Patents Assigned to BK Giulini Chemie GmbH & Co.
  • Patent number: 6352587
    Abstract: A process for coloring an unglazed ceramic with an aqueous colorant solution containing a chromium (III) coordination compound which is at least partially neutralized and stable, including (a) dissolving a carboxylic acid selected from the group consisting of acetic acid, an organic dicarboxylic acid having a general formula (COOH)—(CH2)n—(COOH), where n ranges from 0 to 10, and an unsaturated, organic dicarboxylic acid in water at a temperature ranging from 40 to 60° C. to provide an aqueous solution of a carboxylic acid; (b) adding a chromium (III) compound to the aqueous solution of a carboxylic acid while stirring for a time and at a temperature effective for reaction to form an aqueous solution containing a chromium (III) coordination compound; (c) filtering the aqueous solution containing the chromium (III) coordination compound to provide a filtered aqueous solution; and (d) adjusting pH of the filtered aqueous solution to a pH ranging from 3 to 6.
    Type: Grant
    Filed: June 1, 1999
    Date of Patent: March 5, 2002
    Assignee: BK Giulini Chemie GmbH & Co. OHG
    Inventors: Thomas Staffel, Jürgen Straub, Thomas Klein
  • Patent number: 6268465
    Abstract: An aliphatic polyester amide which is hydrolysis-resistant includes a ternary polycondensation product of monomeric constituents composed of a monomeric constituent A which is at least one diol having a general formula: HO—R1—OH, where R1 is an aliphatic residue having 2-16 carbon atoms; a monomeric constituent B which is at least one dicarboxylic acid having a general formula: HOOC—R2—COOH, where R2 is an aliphatic residue having 1-14 carbon atoms; and a monomeric constituent C which is at least one diamine having a general formula: H2N—R3—NH2, where R3 is an aliphatic residue having 2-16 carbon atoms and is present in an amount of up to about 5% by weight based on total weight of the monomeric constituents, wherein polycondensation proceeds in the presence of a catalyst comprised of constituent D, which is a metal-containing catalyst, in combination with constituent E, which is at least one of an organic phosphorus compound and an inorganic phosphorus compound, and wherei
    Type: Grant
    Filed: April 12, 1999
    Date of Patent: July 31, 2001
    Assignee: BK Giulini Chemie GmbH Co OHG
    Inventors: Gudrun Chomiakow, Hasan Ulubay, Emil Wilding
  • Patent number: 6114054
    Abstract: A method for coloring a surface of a ceramic mass to produce a colored ceramic body includes providing a host lattice material composed of a colorless metal oxide compound which crystallizes into one of a spinel lattice or a rutile lattice and which may be water soluble; providing an aqueous coloring solution containing water; a first water soluble compound including a metal ion which is one of a two-valent metal ion or a three-valent metal ion and which colors the host lattice material; and a second water soluble compound including a metal ion which is one of a five-valent metal ion or six-valent metal ion and which provides electrostatic balance; generating a mixed-phase pigment in the surface of the ceramic mass by one of (i.) working a fine powder of the colorless metal oxide into the ceramic mass and applying the aqueous coloring solution onto at least one surface of the ceramic mass, or (i.i.
    Type: Grant
    Filed: December 15, 1998
    Date of Patent: September 5, 2000
    Assignee: BK Giulini Chemie GmbH & Co.
    Inventors: Thomas Klein, Thomas Staffel, Jurgen Straub, Lysander Fischer
  • Patent number: 6045859
    Abstract: The present invention relates to a method for coloring ceramic surfaces, wherein the surfaces are treated with an aqueous solution of alkali metal or ammonium dithiosulphatoaurate(I) with a gold concentration of 0.1-10% by weight, the water is evaporated and the dithiosulphatoaurate(I) is decomposed at temperatures of 300-1400.degree. C.
    Type: Grant
    Filed: November 12, 1998
    Date of Patent: April 4, 2000
    Assignee: BK Giulini Chemie GmbH & Co. OHG
    Inventors: Thomas Klein, Thomas Staffel, Lysander Fischer, Richard Walter, Peter Patzelt