Abstract: A dividing wall column system for producing hexane includes a dividing wall column including a dividing wall that divides the dividing wall column at least partially into a first side and a second side, with one side of the first and second sides configured to operate as a deisohexanizer column and the other side of the first and second side configured to operate as a hexane column to produce hexane.

Abstract: An aspect of the present disclosure relates to a process for preparing a composite hydroalkylation catalyst including: (a) effecting impregnation of a hydrogenation metal on an inorganic oxide to form a metal impregnated inorganic oxide; (b) effecting calcination of the metal impregnated inorganic oxide to obtain a calcined metal impregnated inorganic oxide; (c) preparing a composite mixture comprising a molecular sieve, the calcined metal impregnated inorganic oxide and a binder; (d) preparing an extruded catalyst; and (e) effecting calcination of the extruded catalyst to obtain the composite hydroalkylation catalyst. The composite hydroalkylation catalyst prepared using this process affords dramatic improvement in conversion of mononuclear aromatic hydrocarbon and the yield of the hydroalkyled mononuclear aromatic hydrocarbon (e.g. CHB).

Abstract: An aspect of the present disclosure relates to a process for solvent deasphalting dearomatization, said process including: effecting deasphaltenation of a heavy oil feed by contacting the feed with a paraffinic rich solvent, optionally, in presence of a FCC catalyst to obtain a deasphalted oil rich stream, said paraffinic rich solvent being untreated naphtha; contacting the DAO rich stream with a second solvent to obtain a raffinate stream rich in non-asphaltene and non-aromatic contents and a solvent rich stream; contacting the raffinate stream with water in a first decanter to obtain a first stream rich in aromatic-lean fraction and a second stream rich in the second solvent and water; subjecting the first stream to distillation to recover the paraffinic rich solvent and to obtain deasphalted oil; contacting the solvent rich stream with water in a second decanter to obtain an aromatic rich fraction and a third stream rich in the second solvent and water; and subjecting the second stream and the third stream

Abstract: The present invention relates to an advanced process control system (APC) for a continuous catalytic regeneration reformer with master-slave configuration to control coke on spent catalyst while maximizing heavy reformate octane barrel using online inferential, both for coke content of spent catalyst and octane of heavy reformate. Further, the present invention relates to provide an APC system for a continuous catalytic regeneration reformer with master-slave configuration, which comprises of a master APC, a reactor APC, and a regenerator APC, wherein, the reactor APC and the regenerator APC are linked to the master APC.

Abstract: In accordance with the present subject matter there is provided a process for producing mono-, di- and triesters of glycerol over a catalyst composition. The catalyst composition including a base catalyst and a support material based on phyllosilicates of montmorillonite structure and the process for preparing the catalyst composition is also described.

Abstract: The present disclosure provides a fuel composition for improving the lubricity property. Further provided is a process for preparation of the composition.

Abstract: The present invention relates to an advanced process control system (APC) for a continuous catalytic regeneration reformer with master-slave configuration to control coke on spent catalyst while maximizing heavy reformate octane barrel using online inferential, both for coke content of spent catalyst and octane of heavy reformate. Further, the present invention relates to provide an APC system for a continuous catalytic regeneration reformer with master-slave configuration, which comprises of a master APC, a reactor APC, and a regenerator APC, wherein, the reactor APC and the regenerator APC are linked to the master APC.

Abstract: The present invention provides a process for preparing a zeolite by hydrothermal heating of silica precursor and alumina precursor along with a combination of two structure-directing organic templates, N,N-dimethyl formamide and 1,6-diaminohexane in the presence of an alkali. The use of two structure-directing organic templates, not only reduces the crystallization time but also enables the preparation of more catalytically active ZSM-22 of submicron crystallite size. The present invention also provides a process of preparing a noble metal containing zeolite catalyst for hydroisomerization of long chain n-paraffins.

Abstract: The present invention provides a process for in-situ preparation of metal oxide(s) comprising the step of precipitating a metal salt solution with Fehling's reagent B and glucose at a suitable temperature. The metal oxide(s) prepared according to the present invention can be used for diverse applications including their utility as catalyst(s) in one or more reactions. The present invention further provides a highly selective bi-functional hybrid catalyst for direct conversion of syn-gas to dimethyl ether (DME) and methods of preparation thereof. The one or more metal oxide(s) can be directly obtained from the metal precursors following the method(s) of the present invention instead of metal hydroxides as in conventional known methods, thereby eliminating the necessity of high temperature calcination step(s) and rigorous reduction procedure(s).

Abstract: A method for inhibiting corrosion on internal metal surfaces of an overhead condenser of a crude distillation unit in which hydrocarbons, water and amine hydrochlorides condense, the method includes adding to the overhead condenser an amine composition in an amount and at a rate sufficient to maintain the pH of water condensate in the condenser above a pH of about 5, the amine composition made of a mixture of four amines wherein the amines are monoethanloamine, methoxypropyl amine, morpholine and cyclohexylamine present in a weight ratio ranging from about 25:30:25:20 to about 30:40:15:15. Further, a system and method assess the corrosion rate and optimize the dosage of neutralizing amine composition during the operating conditions of overhead condensing system.

Abstract: The present disclosure provides methods and apparatus for catalytic cracking of hydrocarbon feed. The apparatus includes a plurality of stages, wherein hydrocarbon feed is introduced into a bottom stage reactor and flows in an overall upward direction. A reaction catalyst stream is introduced into a top stage reactor and flows in an overall downward direction. In each of the stages, the hydrocarbon feed is allowed to come in contact with the reaction catalyst stream received at the particular stage for cracking of the hydrocarbon feed. The final cracked product stream is obtained at an outlet of the top stage reactor and a final spent catalyst stream is obtained at an outlet of the bottom stage reactor.

