Abstract: A relief valve monitoring system and method can monitor the pressure in a pressure vessel in an ammonia refrigeration system and warn of an impending overpressure condition and a possible subsequent ammonia release event through a pressure relief valve. If a pressure relief valve opens, the relief valve monitoring system and method can identify the relief valve that has opened by monitoring the downstream pressure of the relief valve, accurately determine the amount of ammonia refrigerant that has been released into a common collection header, and purge the common collection header of residual ammonia after the ammonia release event has ended.