Patents Assigned to Catalysts and Chemicals Industries Co., Ltd.
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Patent number: 6586104Abstract: A coating liquid for forming a transparent coating comprising fine particles of an inorganic compound and a hydrolyzate of an organosilicon compound represented by the general formula (I): RnSi(OR′)4−n (I) wherein R and R′ represent organic groups which may be identical to each other or different from each other, and n is an integer of 1 to 3. This coating liquid ensures excellent substrate wettability and compatibility with various organic solvents so that the printability and applicability thereof are desirable, with the result that a transparent coating film of high uniformity, for example, a flattening coating film, can be formed. The present invention comprises a substrate having a transparent coating film formed on the substrate surface from the above coating liquid.Type: GrantFiled: February 23, 1998Date of Patent: July 1, 2003Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Masayuki Matsuda, Nobuaki Yoshida, Tsuguo Koyanagi, Michio Komatsu
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Patent number: 6580026Abstract: A photovoltaic cell including a first substrate having on its surface a first electrode layer having on its surface a semiconductor film on which a photosensitizer is adsorbed, and a second substrate having on its surface a second electrode layer. The first and second substrates are arranged so that the first electrode layer overlaid with the semiconductor film and the second layer are opposite each other with an electrolyte layer disposed therebetween. The electrolyte layer includes an electrolyte and a liquid crystal and at least one of the electrode-layer-having substrates is transparent.Type: GrantFiled: February 28, 2001Date of Patent: June 17, 2003Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Tsuguo Koyanagi, Michio Komatsu
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Publication number: 20030089045Abstract: Silica particles for polishing to planarize a surface of a substrate without generating scratches, having the average particle diameter in the range from 5 to 300 nm, carbon content in the range from 0.5 to 5 weight %, and 10%-compressive elasticity modulus in the range from 500 to 3000 kgf/mm2. When the carbon content in the silica particles is less than 0.5 weight %, there is no residual alkoxy group and siloxane bonding proceeds, so that the obtained particles are hard. In that case, although the polishing rate is high, scratches remain or are generated anew after polishing, and planarity of the polished surface is insufficient. On the other hand, when the carbon content is over 5 weight %, many residual alkoxy group are contained in the particles, so that the particles are relatively soft and a sufficient polishing rate can not be achieved.Type: ApplicationFiled: November 12, 2002Publication date: May 15, 2003Applicant: CATALYSTS & CHEMICALS INDUSTRIES CO., LTD.Inventors: Kazuhiro Nakayama, Akira Nakashima, Michio Komatsu
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Publication number: 20030089276Abstract: The present invention provides amorphous inorganic particles as a dental material comprising silica and inorganic oxide(s) other than silica and having high x-ray impermeability. The inorganic particles as a dental material comprise silica with the content in the range from 70 to 98 weight % and oxide(s) of one or more elements selected from the group consisting of Zr, Ti, La, Ba, Sr, Hf, Y, Zn, AL, and B, wherein 5 to 70 weight % of the silica is originated from an acidic silicic acid solution and 30 to 95 weight % of the silica is originated from a sol of silica. This inorganic particles as a dental material have average particle diameter in the range from 1 to 10 &mgr;m, specific surface area in the range from 50 to 350 m2/g, pore volume in the range from 0.05 to 0.5 ml/g, amorphous crystallinity as observed by x-ray diffraction, and the refractive index in the range from 1.47 to 1.60.Type: ApplicationFiled: November 12, 2002Publication date: May 15, 2003Applicant: CATALYSTS & CHEMICALS INDUSTRIES CO., LTD.Inventors: Hiroyasu Nishida, Noboru Senju, Michio Komatsu
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Patent number: 6562465Abstract: A coating liquid for forming a silica-based film having a low dielectric constant, as low as 3 or less, comprising (i) silica-based fine particles having phenyl groups and (ii) a polysiloxazane which can be produced by reacting hydrolyzate of an alkoxysilane represented by the formula (XnSi(OR1)4−n)and/or hydrolyzate of a halogenated silane represented by the formula (XnSiX′4−n) with a polysilazane represented by —(SiR2R4—NR3)—m, or a coating-liquid for forming the silica-based film, comprising (i) silica-based fine particles having phenyl groups and (ii′) an oxidatively decomposable resin with the weight ratio of the particles to the resin being in the range of 0.5 to 5.Type: GrantFiled: December 23, 1999Date of Patent: May 13, 2003Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Akira Nakashima, Atsushi Tonai, Michio Komatsu