Abstract: Methods and systems for predicting crude oil blend compatibility and optimizing blends for increasing heavy crude oil processing are described. The method includes receiving ratios of physical parameters of crude oils for optimization of crude oil blend. The physical parameter ratios are based on Kinematic Viscosity (V), Sulphur (S), Carbon Residue (C), and American Petroleum Institute (API) gravity. The crude oil blend compatibility (K model) is determined and generated using the physical parameter ratios. The K model is developed by coefficients obtained by regression analysis between the ratios of physical parameters of known crude oils and composite compatibility measure determined from multiple compatibility test results of the known crude oils. The predicted crude oil blend compatibility can be used for optimizing heavy crude oil processing.

Abstract: The present invention provides a process for preparing a zeolite by hydrothermal heating of silica precursor and alumina precursor along with a combination of two structure-directing organic templates, N,N-dimethyl formamide and 1,6-diaminohexane in the presence of an alkali. The use of two structure-directing organic templates, not only reduces the crystallization time but also enables the preparation of more catalytically active ZSM-22 of submicron crystallite size. The present invention also provides a process of preparing a noble metal containing zeolite catalyst for hydroisomerization of long chain n-paraffins.

Abstract: Provided is a method for predicting kinematic viscosity of a fraction of a crude oil to optimize selection of crude oils. The method includes receiving parameters of the crude oil, such as Vacuum Residue yield and Conradson Carbon Residue (CCR), content as an input. The method also includes determining kinematic viscosity of the fraction of the crude oil at a first predetermined temperature based on a first correlation model between the physical parameters of the crude oil and the kinematic viscosity at the first predetermined temperature. The method further includes generating the kinematic viscosity of the fraction of the crude oil at the predetermined temperature based on the first correlation model corresponding to the input. Also provided is a system for predicting kinematic viscosity at a predetermined temperature to optimize crude oil selection. Further provided is a method for estimating an amount of cutter stock for crude oil processing.

Abstract: A method for modification of pretreated acidic porous material via selective cation exchange using suitable solvent to obtain higher noble metal dispersion is described herein. The solvent system required for cation exchange should have its dielectric constant in the range of 25-45, wherein this solvent property is found to impart significant effect on cation loading and distribution, which in turn defines the stability, dispersion of the noble metals. The catalyst so obtained has higher noble metal dispersion and when used for hydroisomerization reaction, leads to higher selectivity even at significantly high conversion values.

Abstract: The present invention relates to a process for co-gasification of two or more carbonaceous feedstock, said process comprising combusting a first carbonaceous feedstock having high calorific value with low ash and high hydrogen content, to produce a heated effluent; carrying the heated effluent to second reactor where the heated effluent reacts with a second carbonaceous feedstock, having low calorific value with high ash and low hydrogen content, to produce synthesis gas.

Abstract: Methods, apparatus and processes for three phase contacting and reactions in a cross flow reactor with reduced feed vaporization, low pressure operation, higher liquid holdup, lower reactor pressure drop, low severity operation, and reduced product inhibitory effects. A cross flow reactor for three phase catalytic hydroprocessing, having at least one reactor stage is disclosed. The reactor stage has a central gas distributor with perforated lateral surface for distributing gas, a middle region accommodating a packed catalyst bed, and an outer gas space for removal of effluent gases from the middle region. The middle region receives a liquid reactant and gas from central gas distributor to carry out three phase catalytic hydroprocessing reaction.

Abstract: Method(s) and a system for predicting the refining characteristics of an oil sample are described. The method of predicting the refining characteristics, such as distillate yield profile, processability, product quality or refinery processing cost, may include development of a prediction model based on regression analysis. The method may further include determining the physical properties of the oil sample and predicting the refining characteristics based on the developed prediction model. The determination of the physical properties of the oil sample includes determining at least one of Conradson Carbon Residue (CCR) content, Ramsbottom Carbon Residue (RCR) and Micro Carbon Residue (MCR).

Abstract: A method for inhibiting corrosion on internal metal surfaces of an overhead condenser of a crude distillation unit in which hydrocarbons, water and amine hydrochlorides condense, the method includes adding to the overhead condenser an amine composition in an amount and at a rate sufficient to maintain the pH of water condensate in the condenser above a pH of about 5, the amine composition made of a mixture of four amines wherein the amines are monoethanloamine, methoxypropyl amine, morpholine and cyclohexylamine present in a weight ratio ranging from about 25:30:25:20 to about 30:40:15:15. Further, a system and method assess the corrosion rate and optimize the dosage of neutralizing amine composition during the operating conditions of overhead condensing system.

Abstract: Provided is a method for predicting kinematic viscosity of a fraction of a crude oil to optimize selection of crude oils. The method includes receiving parameters of the crude oil, such as Vacuum Residue yield and Conradson Carbon Residue (CCR), content as an input. The method also includes determining kinematic viscosity of the fraction of the crude oil at a first predetermined temperature based on a first correlation model between the physical parameters of the crude oil and the kinematic viscosity at the first predetermined temperature. The method further includes generating the kinematic viscosity of the fraction of the crude oil at the predetermined temperature based on the first correlation model corresponding to the input. Also provided is a system for predicting kinematic viscosity at a predetermined temperature to optimize crude oil selection. Further provided is a method for estimating an amount of cutter stock for crude oil processing.