Abstract: This disclosure includes high-temperature, thermally-insulative laminates, Some laminates have a front surface, a back surface, one or more heat-dispersing layers, each comprising at least 90% by weight of: a metal having a melting point of at least 1,300° C. and a thermal conductivity of at least 15 W/Km; or graphite, and one or more heat-insulating layers coupled to the heat-dispersing layer(s), the heat-insulating layer(s) each including a layer of polymeric aerogel, wherein at least a majority of the front surface is defined by one of the heat-dispersing layer(s).

Abstract: An aerogel article that includes a plurality of aerogel particles is disclosed. The plurality of aerogel particles each include a polymeric matrix defining pores of the plurality of aerogel particles. The polymeric matrix includes a non-consolidated portion comprising the pores and a consolidated portion plasticized by a plasticizing solvent. The plurality of aerogel particles are bonded to each other through an interface that comprises the consolidated portions of adjacent ones of the plurality of aerogel particles.

Abstract: A macroporous-structured polymeric aerogel, and methods for making and using the same, having a polymeric matrix that includes macropores is disclosed.

Abstract: An organic polymer aerogel that includes an organic polymer gel matrix and microstructures dispersed or embedded within the aerogel is disclosed. The aerogel can have an at least bimodal pore size distribution comprising a first peak of less than or equal to 65 nm and a second peak greater than or equal to 100 nm.

Abstract: An aerogel that includes an open-cell structure and a polymer matrix is disclosed. The polymer matrix can include a branched polyimide polymer having a degree of branching of at least 0.5. The polymer matrix can contain less than 5% by weight of crosslinked polymers.

Abstract: A laminate comprises one or more electrically-conductive layers and one or more electrically-insulative layers coupled to the electrically-conductive layer(s). Each of the electrically-conductive layer(s) can comprise at least 90% by weight of copper. Each of the electrically-insulative layer(s) can comprise a layer of polymeric aerogel. For at least one of opposing front and back surfaces of the laminate, at least a portion of the surface is defined by one of the electrically-conductive layer(s).

Abstract: A reinforced polymeric aerogel composite is disclosed. The composite can include a first portion comprising a polymeric aerogel, and a second portion comprising a fiber support, wherein fibers in the fiber support comprise a mineral or a polymer, wherein the first portion is in direct contact with the fibers of the second portion; and wherein the composite has a thickness of 1.5 to 15 mils thick.

Abstract: A thermally treated open-cell structured polymeric material comprising a polyamic amide containing polymer is disclosed. The polyamic amid containing polymer can have a repeating structural unit of: where X is a first organic group having at least two carbon atoms, Y is a second organic group having at least two carbon atoms, Z and Z? are each independently a hydroxyl group or a nitrogen containing hydrocarbon compound comprising at least one secondary nitrogen with the proviso that that at least one of Z or Z? is the nitrogen containing hydrocarbon compound comprising at least one secondary nitrogen, and m and n are average number of repeat units per chain ranging from 1 to 2000.

Abstract: A laminate having thermal-protection and flame-retardant properties is disclosed. The laminate can include a flame-retardant layer and an aerogel layer, wherein the laminate has opposing front and back surfaces, the flame-retardant layer defines at least a majority of the front surface, and a thickness of the laminate is less than or equal to 25.4 millimeters (mm).

Abstract: Aerogel filled polymeric composites, methods of making and uses thereof are described. A polymeric composite material can include a continuous polymeric matrix and a discontinuous phase that includes a plurality of polymeric aerogel particles dispersed within the continuous polymeric matrix.

Abstract: Thermally treated aerogel compositions that include polyamic amides in an amount less than the aerogel compositions that include polyamic amides prior to thermal treatment, and articles of manufacture that include or are manufactured from the aerogel compositions are described.

Abstract: A laminate can include one or more thermally-insulative layers, each having a thermal conductivity that is less than or equal to 0.05 W/m·K, wherein the laminate has a thickness that is less than or equal to 500 ?m and a thermal diffusivity that is less than or equal to 0.10 mm2/s. The laminate can include an adhesive layer, wherein aback surface of the laminate is at least partially defined by the adhesive layer or a liner layer that is removably disposed on the adhesive layer. The laminate can include a protective layer that defines at least a portion of a front surface of the laminate, wherein the protective layer has a thermal conductivity that is at least 3.5 times the thermal conductivity of each of the thermally-insulative layer(s).

Abstract: A fiber-reinforced aerogel is disclosed. The aerogel can include a porous organic polymer matrix and fibers included in the porous organic polymer matrix. The aerogel can include a thermal conductivity of less than or equal to 60 mWIm·K at a temperature of 20° C., at least a bimodal pore size distribution with a first mode of pores having an average pore size of less than or equal to 50 nanometers (nm) and a second mode of pores having an average pore size of greater than 50 nm, and a planar shape having a thickness of 5 millimeters (mm) or less and is capable of being rolled up into a roll, wherein the fibers form a woven fiber matrix.

Abstract: An aerogel that includes an open-cell structured polymer matrix is disclosed. The aerogel includes 5 wt. % to 50 wt. % of a polyamic amide polymer, based on the total weight of the aerogel, pores and at least 90% of the pore volume of the aerogel is made up of macropores, a porosity of at least 50%, as measure according to ASTM D4404-10, a density of 0.01 g/cm3 to 0.5 g/cm3, and the aerogel is thermally stable to resist browning at 330° C.

Abstract: A macroporous-structured polymeric aerogel, and methods for making and using the same, having a polymeric matrix that includes macropores is disclosed.

Abstract: A composite comprising a non-fibrous organic polymer aerogel layer having a first surface and an opposing second surface and a support layer having a first surface and an opposing second surface is disclosed. An interface can be formed between a portion of the first surface of the aerogel layer and a portion of the second surface of the support layer such that the aerogel and support layers are attached to one another. A majority of the volume of the aerogel layer does not have to include the support layer. The composite can have a thickness of 3 mils to 16 mils.

Abstract: Thermally treated aerogel compositions that include polyamic amides in an amount less than the aerogel compositions that include polyamic amides prior to thermal treatment, and articles of manufacture that include or are manufactured from the aerogel compositions are described.

Abstract: An organic polymer aerogel that includes an organic polymer gel matrix and microstructures dispersed or embedded within the aerogel is disclosed. The aerogel can have an at least bimodal pore size distribution comprising a first peak of less than or equal to 65 nm and a second peak greater than or equal to 100 nm.

Abstract: This disclosure includes aerogel articles made from aerogel particles and methods for making the same. Some methods include disposing a composition into a mold, the composition having aerogel particles, each including a polymeric matrix defining pores of the aerogel particle, and a plasticizing solvent and/or an adhesive, and forming the aerogel article at least by applying pressure to the composition disposed within the mold.

Abstract: Aerogel compositions, methods for preparing the aerogel compositions, articles of manufacture that include or are made from the aerogel compositions are described and uses thereof. The aerogels include a branched polyimide matrix with little to no crosslinked polymers.