Patents Assigned to CALIX LTD
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Patent number: 12391611Abstract: The invention provides a powder-gas heat exchanger for exchanging heat between a powder stream and a gas stream in counter-current flow comprising a powder stream mass flow rate substantially equal to a gas stream mass flow rate in a vertical shaft heat exchanger. A hot gas stream may be adapted for use in heating a cool solids stream, or a cool gas stream may be adapted for use in cooling a hot solids stream.Type: GrantFiled: April 1, 2021Date of Patent: August 19, 2025Assignee: CALIX LTDInventors: Mark Geoffrey Sceats, Adam Vincent, Matthew Gill, Simon Thomsen, Phil Hodgson
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Patent number: 12315907Abstract: A process for producing a cathode or anode material adapted for use in the manufacture of fast rechargeable ion batteries. The process may include the steps of selecting a precursor material; grinding the precursor material to produce a powder; calcining the precursor powder, processing the hot precursor powder in a second calciner reactor segment; quenching the second precursor powder; and activating the particles of the second precursor powder.Type: GrantFiled: May 22, 2023Date of Patent: May 27, 2025Assignee: CALIX LTDInventors: Mark Sceats, Philip Hodgson, Khokan Kanti Majumder
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Publication number: 20240327937Abstract: An externally heated vertical reactor for reduction of iron ore, the reactor including: (a) a reactor tube positioned vertically adjacent to a furnace; (b) an external furnace positioned vertically adjacent at least one wall of the reactor tube to provide heat to be conducted through the at least one wall; (c) an input port at a base of the reactor tube, wherein the reducing gases are heated and injected into the input port such that the reducing gases rise upward through the reactor tube; (d) a gas exhaust positioned adjacent a top surface of the reactor; (e) a gas filter positioned adjacent an entrance to the gas exhaust; and (f) a bed positioned at the base of the reactor tube, wherein the reduced iron powder product is collected in the bed at the base of the reactor tube.Type: ApplicationFiled: October 18, 2022Publication date: October 3, 2024Applicant: CALIX LTDInventors: Mark SCEATS, Andrew ADIPURI, Matthew BOOT-HANDFORD, Matthew GILL, Thomas DUFTY, Adam VINCENT
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Patent number: 11701630Abstract: A method and system for producing nano-active powder materials. The method can be used with a reactor system comprising stages in which input particles flow under gravity progressively through stages of the reactor. A powder injector first stage in which ground input precursor powder is injected into the reactor. An externally heated preheater stage may be in the reactor, in which the precursor powder is heated to a temperature of calcination reaction. An externally heated calciner stage in the reactor, in which primary precursor volatile constituents can be rapidly removed calcination reactions as a high purity gas stream to produce the desired nano-active product. A post-processing reactor stage in which there is a change of the gas stream composition to produce the desired hot powder product by virtue of the nano-activity of the first powder material. A powder ejector stage in which the hot powder product is ejected from the reactor.Type: GrantFiled: August 12, 2022Date of Patent: July 18, 2023Assignee: CALIX LTDInventors: Mark Sceats, Philip Hodgson, Adam Vincent, Simon Thomsen, Matthew Gill, Daniel Rennie
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Patent number: 11695103Abstract: A process for producing a cathode or anode material adapted for use in the manufacture of fast rechargeable ion batteries. The process may include the steps of Selecting an precursor material that, upon heating in a gas stream, releases volatile compounds to create porous materials to generate a material compound suitable for an electrode in an ion battery. Grinding the precursor material to produce a powder of particles with a first predetermined particle size distribution to form a precursor powder. Calcining the precursor powder in a flash calciner reactor segment with a first process gas at a first temperature to produce a porous particle material suitable for an electrode in an ion battery, and having the pore properties, surface area and nanoscale structures for applications in such batteries.Type: GrantFiled: January 12, 2018Date of Patent: July 4, 2023Assignee: CALIX LTDInventors: Mark Sceats, Philip Hodgson, Khokan Kanti Majumder
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Patent number: 11446621Abstract: A method and system for producing nano-active powder materials. The method can be used with a reactor system comprising stages in which input particles flow under gravity progressively through stages of the reactor. A powder injector first stage in which ground input precursor powder is injected into the reactor. An externally heated preheater stage may be in the reactor, in which the precursor powder is heated to a temperature of calcination reaction. An externally heated calciner stage in the reactor, in which primary precursor volatile constituents can be rapidly removed calcination reactions as a high purity gas stream to produce the desired nano-active product. A post-processing reactor stage in which there is a change of the gas stream composition to produce the desired hot powder product by virtue of the nano-activity of the first powder material. A powder ejector stage in which the hot powder product is ejected from the reactor.Type: GrantFiled: October 27, 2017Date of Patent: September 20, 2022Assignee: CALIX LTDInventors: Mark Sceats, Philip Hodgson, Adam Vincent, Simon Thomsen, Matthew Gill, Daniel Rennie
