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are described.
Type:
Grant
Filed:
July 23, 2004
Date of Patent:
December 9, 2008
Assignee:
BASF Aktiengesellschaft
Inventors:
Samuel Neto, Hartmut Hibst, Frank Rosowski, Sebastian Storck
Abstract: In a continuous process for fractionating a C4 fraction (C4) by extractive distillation using a selective solvent (LM) in an extractive distillation column (EDK), it is proposed that a dividing wall (TW) is installed in the longitudinal direction in the extractive distillation column (EDK) to form a first region (A), a second region (B) and a lower combined column region (C) and a top stream (C4H10) comprising the butanes is taken off from the first region (A), a top stream (C4H8) comprising the butenes is taken off from the second region (B) and a stream (C4H6) comprising the hydrocarbons from the C4 fraction which are more soluble in the selective solvent (LM) than are the butanes and the butenes is taken off from the lower combined column region (C).
Type:
Grant
Filed:
July 22, 2003
Date of Patent:
December 9, 2008
Assignee:
BASF Aktiengesellschaft
Inventors:
Till Adrian, Thomas Hill, Klaus Kindler, Bernd Heida
Abstract: The present invention relates to a polymer blend membrane comprising a bridged polymer which is produced by a selected process. The membrane of the invention displays a significantly improved fracture toughness (elongation at break/stress) combined with virtually unchanged other properties. The membranes of the invention are suitable for producing membrane-electrode units for fuel cells.
Abstract: Process for recovering (chloro)hydrocarbon-free hydrogen chloride and phosgene-free (chloro)hydrocarbons from a hydrogen chloride stream comprising (chloro)hydrocarbons and phosgene, which comprises i) in a first step, connecting a first adsorber and a second adsorber in series and passing the fresh hydrogen chloride stream comprising phosgene and (chloro)hydrocarbons firstly through the first adsorber and subsequently through the second adsorber until essentially no more (chloro)hydrocarbon is adsorbed by the first adsorber, ii) in a second step, passing the fresh hydrogen chloride stream through the second adsorber while the first adsorber is regenerated, with essentially phosgene-free (chloro)hydrocarbon being obtained in the regeneration, iii) in a third step, passing the fresh hydrogen chloride steam firstly through the second adsorber and subsequently through the regenerated first adsorber until essentially no more (chloro)hydrocarbon is adsorbed by the second adsorber, iv) in a fourth step, passing
Type:
Application
Filed:
January 25, 2007
Publication date:
December 4, 2008
Applicant:
BASF SE
Inventors:
Martin Sesing, Heiner Schelling, Jurgen Ciprian, Filip Deberdt, Martin Karches, Olga Schubert
Abstract: A process for recharging the reaction tubes of a tube bundle reactor with a new fixed catalyst bed, in which a heterogeneously catalyzed partial gas phase oxidation of an organic compound had been performed beforehand in a preceding fixed catalyst bed comprising Mo-comprising multielement oxide active compositions to form a steam-comprising product gas mixture, in which, before the recharge, solid deposit which had been deposited on the tube inner walls and comprises molybdenum oxide and/or molybdenum oxide hydrate is brushed away with the aid of a brush.
Type:
Application
Filed:
May 30, 2008
Publication date:
December 4, 2008
Applicant:
BASF SE
Inventors:
Volker SCHLIEPHAKE, Klaus BOTT, Rolf-Dieter BECHER, Klaus Joachim MULLER-ENGEL, Jochen PETZOLDT, Ulrich CREMER, Andreas RAICHLE
Abstract: Process for preparing multimetal cyanide compounds, which comprises the steps a) reaction of the aqueous solution of a metal salt of the general formula (I) M1gXn ??(I) with the aqueous solution of a cyanometalate compound of the general formula (II) M3r[M2(CN)b]d, , ??(II) if appropriate in the presence of organic ligands, organic additives and/or surface-active agents, to form a multimetal cyanide compound of the general formula (III) M1a[M2(CN)b]d.fM1jXk.h(H2O).eL.
Abstract: A transgenic plant transformed by a Protein Kinase Stress-Related Polypeptide (PKSRP) coding nucleic acid, wherein expression of the nucleic acid sequence in the plant results in increased tolerance to environmental stress as compared to a wild type variety of the plant. Also provided are agricultural products, including seeds, produced by the transgenic plants. Also provided are isolated PKSRPs, and isolated nucleic acid coding PKSRPs, and vectors and host cells containing the latter.
Type:
Application
Filed:
July 9, 2008
Publication date:
December 4, 2008
Applicant:
BASF Plant Science GmbH
Inventors:
Nocha van Thielen, Oswaldo da Costa e Silva, Ruoying Chen
Abstract: A mixed powder or mixed granule comprising at least 80% by weight of a mixture of (a) from 5 to 95% by weight of at least one glutamic acid-N,N-diacetic acid derivative of the general formula (I) MOOC—(CH2)2C(COOM)-N(CH2COOM)2 ??(I) where M is hydrogen, ammonium, alkali metal, (b) from 5 to 95% by weight of at least one polyethylene glycol or of at least one nonionic surfactant or of a mixture thereof or of a polymer selected from the group consisting of polyvinyl alcohols, polyvinylpyrrolidones (PVP), polyalkylene glycols and derivatives thereof, processes for producing these mixed powders or mixed granules, the use of these mixed powders or mixed granules, and a solid laundry detergent and a solid dishwasher detergent comprising the inventive mixed powder or mixed granule are described.