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Patent number: 6562323Abstract: A composite powder prepared by coating a ramentaceous substrate with at least two color layers. A difference between the maximum value and the minimum value of the ab hue angle hab (hmax−hmin) as defined in the recommendation on uniform color space by CIE is in the range from 10° to 180°. A ratio of the maximum value vs the minimum value of the brightness L* as defined in the recommendation is in the range from 1.0 to 2.0. According to the viewing angle, the color tone of the composite powder changes.Type: GrantFiled: September 29, 2000Date of Patent: May 13, 2003Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Takumi Miyazaki, Hirokazu Tanaka
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Publication number: 20030062599Abstract: A process for producing semiconductor substrates with a coating film having an excellent chemical resistance with a high yield and an excellent production reliability without any development of cracks and any generation of foreign matters due to a projected portion of the coating film is described, which includes the steps of:Type: ApplicationFiled: September 19, 2002Publication date: April 3, 2003Applicant: CATALYSTS & CHEMICALS INDUSTRIES CO., LTD.Inventors: Miki Egami, Ryo Muraguchi
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Patent number: 6538194Abstract: A photoelectric cell that includes a first insulating base, having on its surface a first electrode layer, which has on its surface a metal oxide semiconductor film, which includes anatase titanium oxide particles, on which a photosensitizer is adsorbed and a second insulating base having on its surface a second electrode layer and an electrolyte sealed between the metal oxide semiconductor film and the second electrode layer. The first electrode layer and the second electrode layer are arranged opposite from each other. At least one of the first and second insulating bases with an electrode layer is transparent.Type: GrantFiled: November 28, 2000Date of Patent: March 25, 2003Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Tsuguo Koyanagi, Michio Komatsu, Hirokazu Tanaka, Katsuhiro Shirono
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Publication number: 20030031840Abstract: The invention provides a recording sheet having an ink-receiving layer, which comprises a substrate sheet and an ink-receiving layer formed thereon, said ink-receiving layer comprising oxide particles, wherein the ink-receiving layer has pores having a diameter in the range of 3.4 to 2,000 nm, the pore volume of pores having a diameter of 3.4 to 30 nm is in the range of 0.2 to 1.8 ml/g, and the pore volume of pores having a diameter of 30 to 2,000 nm is in the range of 0.1 to 1.5 ml/g. It is preferable that the oxide particles have an average particle diameter of 2 to 1,000 nm and are a mixture of hydrophobic oxide particles and hydrophilic oxide particles. This recording sheet shows sufficient strength, has excellent printability such that images of uniform density and high sharpness can be printed thereon without bleeding, and is excellent in water resistance, weathering resistance and fading resistance.Type: ApplicationFiled: June 17, 2002Publication date: February 13, 2003Applicant: Catalysts & Chemicals Industries Co., Ltd.Inventors: Hiroyasu Nishida, Mitsuru Nakai, Michio Komatsu
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Patent number: 6482419Abstract: An inorganic composite powder is formed of a scaled substrate, and at least three inorganic oxide layers having different refractive indexes respectively and sequentially laminated in an order of high refractive index to low refractive index from a surface of the scaled substrate to an utmost outer layer. A refractive index of an inorganic oxide used for forming the utmost outer layer is 1.73 or less, and a difference in the refractive indexes between the utmost layer and a layer adjacent thereto is 0.6 or less. Alternatively, the thickness of at least one of a second or higher inorganic oxide layer is within ±20% of a value d given by an equation: d=(&lgr;×X/4)/n, wherein &lgr; indicates a wavelength of visual light, X indicates an odd integer, and n indicates the refractive index of the inorganic oxide.Type: GrantFiled: September 29, 2000Date of Patent: November 19, 2002Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Takumi Miyazaki, Hirokazu Tanaka
