Abstract: A resin useful for producing objects is provided, which resin contains a photoinitiator of low cytotoxicity. The resins may be suitable for use in additive manufacturing techniques such as bottom-up and top-down stereolithography, produce objects that are bioresorbable and non-cytotoxic, and/or produce objects that are flexible or elastic. Methods of use of the resin and objects produced therefrom are also provided.

Abstract: An ocean alkalinity enhancement (OAE) system that reduces atmospheric CO2 and mitigates ocean acidification by electrochemically processing feedstock solution (e.g., seawater or brine) to generate an alkalinity product that is then supplied to the ocean. The OAE system includes a base-generating device and a control circuit disposed within a modular system housing deployed near a salt feedstock. The base-generating device (e.g., a bipolar electrodialysis (BPED) system) generates a base substance that is then used to generate the ocean alkalinity product. The control circuit controls the base-generating device such that the alkalinity product is supplied to the ocean only when (1) sufficient low/zero-carbon electricity is available, (2) it is safe to operate the base-generating device, and (3) supplying the alkalinity product will not endanger sea life.

Abstract: A method for the production of an object by additive manufacturing includes inputting a boundary shape and desired mechanical properties for said object, subdividing said boundary shape into a plurality of adjacent work cells, providing a plurality of lattices in a database, each lattice of the database including a geometry and a mechanical property, filling a first one of said work cells with a lattice from the database, the lattice selected based on the correspondence of the mechanical properties of said lattice to said desired mechanical properties of said object, filling the remaining ones of said work cells with lattices from said database to produce a filled boundary shape, each said lattice selected based on: the correspondence of the mechanical properties of said lattice to the desired mechanical properties of the object, and the compatibility of adjacent lattices in adjacent work cells with one another.

Abstract: A method of separating excess resin from at least one object includes: (a) stereolithographically producing at least one object, each object having at least one retention feature (32) formed thereon, each object carrying excess resin on a surface thereof; then (b) mounting each object on at least one transfer frame (21), each transfer frame having at least one retention member (22) that mates with the retention feature; (c) connecting each transfer frame to a rotor with the at least one object carried thereon; (d) centrifugally separating excess resin from each object by spinning the rotor with each transfer frame connected thereto while the at least one object remains connected to each transfer frame by the retention feature; then (e) removing each transfer frame from the rotor, with excess resin separated from each at least one object thereon.

Abstract: A polymerizable liquid useful for the production of a three-dimensional object comprised of silicone, or a copolymer thereof, which includes at least one constituent selected from the group consisting of (i) a blocked or reactive blocked siloxane-containing prepolymer, (ii) a blocked or reactive blocked siloxane-containing polyisocyanate, and (iii) a blocked or reactive blocked siloxane-containing polyisocyanate chain extender. Methods of using the same in additive manufacturing processes such as continuous liquid interface production are also described.

Abstract: A dental model, includes (a) an upper segment, the upper segment having a shape corresponding to at least a portion of a dental arch of a human patient; (b) a base segment having an external surface and a bottom surface; (c) at least one internal cavity formed in the base segment, and optionally the upper segment, the at least one internal cavity extending through the bottom surface; and (d) at least one wash channel extending from the external surface of the base segment through the base segment and into the at least one internal cavity.

Abstract: A method of separating excess resin from at least one object, includes: (a) stereolithographically producing at least one object on at least one carrier platform, each carrier platform having a planar build surface to which at least one object is connected, each object carrying excess resin on a surface thereof; then (b) mounting each carrier platform to a rotor; (c) centrifugally separating excess resin from each object by spinning the rotor with each carrier platform connected thereto while each object remains connected to each carrier platform; and then (d) removing each carrier platform from the rotor with each object thereon, with excess resin separated therefrom.

Abstract: MRV for an ocean CDR system is achieved by varying the release/delivery of base substance into ocean seawater such that the base substance propagates as a series of release batch wavefronts along a dispersion path. A release frequency, which controls a timing of the release batch wavefronts, is selected to coincide with a non-natural frequency (e.g., a frequency exhibiting quiet/weak power spectra in a natural seawater chemistry variation power spectrum). Time-based seawater carbonate chemistry measurement data, which is collected by ocean-based sensors disposed in the base substance's dispersion path during base substance release, records both human-induced contributions caused by the release batch wavefronts and natural seawater chemistry variations.

Abstract: A method of forming a three-dimensional object comprised of a silicone polymer is carried out by: (a) providing a silicone dual cure resin; (b) forming a three-dimensional intermediate from that resin, where the intermediate has the shape of, or a shape to be imparted to, the three-dimensional object, and where the resin is solidified in that intermediate object by irradiating with light; and then (c) further reacting the three-dimensional intermediate to form the three-dimensional object. The silicone dual cure resin includes: (i) a light polymerizable first reactant; (ii) a photoinitiator; (iii) at least one additional reactant(s), and (iv) optionally a catalyst. At least one of the first reactant and the additional reactant(s) contains a siloxane linkage.

