Abstract: Systems and methods of chemical process simulation providing improved methods and systems for expressing the composition of a stream in a chemical process model in a manner that is not immediately indicative of the underlying composition, providing for improved accuracy of allocation of a process output stream to the appropriate source(s), avoiding duplication of components or other inaccurate component representations in relation to critical calculations, and improving the operation of a computer or other computing system for performing chemical process modeling and simulation. The systems or methods provide for three distinct layers of interaction, separating mixed species displayed to the user from individual species used in calculations, while providing transformation objects between dataset layers to provide for accurate modeling, calculation, and display.

Abstract: Systems and methods of chemical process simulation providing improved methods and systems for expressing the composition of a stream in a chemical process model in a manner that is not immediately indicative of the underlying composition, providing for improved accuracy of allocation of a process output stream to the appropriate source(s), avoiding duplication of components or other inaccurate component representations in relation to critical calculations, and improving the operation of a computer or other computing system for performing chemical process modeling and simulation. The systems or methods provide for three distinct layers of interaction, separating mixed species displayed to the user from individual species used in calculations, while providing transformation objects between dataset layers to provide for accurate modeling, calculation, and display.

Abstract: Apparatus and associated methods relate to generating, from a predetermined distillation profile (DPBASE-P) of a multicomponent base fluid, a thermodynamically accurate distillation profile (DPMIX) of a mixture of the base fluid and at least one additive. In an illustrative example, at least one calibrating parameter (P) of a distillation model (DM) is determined according to DPBASE-P. The base fluid and the mixture may, for example, be represented by a base composition profile (CPBASE) and mixture composition profile (CPMIX), respectively, of pure chemical components. The DM may, for example, be calibrated to DPBASE-P to generate a distillation profile of the base fluid as a function of CPBASE and P. The calibrated DM may, for example, be configured to generate DPMIX as a function of P and CPMIX. Various embodiments may advantageously enable rapid characterization of a mixture from a known distillation profile of the base fluid.

Abstract: Systems and methods of chemical process simulation providing improved methods and systems for expressing the composition of a stream in a chemical process model in a manner that is not immediately indicative of the underlying composition, providing for improved accuracy of allocation of a process output stream to the appropriate source(s), avoiding duplication of components or other inaccurate component representations in relation to critical calculations, and improving the operation of a computer or other computing system for performing chemical process modeling and simulation. The systems or methods provide for three distinct layers of interaction, separating mixed species displayed to the user from individual species used in calculations, while providing transformation objects between dataset layers to provide for accurate modeling, calculation, and display.

Abstract: A process for converting natural gas to a hydrocarbon liquid wherein a stream of natural gas at a selected pressure is mixed with a hot gas stream which is at a temperature sufficient to affect a chemical reaction and form an intermediate product stream containing reactive hydrocarbons, the intermediate product stream being quenched and the quenched intermediate product stream being reacted in a catalytic liquification zone to produce a hydrocarbon liquid.

Abstract: An improved process for the conversion of normally gaseous methane-containing hydrocarbon mixtures, such as natural gas, to a normally liquid hydrocarbon product comprises separating the methane component of the gaseous mixture from the heavier hydrocarbon component, cracking the separated heavier: hydrocarbon component at a relatively low temperature and optionally cracking the methane component at a relatively high temperature. The low temperature cracking product and any high temperature cracking product are separated into a light product of principally hydrogen and a heavy product comprising unsaturated hydrocarbons. This heavy product is reacted with methane in the presence of an acidic alkalization catalyst. The resulting product mixture is separated into a light product, a portion of which is recycled, and the normally liquid hydrocarbon product.

Abstract: An improved process for the glycol dehydration of water-containing natural gas comprises contacting the natural gas and glycol in a contacting zone to produce a dried natural gas and a water-rich glycol, and heating the water-rich glycol in a regeneration zone to produce a water-lean glycol for reintroduction into the contacting zone and a water-containing gaseous overhead. The gaseous overhead is partially condensed and the resulting gaseous components are returned to the contacting zone. In a preferred embodiment, the glycol is further purified by contact in a separate stripping column with dry stripping gas under a pressure lower than that of the regeneration zone.