Patents Assigned to Bio-Tec Biologische Naturverpackungen GmbH & Co. KG
  • Patent number: 11358378
    Abstract: A multi-layer polymer film comprising at least one middle layer A, the polymeric constituents of which are soluble in aqueous solution, and in each case at least one substantially water-impermeable covering layer B, C arranged above and below the at least one middle layer A, wherein the layers A, B and C independently of each other in each case comprise at least one thermoplastic polymer and at least one of the covering layers B and C comprises at least one polyhydroxyalkanoate is presented and described. Processes for the production of the multi-layer polymer film according to the invention and its use for the production of molded parts, films or bags are furthermore presented and described.
    Type: Grant
    Filed: November 19, 2015
    Date of Patent: June 14, 2022
    Assignee: BIO-TEC BIOLOGISCHE NATURVERPACKUNGEN GMBH & CO. KG.
    Inventors: Ralf Hackfort, Johannes Mathar, Frank Rörthmans, Harald Schmidt, Christoph Hess
  • Patent number: 11235497
    Abstract: A process is presented and described for the production of moldings, comprising the steps of (a) providing a polymer composition comprising from 1 to 99% by weight of polyhydroxyalkanoate and from 1 to 99% by weight of starch-containing polymer; (b) homogenizing the polymer composition with use of thermal and/or mechanical energy; (c) introducing the polymer composition into a mold; (d) molding the molding in the mold; and (e) removing the molding from the mold. The process described is in particular suitable for the production of hard capsules.
    Type: Grant
    Filed: December 23, 2015
    Date of Patent: February 1, 2022
    Assignee: BIO-TEC BIOLOGISCHE NATURVERPACKUNGEN GMBH, & CO. KG
    Inventors: Harald Schmidt, Christoph Hess, Wolfgang Friedek
  • Patent number: 11208551
    Abstract: A polymer composition is presented and described and includes, based on the total weight of the polymer composition, the following components: a. from 15 to 70% by weight of PLLA, b. from 0.1 to 15% by weight of PDLA, c. from 5 to 40% by weight of polyester, and d. from 5 to 40% by weight of organic or inorganic filler. These polymer compositions can be biodegradable, comprise mainly bio-based carbon, and have an increased heat deflection temperature. These polymer compositions can moreover be used in specific processes in order to produce molded parts, films, or fibers which by virtue of their high heat deflection temperature can also be used as containers for coffee-preparation systems.
    Type: Grant
    Filed: February 2, 2015
    Date of Patent: December 28, 2021
    Assignee: BIO-TEC BIOLOGISCHE NATURVERPACKUNGEN GMBH & CO. KG
    Inventors: Harald Schmidt, Christoph Hess, Wolfgang Friedek, Ralph Beckmann
  • Patent number: 10131783
    Abstract: The invention relates to a polymer compound which, based on the total weight of the polymer compound, comprises at least the following components: (a) 5 to 50 wgt.-% destructed starch and/or starch derivative, (b) 20 to 70 wgt.-% aliphatic-aromatic copolymer, (c) 10 to 50 wgt.-% polyhydroxyalkanoate and (d) 3 to 25 wgt.-% polyactic acid. Such polymer compounds are characterized by a high ratio of bio-based carbon and exhibit no significant embrittlement or worsening of the mechanical properties profile, despite the presence of increased volumes of polyhydroxyalkanoate, even after storage. The invention further relates to production methods for the polymer compound according to the invention, and use thereof in the production of films, molded parts or fibers.
    Type: Grant
    Filed: April 8, 2014
    Date of Patent: November 20, 2018
    Assignee: BIO-TEC BIOLOGISCHE NATURVERPACKUNGEN GMBH & CO. KG
    Inventors: Harald Schmidt, Christoph Hess, Christophe Bréso, Ralf Hackfort, Frank Rörthmans, Wolfgang Friedek
  • Patent number: 7344784
    Abstract: Fibrous sheets are coated or impregnated with a biodegradable composition to render the sheets more resistant to penetration by liquids. Biodegradable polymer blends suitable for use in coating or impregnating a fibrous sheet can be manufactured from at least one type of polyhydroxybutyrate, optionally in combination with at least one additional biodegradable polymer (e.g., a “hard” biodegradable polymer having a glass transition temperature of at least about 10° C. and/or a “soft” biodegradable polymer having a glass transition temperature less than about 0° C. Sufficient inorganic filler may be included so as to render the treated sheet microwaveable. The biodegradable polymer compositions are especially well-suited for coating or impregnating paper sheets, e.g., 12-15 lb/3000 ft2 tissue paper to yield food wraps. Food wraps will typically be manufactured to have good “dead-fold” properties so as to remain in a wrapped position and not spring back to an “unwrapped” form.
    Type: Grant
    Filed: June 20, 2006
    Date of Patent: March 18, 2008
    Assignee: bio-tec Biologische Naturverpackungen GmbH & Co., KG.
