Abstract: A process, formula and apparatus for the treatment and sterilization of biological, solid, liquid, ferrous metallic, non-ferrous metallic, toxic and hospital dangerous waste or residual material utilizes a mixture of oxygen, ozone, water, and optionally, carbon dioxide, in variable proportions and rates. The apparatus comprises an oxygen container (10) and a carbon dioxide container (11) from which the oxygen and the carbon dioxide are incorporated through respective conduits (13) and (15) to an ozonizer (1) provided with cooling water inlet (16) and outlet (17). The conduits (13) and (15) exit adjacent to the ozone conduit (14), up to the injector (3), and are actuated by the pump (2) and pass through the mixing conduit (4) to the absorption and outgassing tank (5) from which the conduit (6) for the washing fluid passes to the treatment tank (7) having a degasification valve (12) or catalyst.