Abstract: Epoxy resins which are diglycidyl ethers of tetrabromobisphenol A having a crystalline structure and in particulate form have an epoxy equivalent weight between 320 and 380 g/eq and a chlorine content that is smaller than 0.3%.
Abstract: A process for the preparation of p-fluorophenol, which comprises hydrolyzing p-bromofluorobenzene with a mixture of NaOH and Na.sub.2 CO.sub.3 in the presence of a copper catalyst.
Abstract: A process for the preparation of thermally stable polymers of the formula I: ##STR1## wherein n+m=1 through 5, and x denotes the degree of polymerization, comprises polymerizing monomers of the formula Ia: ##STR2## wherein n+m=1 through 5, in a non-protic solvent.
Abstract: Process for the production of p-bromofluorobenzene by the bromination of fluorobenzene, characterized in that the bromination is carried out with liquid bromine at temperatures below 0.degree. C.
Abstract: A process for the preparation of octyl p-methoxy cinnamate is provided. The procedure generally concerns reacting p-bromo anisole with acrylic acid; and esterifying the resulting product with 2-ethyl hexanol. Preferred reactants and conditions are provided.
Abstract: A brominated epoxy oligomer of the formula ##STR1## having a molecular weight of least 3,000, useful as a flame retardant additive for polypropylene and ethylene propylene copolymers is described.
Abstract: A process for the preparation of 5-hydroxyisophthalic acid (5-HIPA) that comprises hydrolyzing a starting material chosen from among 5-bromoisophthalic acid (5-BIPA), mixtures of 5-BIPA and dibromoisophthalic acid isomers, and salts of thereof in an aqueous alkaline solution, in the presence of a catalytically effective amount of a copper compound catalyst and in a temperature range of between 100.degree. and 270.degree. C.
Type:
Grant
Filed:
March 26, 1996
Date of Patent:
December 30, 1997
Assignee:
Bromine Compounds Ltd.
Inventors:
Mark Gelmont, Joseph Bercovici, Jakob Oren
Abstract: A method for the production of finely particulate solid chemical products from a molten stock comprises the steps of: (a) feeding the product, as molten stock, to an elongated treatment space, sealed from the ambient; (b) causing the product to flow as a flowable mass within space, while leaving a free portion of said space above the surface of said mass; (c) maintaining in said space an atmosphere that is non-reactive with said product; (d) subjecting said product to a stirring and mixing action by rotary means; (e) concurrently cooling said product as it proceeds along said space, whereby to solidify it; (f) concurrently detaching any product that adheres to surfaces within said space; and (g) discharging the solidified product, in the form of solid particles, from said elongated treatment space.
Type:
Grant
Filed:
April 30, 1996
Date of Patent:
December 16, 1997
Assignee:
Bromine Compounds, Ltd.
Inventors:
Avi Prager, Moti Veinberg, Baruch Grinbaum, Yehuda Keren, Rafael Shemer, Iulio Bitherfeld, Leonid Zaslavsky
Abstract: Novel fire retardant compounds are disclosed, which are poly-halogenated TMPI and MPI compounds containing three or more halogen atoms per molecule. A process for the preparation of these compounds and polymeric compositions containing them are also described.
Type:
Grant
Filed:
May 18, 1995
Date of Patent:
December 9, 1997
Assignee:
Bromine Compounds, Ltd.
Inventors:
Leonard Shorr, Antebi Salomone, Theodor-Morel Fishler, Michael Eroshov, Ita Finberg
Abstract: A composition comprising A) an aqueous solution wherein the total content of 3-isothiazolinones is below 8 wt/%, and B) a stabilizing compound of the formula:[R.sub.x A--C.sub.6 H.sub.2 R.sup.1 R.sup.2 ].sub.y --Zwherein:R, R.sup.1 and R.sup.2 each independently represents hydrogen, a straight-chained or branched or cyclic alkyl radical, aralkyl or aryl;A is oxygen or nitrogen;Z represents AR.sub.x, R.sup.1, R.sup.2, alkoxy methylene, methylene or alkylidene;provided that when A is oxygen, x is 0 or 1 and when A is nitrogen, x is 1 or 2; and y is 1 or 2;exhibits improved stability.
Abstract: A method of improving the surface compatibility properties of polypropylene comprises thermo-processing polypropylene together with at least one aromatic ring-polybrominated olefinic compound, in the absence of free radical initiators.
Abstract: Compounds of the formula: ##STR1## wherein: n=0 or 1;R.sub.1 and R.sub.2 are C.sub.1 to C.sub.3 alkyl groups, or R.sub.2 may be H when n=0; and Y is selected from the group: ##STR2## wherein: m=1-6Z=SO.sub.2, S, C=O, CH.sub.2 or C(CH.sub.3).sub.2 ; and a process for their preparation are described.
Type:
Grant
Filed:
March 7, 1991
Date of Patent:
September 6, 1994
Assignee:
Bromine Compounds, Ltd.