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Patent number: 6451436Abstract: A coating liquid for forming a silica-containing film with a low-dielectric constant, which enables the formation of a low-density film having a dielectric constant as low as 3 or less and being excellent not only in resistance of oxygen plasma and in process adaptation but also in adhesion to a substrate and in film strength, is provided. A substrate coated with the silica-containing film having the above characteristics, which is obtained by the use of the above coating liquid, is further provided.Type: GrantFiled: May 24, 2000Date of Patent: September 17, 2002Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Michio Komatsu, Akira Nakashima, Miki Egami
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Patent number: 6447881Abstract: The invention provides a recording sheet having an ink-receiving layer, which comprises a substrate sheet and an ink-receiving layer formed thereon, said ink-receiving layer comprising oxide particles, wherein the ink-receiving layer has pores having a diameter in the range of 3.4 to 2,000 nm, the pore volume of pores having a diameter of 3.4 to 30 nm is in the range of 0.2 to 1.8 ml/g, and the pore volume of pores having a diameter of 30 to 2,000 nm is in the range of 0.1 to 1.5 ml/g. It is preferable that the oxide particles have an average particle diameter of 2 to 1,000 nm and are a mixture of hydrophobic oxide particles and hydrophilic oxide particles. This recording sheet shows sufficient strength, has excellent printability such that images of uniform density and high sharpness can be printed thereon without bleeding, and is excellent in water resistance, weathering resistance and fading resistance.Type: GrantFiled: December 23, 1998Date of Patent: September 10, 2002Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Hiroyasu Nishida, Mitsuru Nakai, Michio Komatsu
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Patent number: 6359667Abstract: An organopolysiloxane fine particle comprising as a principal component a polysiloxane having a hydrocarbon group (a) directly bonded to a silicon atom and having an OH group (b) directly bonded to a silicon atom, wherein: (i) carbons contained in the hydrocarbon group (a) constitute 5 to 35% of the weight of the organopolysiloxane fine particles, and (ii) the OH group (b) is in an amount of 1 to 8 meq per g of the organopolysiloxane fine particles, the organopolysiloxane fine particles having: (iii) a 10% compressive modulus of elasticity of 150 to 900 Kg/mm2, (iv) an average compressive deformation (Cr)m of 20 to 60%, (v) an average elastic recovery (Rr)m of 60 to 90%, and (vi) an average particle diameter of 0.5 to 50 &mgr;m.Type: GrantFiled: August 8, 2000Date of Patent: March 19, 2002Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Tsuguo Koyanagi, Michio Komatsu, Kazuhiro Nakayama
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Patent number: 6355260Abstract: White or colored pigments which do not suffer from color tone or hiding performances thereof even when the surface is moistened with water or oil, without spoiling coloring performance or hiding performance of the pigments themselves. These pigments are surface-coated with an inorganic compound having the refractive index of 1.8 or below. The inorganic compound is preferably silicon oxide, and the pigments are preferably inorganic pigments comprising titanium oxide, zinc oxide, or iron oxide. The cosmetics of the invention are blended the pigments therein.Type: GrantFiled: June 3, 1999Date of Patent: March 12, 2002Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Hirokazu Tanaka, Takumi Miyazaki
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Patent number: 6340641Abstract: The present invention provides a method of easily planarizing the uneven surface of a substrate having an uneven surface. This method comprises the steps of forming a coating film containing spherical fine particles on a surface of a smooth substrate; sticking the surface of the smooth substrate provided with the coating film containing spherical fine particles to the uneven surface of a substrate having an uneven surface; and transferring the coating film containing spherical fine particles to the uneven surface of the substrate so that the uneven surface is planarized.Type: GrantFiled: April 29, 1999Date of Patent: January 22, 2002Assignees: Catalysts & Chemicals Industries Co., Ltd., Nippon Telegraph and Telephone CorporationInventors: Ryo Muraguchi, Akira Nakashima, Atsushi Tonai, Michio Kimatsu, Katsuyuki Machida, Hakaru Kyuragi, Kazuo Imai