Abstract: Provided is method of making a three-dimensional object comprising polyurea, which may include: (a) dispensing a one part (1K) dual cure resin into a stereolithography apparatus, the resin comprising or consisting essentially of a photoinitiator, a reactive blocked polyisocyanate, optionally a catalyst such as a polyurethane blowing catalyst, and optionally a polyepoxide; (b) additively manufacturing from said resin an intermediate object comprising the light polymerization product of said reactive blocked polyisocyanate; (c) optionally cleaning said intermediate object; and (d) reacting said polymerization product in said intermediate with water in the presence of a catalyst such as a polyurethane blowing catalyst (which may be included in the resin, the water, or both) to generate polyamine in situ that sequentially reacts with the remainder of the polymerization product to form urea linkages and thereby produce a three-dimensional object comprising polyurea.

Abstract: Provided herein according to aspects of the present invention are resins that: (a) are suitable for use in additive manufacturing techniques such as bottom-up and top-down stereolithography, (b) produce objects that are bioresorbable, and (c) produce objects that are flexible or elastic (preferably at at least typical room temperatures of 25° C., and in some embodiments at typical human body temperatures of 37° C.). Such resins may include: (a) a bioresorbable polyester oligomer having reactive end groups; (b) non-reactive diluent; (c) optionally reactive diluent; and (d) a photoinitiator.

Abstract: An additively manufactured lattice structure includes (a) a first three-dimensional lattice including a repeating interconnected array of a first lattice unit cell, (b) a second three-dimensional lattice including a repeating interconnected array of a second lattice unit cell, wherein said second lattice unit cell is different from said first lattice unit cell, and (c) a first transition segment interconnecting said first three-dimensional lattice and said second three-dimensional lattice. The first transition segment includes (i) a first three-dimensional transitional lattice including a repeating array of said first lattice unit cell and (ii) interleaved with and interconnected to said first three-dimensional transitional lattice, a second three-dimensional transitional lattice including a repeating array of said second lattice unit cell.

Abstract: Provided herein is a method of recycling reactive prepolymers from additively manufactured articles or recovered coating material that comprises a crosslinked polymer formed from a single-cure resin comprising a reactive blocked prepolymer and a crosslinker, by forming and recovering a regenerated reactive prepolymer. Light-polymerizable resins, methods of making recyclable objects from such resins, and methods for sustainable manufacturing are also provided.

Abstract: A test cell useful for determining the photosensitivity of a photopolymerizable material, includes a support plate having a top surface portion, a bottom surface portion, and an opening extending therebetween, a light-transmissive base member removably or permanently connected to said bottom surface portion to form with said opening a well, into which well photopolymerizable material can be deposited, and a sensor comprising a thermal sensor, strain sensor, or combination thereof operatively associated with said light-transmissive base member.

Abstract: A method of forming a three-dimensional object (e.g. comprised of polyurethane, polyurea, or copolymer thereof) is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid comprising a mixture of: (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid blocked polymer scaffold and advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, with the intermediate containing the second solidifiable component; and then (d) contacting the three-dimensional intermediate to water to form the three-dimensional object.

Abstract: Provided herein according to some embodiments is a dual cure additive manufacturing resin, comprising: (i) a light polymerizable component, (ii) a photoinitiator, (iii) a heat polymerizable component, and (iv) a non-reactive diluent, which resin is useful for the production of three-dimensional objects by additive manufacturing. Methods of using the same are also provided.

Abstract: A method of making a physical object having a desired geometry from a resin such as a dual cure resin by an additive manufacturing process such as a dual cure additive manufacturing process includes (a) entering into a processor a first input geometry for the physical object, the first input geometry corresponding to a desired geometry for the physical object; (b) modifying in the processor the first input geometry to a candidate inversely distorted input geometry for the physical object; (c) generating a simulated object from the candidate inversely distorted input geometry with a Multiphysics model simulation of the additive manufacturing process, the simulated object including distortions towards the desired geometry arising from the additive manufacturing process; (d) evaluating whether the simulated object sufficiently corresponds to the desired geometry for the physical object.

Abstract: A method of forming a dual cure three-dimensional object by additive manufacturing may be carried out by mixing a first precursor liquid and a second precursor liquid to produce a polymerizable liquid comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component (e.g., a second reactive component) that is different from the first component (e.g., that does not contain a cationic photoinitiator, or is further solidified by a different physical mechanism, or further reacted, polymerized or chain extended by a different chemical reaction). In the foregoing: (i?) at least one reactant of the second solidifiable component is contained in the first precursor liquid, and (ii?) at least one reactant or catalyst of the second solidifiable component is contained in the second precursor liquid. Once mixed, the three-dimensional object may be formed from the resin by a dual cure additive manufacturing process.

Abstract: The present invention concerns methods of forming a three-dimensional object, and polymerizable liquids such as dual cure resins useful for making a three-dimensional object by sterolithography, such as by continuous liquid interface production (CLIP), wherein the three-dimensional object is flame retardant.

Abstract: Provided herein is a resin product useful for the production of three-dimensional objects by additive manufacturing, and methods using the same. The resin may include a reactive blocked prepolymer comprising a prepolymer blocked with reactive blocking groups; a polyol; a photoinitiator; and at least one organometallic catalyst. A packaged product useful for the production of three-dimensional objects by additive manufacturing, the product comprising a single container having a single chamber and a resin in the chamber with all components mixed together, is also provided.