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Patent number: 11401183Abstract: A method of manufacture of high-solids hydroxide slurries from caustic calcined carbonate powder is described, whereby the properties of the slurry are its low resistance to shear thinning to facilitate transport, a high stability for transport and storage, ease of reconstitution after long periods of storage, and, as required, a high concentration of chemically reactive species at the particle surface. The method achieves these specifications by mixing caustic calcined carbonate or hydroxide powder with water in an insulated reactor vessel, and agitating the slurry sufficiently such that the hydration reaction causes the water to spontaneously boil, such that the remaining hydration proceeds spontaneously under the fixed conditions of boiling through the water loss. The mixing process is preferably carried out by a shear pump. A viscosity modifier, such as acetic acid, is used to thin the slurry to enable the mixing system to maintain uniform mixing.Type: GrantFiled: June 22, 2020Date of Patent: August 2, 2022Assignee: Calix LtdInventors: Mark Sceats, Adam Vincent
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Publication number: 20210289790Abstract: A process and apparatus for manufacture of biocide products are described. The biocide properties arise from the caustic calcined powder, from carbonates such as such as magnesite and dolomite, and from hydroxides such as brucite. The method of manufacture is based on the production of high surface area oxide particles using an indirectly heated counterflow reactors for specifically calcining the carbonates and the hydroxides without significant sintering. The biocide products may be a powder or a hydrated slurry. A hydrated slurry is preferred for agricultural applications as a spray. For aquaculture applications, the products have a preferred particle size distribution to impact the aquatic and benthic ecosystems, and a Ca/Mg ratio that promotes the growth of the cultivates species when applied as a powder or a slurry.Type: ApplicationFiled: June 4, 2021Publication date: September 23, 2021Applicant: CALIX LTDInventor: Mark SCEATS
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Patent number: 11026428Abstract: A process and apparatus for manufacture of biocide products are described. The biocide properties arise from the caustic calcined powder, from carbonates such as such as magnesite and dolomite, and from hydroxides such as brucite. The method of manufacture is based on the production of high surface area oxide particles using an indirectly heated counterflow reactors for specifically calcining the carbonates and the hydroxides without significant sintering. The biocide products may be a powder or a hydrated slurry. A hydrated slurry is preferred for agricultural applications as a spray. For aquaculture applications, the products have a preferred particle size distribution to impact the aquatic and benthic ecosystems, and a Ca/Mg ratio that promotes the growth of the cultivates species when applied as a powder or a slurry.Type: GrantFiled: June 2, 2017Date of Patent: June 8, 2021Assignee: CALIX LTDInventor: Mark Sceats
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Patent number: 10829413Abstract: A process for producing a highly calcined and uniformly calcined product from a feedstock. The process comprising the steps of grinding the feedstock to powder, preheating the powder, and calcining the powder in a reactor plant that comprises a number of reactor segments in which a flash calciner is used in each progressive reactor segment to incrementally react the powder by raising the temperature in each segment. The last segment may be a high-temperature reactor that has a controlled residence time and temperature that may allow controlled finishing of the calcination process to achieve a desired degree of calcination and sintering of the product; and cooling of the product.Type: GrantFiled: November 11, 2015Date of Patent: November 10, 2020Assignee: Calix LtdInventor: Mark Sceats
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Patent number: 10800683Abstract: A method of manufacture of high-solids hydroxide slurries from caustic calcined carbonate powder is described, whereby the properties of the slurry are its low resistance to shear thinning to facilitate transport, a high stability for transport and storage, ease of reconstitution after long periods of storage, and, as required, a high concentration of chemically reactive species at the particle surface. The method achieves these specifications by mixing caustic calcined carbonate or hydroxide powder with water in an insulated reactor vessel, and agitating the slurry sufficiently such that the hydration reaction causes the water to spontaneously boil, such that the remaining hydration proceeds spontaneously under the fixed conditions of boiling through the water loss. The mixing process is preferably carried out by a shear pump. A viscosity modifier, such as acetic acid, is used to thin the slurry to enable the mixing system to maintain uniform mixing.Type: GrantFiled: February 21, 2019Date of Patent: October 13, 2020Assignee: Calix LtdInventors: Mark Sceats, Adam Vincent
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Patent number: 10570061Abstract: A method of manufacture of Portland cement clinker is described in a dry process that captures the carbon dioxide emitted from the calcination of carbonate minerals, principally limestone. The process uses an indirectly heated, counter-flow reactor to pre-heat and calcine the cement meal to produce a separate calcined meal and carbon dioxide gas stream, with external heat being provided by the combustion of a secondary fuel stream with pre-heated air. This calcined meal is injected into the conventional rotary kiln, where the hot flue gas from combustion of the primary fuel with pre-heated air is used to fuse, react and sinter the powders to form granules of cement clinker. The clinker and carbon dioxide streams are cooled by the air pre-heaters.Type: GrantFiled: November 19, 2014Date of Patent: February 25, 2020Assignee: CALIX LTDInventor: Mark Sceats