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Publication number: 20010028890Abstract: Spherical composite particles comprise inorganic fine particles and resin fine particles of jointed to each other and the average particle diameter is in the range from 0.5 to 100 g m, in which the average particle diameter of the inorganic fine particles is in the range from 5 to 600 nm and the average particle diameter of the resin fine particles is in the range from 10 to 500 nm. The spherical composite particle comprises an inorganic fine particle and a resin fine particle each having almost same size, jointed to each other, and the hardness, softness, and adaptability to being spread on skin can finely be adjusted to desired ones in a wide range respectively according to the contact feeling required for the cosmetics in which the particles are blended.Type: ApplicationFiled: February 22, 2001Publication date: October 11, 2001Applicant: CATALYSTS & CHEMICALS INDUSTRIES CO., LTD.Inventors: Takumi Miyazaki, Hirokazu Tanaka
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Patent number: 6294230Abstract: The present invention relates to spherical laminated particles each comprising a core particle and a laminate part disposed on a surface of the core particle, wherein the laminate part has a compressive modulus which is smaller than that of the core particle. These spherical laminated particles have a large compressive strength and is excellent in the recovery from a deformation by an arbitrary load, when the load is removed afterwward, as compared with conventional elastic particles composed of a single substance. Therefore, the use of these spherical laminated particles as spacers minimizes the difference in extent of displacement of spacer particles attributed to the difference in load on individual spacer particles caused by, for example, the waviness of a substrate for liquid crystal display cell during the manufacturing of the liquid crystal display cell, so that the cell gap uniformity can be ensured.Type: GrantFiled: August 27, 1999Date of Patent: September 25, 2001Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Tsuguo Koyanagi, Kazuhiro Nakayama, Yutaka Mitsuo, Mitsuru Nakai, Michio Komatsu
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Patent number: 6261357Abstract: A coating liquid for forming a low-permittivity silica film, which is capable of forming an insulating film that has a relative permittivity as low as up to 3 and is excellent in adherence to a substrate surface, mechanical properties, chemical resistance such as alkali resistance and also crack resistance, and which is capable of smoothing the irregularities of a substrate surface to a satisfactorily high degree, is provided. Further, a substrate comprising this low-permittivity silica coating film is provided.Type: GrantFiled: September 23, 1998Date of Patent: July 17, 2001Assignees: Catalysts & Chemicals Industries Co., Ltd., Fujitsu LimitedInventors: Miki Egami, Akira Nakashima, Michio Komatsu
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Patent number: 6180030Abstract: A coating liquid for forming a transparent conductive coating, comprising fine particles of a composite metal having an average particle size of 1 to 200 nm and a polar solvent. The above composite metal particles are preferably composed of an alloy of a plurality of metals or comprise fine metal particles or the fine alloy particles covered by a metal having a standard hydrogen electrode potential higher than that of the metal or alloy metal. A substrate with transparent conductive coating comprising a transparent conductive fine particle layer including the composite metal particles and a transparent coating disposed on the transparent conductive fine particle layer. A display device comprising a front panel composed of the above substrate with transparent conductive coating, the transparent conductive coating being formed at an outer surface of the front panel.Type: GrantFiled: April 27, 2000Date of Patent: January 30, 2001Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Toshiharu Hirai, Michio Komatsu, Mitsuaki Kumazawa, Yuji Tawarazako
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Patent number: 6136228Abstract: A coating liquid for forming a transparent conductive coating, comprising fine particles of a composite metal having an average particle size of 1 to 200 nm and a polar solvent. The above composite metal particles are preferably composed of an alloy of a plurality of metals or comprise fine metal particles or the fine alloy particles covered by a metal having a standard hydrogen electrode potential higher than that of the metal or alloy metal.A substrate with transparent conductive coating comprising a transparent conductive fine particle layer including the composite metal particles and a transparent coating disposed on the transparent conductive fine particle layer.A display device comprising a front panel composed of the above substrate with transparent conductive coating, the transparent conductive coating being formed at an outer surface of the front panel.Type: GrantFiled: September 25, 1997Date of Patent: October 24, 2000Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Toshiharu Hirai, Michio Komatsu, Mitsuaki Kumazawa, Yuji Tawarazako