Patent number: 6552026
Abstract: 6-Phenyl-Pyrazolopyrimidines of formula I
wherein
R1 is alkyl, alkenyl, alkynyl, alkadienyl or haloalkyl, cycloalkyl, bicycloalkyl, phenyl, naphthyl, or 5- or 6-membered heterocyclyl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or 5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom,
where these radicals may be unsubstituted or substituted as defined in the specification, Y is oxygen, sulfur, NR2 or a single bond; wherein R2is defined in the specification; and
R1 and R 2 together with the interjacent nitrogen atom may represent a 5- or 6-membered heterocyclic ring, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, which may be substituted by one or more Rc radicals;
m is 0 or an integer from 1 to 4;
L each independently is halogen, nitro, alkyl, alkoxy, and
X is halogen;
processes and intermediates fo
Type:
Grant
Filed:
December 12, 2000
Date of Patent:
April 22, 2003
Assignee:
BASF Aktiengesellschaft
Inventors:
Klaus Jüergen Pees, Jordi Tormo i Blasco, Hubert Sauter, Oliver Cullman, Markus Gewehr, Wassilios Grammenos, Bernd Müller, Thomas Grote, Andreas Gypser, Joachim Rheinheimer, Peter Schäfer, Frank Schieweck, Eberhard Ammermann, Siegried Strathmann, Gisela Lorenz, Rheinhard Stierl
Publication number: 20030066984
Abstract: Improved liquid crystalline materials may be prepared by doping liquid crystalline materials with chiral, uncharged metal compounds of formula [(P1—Y1—A1—Y2—M1—Y3—)nL]2Me or [(P1—Y1—A1—Y2—M1—Y3—)nL]Me(L′(—Y6—M2—Y5—A2—Y4—P2)n′)m. Groups P1 and P2 may be, independently, hydrogen, C1-C12-alkyl groups, polymerizable groups, or radicals containing a polymerizable group. Y1 to Y6 may be, independently, single chemical bonds, ether groups, thio groups, carbonyl groups, acid groups, etc. Groups A1 and A2 are spacers having from 1 to 30 carbon atoms, and M1 and M2 are mesogenic groups. Me may be a transition metal from the fourth, fifth or sixth period of the periodic table, except for technetium, silver, cadmium, gold, mercury, or any of the lanthanoids, or Me may be a main group element from group 14 (IUPAC system), except for carbon and lead.
Type:
Application
Filed:
December 11, 2001
Publication date:
April 10, 2003
Applicant:
BASF AKTIENGESELLSCHAFT
Inventors:
Frank Prechtl, Sylke Haremza, Robert Parker, Kathrin Kurschner, Manfred Braun, Antje Hahn, Ralf Fleischer
Patent number: 6545174
Abstract: 4,4-Diarylbutadienes of the formula I,
where the diene system has the Z,Z; Z,E; E,Z or E,E configuration or a mixture thereof, and where the variables independently of one another have the following meanings: R1 and R2 are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, C1-C12-alkoxy, C1-C20-alkoxycarbonyl, C1-C12-alkylamino, C1-C12-dialkylamino, aryl, hetaryl, unsubstituted or substituted, substituents which confer solubility in water and are selected from the group consisting of carboxylate, sulfonate, or ammonium residues; R3 is COOR5, CONR5R6; R4 is COOR6, CONR5R6; R5 and R6 are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C7-C10-bicycloalkyl, C3-C10-cycloalkenyl, C7-C10-bicycloalkenyl, aryl, hetaryl, unsubstituted or substituted; n is 1 to 3; and R3 and R4 are not COOCH3 when R1 and R2 are hydrogen, are used as photostable UV filters in cosmetic and pharmaceutical preparations to protect the human skin or human hair from the sun's rays,
Type:
Grant
Filed:
January 22, 2001
Date of Patent:
April 8, 2003
Assignee:
BASF Aktiengesellschaft
Inventors:
Thorsten Habeck, Sylke Haremza, Volker Schehlmann, Horst Westenfelder, Thomas Wünsch, Michael Drögemüller, Volker Bomm