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Patent number: 10358364Abstract: A method of manufacture of high-solids hydroxide slurries from caustic calcined carbonate powder is described, whereby the properties of the slurry are its low resistance to shear thinning to facilitate transport, a high stability for transport and storage, ease of reconstitution after long periods of storage, and, as required, a high concentration of chemically reactive species at the particle surface. The method achieves these specifications by mixing caustic calcined carbonate or hydroxide powder with water in an insulated reactor vessel, and agitating the slurry sufficiently such that the hydration reaction causes the water to spontaneously boil, such that the remaining hydration proceeds spontaneously under the fixed conditions of boiling through the water loss. The mixing process is preferably carried out by a shear pump. A viscosity modifier, such as acetic acid, is used to thin the slurry to enable the mixing system to maintain uniform mixing.Type: GrantFiled: October 15, 2014Date of Patent: July 23, 2019Assignee: Calix LtdInventors: Mark Sceats, Adam Vincent
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Patent number: 9913475Abstract: A process and apparatus for manufacture of oxide products for use as biocide, chemical detoxifying, and catalytic support products, from caustic calcined carbonate powder, preferably from magnesite, dolomite, or hydromagnesite, is described. These oxide particles are characterized by high surface area, high porosity and a high degree of calcination, and the method of manufacture utilizes an indirectly heated counterflow reactor. The oxides may be used as a powder, granules, or formulated into a slurry and used as a spray, emulsion, foam or fog, or the powder product may be directly applied. Also described is the formation of particles with microstructures defined by at least one nano-crystalline structure positioned on the outer surface of the particles.Type: GrantFiled: December 10, 2014Date of Patent: March 13, 2018Assignee: Calix LtdInventor: Mark Sceats
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Publication number: 20170320774Abstract: A process for producing a highly calcined and uniformly calcined product from a feedstock. The process comprising the steps of grinding the feedstock to powder, preheating the powder, and calcining the powder in a reactor plant that comprises a number of reactor segments in which a flash calciner is used in each progressive reactor segment to incrementally react the powder by raising the temperature in each segment. The last segment may be a high-temperature reactor that has a controlled residence time and temperature that may allow controlled finishing of the calcination process to achieve a desired degree of calcination and sintering of the product; and cooling of the product.Type: ApplicationFiled: November 11, 2015Publication date: November 9, 2017Applicant: Calix LtdInventor: Mark Sceats
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Publication number: 20170035053Abstract: A process and apparatus for manufacture of oxide products for use as biocide, chemical detoxifying, and catalytic support products, from caustic calcined carbonate powder, preferably from magnesite, dolomite, or hydromagnesite, is described. These oxide particles are characterized by high surface area, high porosity and a high degree of calcination, and the method of manufacture of utilizes an indirectly heated counterflow reactor. The oxides may be used as a powder, granules, or formulated into a slurry and used as a spray, emulsion, foam or fog, or the powder product may be directly applied. Also described is the formation of particles with microstructures defined by at least one nano-crystalline structure positioned on the outer surface of the particles.Type: ApplicationFiled: December 10, 2014Publication date: February 9, 2017Applicants: Calix Ltd, Calix LtdInventor: Mark Sceats
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Patent number: 9469884Abstract: A system and method for the calcination of minerals.Type: GrantFiled: June 5, 2014Date of Patent: October 18, 2016Assignee: Calix LtdInventors: Connor James Horley, Mark Geoffrey Sceats
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Publication number: 20160264435Abstract: A method of manufacture of high-solids hydroxide slurries from caustic calcined carbonate powder is described, whereby the properties of the slurry are its low resistance to shear thinning to facilitate transport, a high stability for transport and storage, ease of reconstitution after long periods of storage, and, as required, a high concentration of chemically reactive species at the particle surface. The method achieves these specifications by mixing caustic calcined carbonate or hydroxide powder with water in an insulated reactor vessel, and agitating the slurry sufficiently such that the hydration reaction causes the water to spontaneously boil, such that the remaining hydration proceeds spontaneously under the fixed conditions of boiling through the water loss. The mixing process is preferably carried out by a shear pump. A viscosity modifier, such as acetic acid, is used to thin the slurry to enable the mixing system to maintain uniform mixing.Type: ApplicationFiled: October 15, 2014Publication date: September 15, 2016Applicants: Calix Ltd, Calix LtdInventors: Mark SCEATS, Adam VINCENT
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Patent number: 8496751Abstract: This invention relates to a cement binder composition and to the use of the binder composition in construction products. The cement binder composition is based on MgO that absorbs CO2 when hardening. The binder composition of the present invention also comprises at least one magnesium carbonate (either hydrated or unhydrated) having the formula xMgCO3-yMg(OH)2-zH2O, wherein x is at least 1, and at least one of y or z is greater than 0. The binder composition may optionally comprise a hydroscopic material, for example NaCl. The MgO when mixed with water in the presence of the magnesium carbonate produces magnesium hydroxide that has a rosette-like morphology (as shown).Type: GrantFiled: June 26, 2009Date of Patent: July 30, 2013Assignee: Calix LtdInventors: Nikolaos Vlasopoulos, Christopher Robert Cheeseman
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Publication number: 20110008227Abstract: A system and method for the calcination of minerals.Type: ApplicationFiled: April 2, 2007Publication date: January 13, 2011Applicant: CALIX LTDInventors: Mark Geoffrey Sceats, Connor James Horley, Patricia Richardson