    Inventor: Simon K. Hodson
  • Patent number: 7297394
    Abstract: Biodegradable polymer blends suitable for laminate coatings, wraps and other packaging materials are manufactured from at least one “hard” biopolymer and at least one “soft” biopolymer. “Hard” biopolymers tend to be more brittle and rigid and typically have a glass transition temperature greater than about 10° C. “Soft” biopolymers tend to be more flexible and pliable and typically have a glass transition temperature less than about 0° C. While hard and soft polymers each possess certain intrinsic benefits, certain blends of hard and soft polymers have been discovered which possess synergistic properties superior to those of either hard or soft polymers by themselves. Biodegradable polymers include polyesters, polyesteramides, polyesterurethanes, thermoplastic starch, and other natural polymers. The polymer blends may optionally include an inorganic filler. Films and sheets made from the polymer blends may be textured so as to increase the bulk hand feel.
    Type: Grant
    Filed: March 1, 2002
    Date of Patent: November 20, 2007
    Assignee: bio-tec Biologische Naturverpackungen GmbH & Co. KG
    Inventors: Kishan Khemani, Harald Schmidt, Simon K. Hodson
  • Patent number: 7241832
    Abstract: Biodegradable polymer blends suitable for laminate coatings, wraps and other packaging materials are manufactured from at least one “hard” biopolymer and at least one “soft” biopolymer. “Hard” biopolymers tend to be more brittle and rigid and typically have a glass transition temperature greater than about 10° C. “Soft” biopolymers tend to be more flexible and pliable and typically have a glass transition temperature less than about 0° C. While hard and soft polymers each possess certain intrinsic benefits, certain blends of hard and soft polymers have been discovered which possess synergistic properties superior to those of either hard or soft polymers by themselves. Biodegradable polymers include polyesters, polyesteramides, polyesterurethanes, thermoplastic starch, and other natural polymers. The polymer blends may optionally include an inorganic filler. Films and sheets made from the polymer blends may be textured so as to increase the bulk hand feel.
    Type: Grant
    Filed: March 1, 2002
    Date of Patent: July 10, 2007
    Assignee: bio-tec Biologische Naturverpackungen GmbH & Co., KG
    Inventors: Kishan Khemani, Harald Schmidt, Simon K. Hodson
  • Publication number: 20060240726
    Abstract: Fibrous sheets are coated or impregnated with a biodegradable composition to render the sheets more resistant to penetration by liquids. Biodegradable polymer blends suitable for use in coating or impregnating a fibrous sheet can be manufactured from at least one type of polyhydroxybutyrate, optionally in combination with at least one additional biodegradable polymer (e.g., a “hard” biodegradable polymer having a glass transition temperature of at least about 10° C. and/or a “soft” biodegradable polymer having a glass transition temperature less than about 0° C. Sufficient inorganic filler may be included so as to render the treated sheet microwaveable. The biodegradable polymer compositions are especially well-suited for coating or impregnating paper sheets, e.g., 12-15 lb/3000 ft2 tissue paper to yield food wraps. Food wraps will typically be manufactured to have good “dead-fold” properties so as to remain in a wrapped position and not spring back to an “unwrapped” form.
    Type: Application
    Filed: June 20, 2006
    Publication date: October 26, 2006
    Applicant: bio-tec Biologische Naturverpackungen GmbH & Co., KG.
    Inventor: Simon Hodson
  • Patent number: 6214907
    Abstract: A biologically degradable polymer mixture is proposed which consists essentially of starch and at least one hydrophobic polymer. The hydrophobic polymer is in this connection at least substantially biologically degradable and thermoplastically processable and the mixture with the starch comprising a polymer phase mediator or a macromolecular dispersing agent so that the starch is present in the mixture as disperse phase with the hydrophobic polymer as continuous phase, and the phase mediator or the dispersing agent is responsible for the molecular coupling of the two phases. As starch there is preferably used thermoplastic starch which has been prepared substantially with the exclusion of water by means of sorbitol or glycerol. The production of the biologically degradable polymer mixture is also carried out substantially with the exclusion of water.
    Type: Grant
    Filed: September 16, 1998
    Date of Patent: April 10, 2001
    Assignee: Bio-Tec Biologische Naturverpackungen GmbH & Co. KG
    Inventor: Ivan Tomka
  • Patent number: 6117925
    Abstract: The present invention relates to thermoplastically processible esterification or transesterification products of starch or of starch derivatives with, for example, lactones, fatty acids, esteramides and the like, wherein the starch or the starch derivative is brought to melt using appropriate softeners or plasticizers before esterification or transesterification.
    Type: Grant
    Filed: February 25, 1999
    Date of Patent: September 12, 2000
    Assignee: Bio-Tec Biologische Naturverpackungen GmbH & Co. KG
    Inventor: Ivan Tomka
  • Patent number: 6096809
    Abstract: A biologically degradable polymer mixture contains at least one starch biopolymer made from renewable raw materials, a plasticizer, and a polymer selected from the following materials: an aromatic polyester; a polyester-copolymer with both aliphatic and aromatic blocks; a polyesteramide; a polyglycol; a polyester urethane; and/or mixtures of these components.
    Type: Grant
    Filed: December 15, 1997
    Date of Patent: August 1, 2000
    Assignee: Bio-Tec Biologische Naturverpackungen GmbH & Co. KG
    Inventors: Jurgen Lorcks, Winfried Pommeranz, Harald Schmidt