Abstract: The invention relates to a process for producing viscoelastic flexible polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, c) blowing agents, wherein the compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b) comprise b1) from 70 to 10 parts by weight of at least one polyether alcohol consisting of exclusively polyoxypropylene units or polyoxypropylene units and not more than 20% by weight, based on the total weight of the alkylene oxides used, of polyoxyethylene units in the polyether chain and having a nominal functionality of from 3 to 6 and a hydroxyl number in the range from 100 to 300 mg KOH/g, b2) from 10 to 70 parts by weight of at least one polyetherol consisting of exclusively polyoxypropylene units or polyoxypropylene units and not more than 20% by weight, based on the total amount of alkylene oxides used, of polyoxyethylene units in the polyether chain and having
Type:
Application
Filed:
November 30, 2006
Publication date:
December 4, 2008
Applicant:
BASF SE
Inventors:
Stephan Göttke, Heinz-Dieter Lutter, Berend Eling, Steven Edward Wujcik
Abstract: Modified open-cell foams with a density in the range from 5 to 1000 kg/m3 and with an average pore diameter in the range from 1 ?m to 1 mm, comprising an amount in the range from 1 to 2500% by weight based on the weight of the unmodified open-cell foam, of at least one polymer which is solid at room temperature and which contains carboxy groups and/or which contains carboxylic ester groups, and which has a molar mass Mn in the range from 1000 to 1000 000 g/mol.
Type:
Application
Filed:
July 14, 2005
Publication date:
December 4, 2008
Applicant:
BASF Aktiengesellschaft
Inventors:
Andreas Fechtenkotter, Michael Ehle, Stefan Frenzel
Abstract: A process for the fermentative production of at least one organic compound having at least 3 C atoms or having at least 2 C atoms and at least one 1 N atom, comprising the following steps: a1) milling a starch feedstock, thus obtaining a millbase which comprises at least part of the nonstarchy solid constituents of the starch feedstock; a2) suspending the millbase in an aqueous liquid and hydrolysis of the starch portion in the millbase by enzymatic liquefaction and, if appropriate, subsequent saccharification, whereby a first liquid (1) which comprises mono- or oligosaccharides is obtained; and b) addition of the liquid (1) which comprises mono- or oligosaccharides together with metabolizable mono-, di- or oligosaccharides or together with a composition which comprises metabolizable mono-, di- or oligosaccharide in a concentration of at least 50% by weight and which is essentially free from solids which are insoluble in water to a fermentation medium comprising a microorganism which is capable of overproduc
Type:
Application
Filed:
November 27, 2006
Publication date:
December 4, 2008
Applicant:
BASF SE
Inventors:
Markus Pompejus, Stephan Freyer, Markus Lohscheidt, Oskar Zelder, Matthias Boy
Abstract: A process for the production of an optically enriched tertiary alcohol of the formula (2a) or (2b), by reacting an epoxide of the formula (1) with a nucleophilic agent Nu in the presence of halohydrin dehalogenase.
Type:
Application
Filed:
December 13, 2006
Publication date:
December 4, 2008
Applicant:
BASF Aktiengesellschaft
Inventors:
Bernhard Hauer, Dick B. Janssen, Maja Majeric Elenkov
Abstract: The present invention relates to a process for purifying a composition (I) at least comprising cyclododecanone. The process according to the invention for purifying a composition (I) at least comprising cyclododecanone comprises at least step (i) (i) irradiation of the composition (I).
Type:
Application
Filed:
October 6, 2006
Publication date:
December 4, 2008
Applicant:
BASF SE
Inventors:
Rolf Pinkos, Harald Rust, Gerd-Dieter Tebben, Alexander Hauk, Christian Muller
Abstract: The present invention relates to a process for preparation of copolymers A) comprising A1) one or more vinylaromatic monomers, A2) one or more vinyl cyanides, and A3) one or more dicarboxylic anhydrides via bulk polymerization or via solution polymerization, an important feature of the invention being that the polymerization is carried out in the presence of from 0.01 to 0.5% by weight of water, based on the total weight of the polymerization mixture. The present invention further relates to the copolymers A), to thermoplastic molding compositions comprising the copolymers A), to the use of the copolymers A) and of the thermoplastic molding compositions, and also to the moldings, foils, fibers, or foams obtainable from the copolymers A) or from the thermoplastic molding compositions.
Type:
Application
Filed:
November 10, 2006
Publication date:
December 4, 2008
Applicant:
BASF SE
Inventors:
Martin Weber, Peter Ittemann, Axel Gottschalk, Bernd Niedermaier, Birgit Reinhard, Cornelius Eme Koning, Lubertus Klumperman, Maarten Pieter Bram Staal
Abstract: The present invention relates to naphthalenetetracarboxylic acid derivates, to a process for their preparation and to their use, especially as an n-type semiconductor.
Abstract: Use of crosslinked polyvinylpyrrolidone with an average particle size of 5-60 ?m and a hydration capacity of greater than 7 g/g as tablet disintegrant
Type:
Application
Filed:
December 11, 2006
Publication date:
December 4, 2008
Applicant:
BASF SE
Inventors:
Karl Kolter, Bernhard Fussnegger, Michael Kerber, Harald Armbruster, Hubertus Folttmann, Ralf Widmaier, Marianna Pierobon
Abstract: The present invention relates to 7-amino-6-heteroaryl-1,2,4-triazolo[1,5-a]pyrimidine compounds of the formula (I), in which the substituents Het, R1, R2, X and Y are as defined in the claims and in the description.
Type:
Application
Filed:
July 6, 2006
Publication date:
December 4, 2008
Applicant:
BASF Aktiengesellschaft
Inventors:
Oliver Wagner, Sarah Ulmschneider, Udo Hunger