Inventors:
Jakob Oren, Joshua Hermolin, David Feldman, Michael Zviely, Dov Zamir, Hugo Keselman
Abstract: Diaminodiphenyl-compounds of the structure selected from: ##STR1## wherein R.sub.1 and R.sub.2 can be: H, --CH.sub.3, --C.sub.2 H.sub.5, --C.sub.3 H.sub.7, --C.sub.4 H.sub.9 or ##STR2## Y can be: C(CH.sub.3).sub.2, ##STR3## n=0; 1. are purified by distilling the crude product obtained under vacuum in one step, in the presence of one or more alkaline bases.
Type:
Grant
Filed:
June 11, 1992
Date of Patent:
August 23, 1994
Assignee:
Bromine Compounds Ltd.
Inventors:
Joshua Hermolin, Hugo Keselman, Jacob Oren
Abstract: Mixtures of 2-methyl-isothiazolin-3-one (5H-MIT) and 5-chloro-2-methylisothiazolin-3-one (5Cl-MIT), are prepared by the chlorination of N-methyl-3-mercaptopropionamide (MMPA) with chlorine in a halogenated solvent in continuous operation.
Type:
Grant
Filed:
February 5, 1992
Date of Patent:
May 24, 1994
Assignee:
Bromine Compounds Ltd.
Inventors:
Reinhard Effenberger, Leonard Shorr, Yehuda Keren
Abstract: In a process for the preparation of substituted maleimides the corresponding amines are reacted with maleic anhydride and the thermal imidization of the resulting substituted amic-acids is effected in a mixed apolar/polar aprotic solvent medium in the presence of an acid catalyst, a substantial portion of the apolar solvent is subsequently selectively removed from the reaction mixture and most of the final product is precipitated.
Type:
Grant
Filed:
February 13, 1992
Date of Patent:
April 26, 1994
Assignee:
Bromine Compounds Ltd.
Inventors:
Michel Adda, Chaim Eidelman, Leonard Shorr
Abstract: Tribromostyrene (TBS) is produced by the preparation of a TBS precursor, which is .beta.-bromoethyl-tribromobenzene (.beta.-BrBr.sub.3), and the successive elimination of hydrogen bromide from said precursor. The precursor is prepared by selective bromination of phenethyl bromide (.beta.-Br), wherein the molar ratio of bromine to phenethyl bromide is comprised between 2.5 and 3.5, and preferably between 3.1 and 3.3 included; and by adding bromine, after an initial addition, at a controlled molar rate.
Type:
Grant
Filed:
August 6, 1992
Date of Patent:
September 7, 1993
Assignee:
Bromine Compounds Ltd.
Inventors:
Nurit Kornberg, David Beneish, Michael Peled
Abstract: In a process for the preparation of 4,4'-dihydroxybiphenyl of high purity 4,4'-dibromobiphenyl is hydrolized in the presence of a copper compound catalyst, the insoluble materials comprising the catalyst is filtered off from the product mixture, 4,4'-dihydroxybiphenyl is precipitated by adjusting the pH and crude 4,4'-dihydroxybiphenyl separated from the product mixture is fractionally distilled to obtain substantially pure 4,4'-dihydroxybiphenyl.
Type:
Grant
Filed:
May 28, 1991
Date of Patent:
March 23, 1993
Assignee:
Bromine Compounds, Ltd.
Inventors:
Jakob Oren, Hugo Kesselman, Joshua Hermolin
Abstract: The present invention relates to fire retardant polymer compositions possessing a non-liner structural configuration resulting by the reaction of N-tribromo-phenylmaleimide, with or without comonomer, with a preformed backbone polymer, in which the bromine content is above 1.2% by weight bromine. The polymer is selected from polystyrene, polyolefins, polyamides, rubbers, polyesters, acrylics, polymeric dienes and mixtures or copolymers thereof. The comonomer present with the N-tribromophenyl-maleimide is selected from the group consisting of acrylonitrile, styrene and vinyl chloride. According to the invention the non-linear structural configurations are obtained either by grafting or crosslinking of the N-tribromophenylmaleimide onto the preformed backbone polymer in the presence of free radical producing means. Optionally, synergistic fire retardant additives such as antimony oxide are incorporated in the compositions.
Type:
Grant
Filed:
November 26, 1990
Date of Patent:
January 19, 1993
Assignee:
Bromine Compounds, Ltd.
Inventors:
Leonard M. Shorr, Theodor M. Fishler, Shaul Yanay, Michael Rumack
Abstract: Biaryl derivatives are produced by coupling an aryl halide in an aqueous alkaline solution in the presence of a palladium catalyst, using formic hydrazide as the reducing agent.
Type:
Grant
Filed:
May 21, 1992
Date of Patent:
January 5, 1993
Assignee:
Bromine Compounds, Ltd.
Inventors:
Abram Becker, Ariel A. Ewenson, Bertha Croitoru