Patents Assigned to CAW Industries, Inc.
  • Patent number: 4377599
    Abstract: Solid carbonaceous fossil fuels such as coal, lignite and peat are treated with an aqueous medium containing a novel catalyst to remove undesirable constituents and produce valuable products. The catalyst is prepared by steps including admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of dissolved water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle-forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. Particles of the fossil fuel, or components thereof, are treated and solubilized in the aqueous catalyst suspension to produce a novel aqueous solution which has highly unusual and unexpected properties. The resultant solution has important applications in agriculture and animal husbandry.
    Type: Grant
    Filed: July 30, 1980
    Date of Patent: March 22, 1983
    Assignee: Caw Industries, Inc.
    Inventor: John W. Willard, Sr.
  • Patent number: 4237101
    Abstract: Solid carbonaceous fossil fuels such as coal, lignite and peat are treated with an aqueous medium containing a novel catalyst to remove undesirable constituents and produce valuable products. The catalyst is prepared by steps including admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of dissolved water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle-forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. In one variant, particles of a fossil fuel containing metal values are treated with an aqueous medium in the presence of the catalyst, and thereafter the treated particles are separated from the aqueous medium and extracted with an aqueous leach solution in which the metal values are soluble.
    Type: Grant
    Filed: April 14, 1978
    Date of Patent: December 2, 1980
    Assignee: CAW Industries, Inc.
    Inventor: John W. Willard, Sr.
  • Patent number: 4126441
    Abstract: Cuttings to be rooted are intimately contacted with water containing a catalytically effective amount of a novel catalyst. The cuttings root faster and/or easier, and the new plants produced therefrom are more vigorous and resistant to disease and/or adverse environmental conditions. In a preferred variant, the water may also contain water soluble catalyst treated lignite. The catalyst is prepared by a process including the steps of admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. The preparation of the novel catalyst and the water soluble catalyst treated lignite is described in detail hereinafter.
    Type: Grant
    Filed: November 8, 1976
    Date of Patent: November 21, 1978
    Assignee: Caw Industries, Inc.
    Inventor: John W. Willard, Sr.
  • Patent number: 4116666
    Abstract: Seeds are intimately contacted with water containing a catalytically effective amount of a novel catalyst to achieve faster germination and/or a higher germination rate. The resultant plants are also more vigorous and resistent to disease and/or adverse environmental conditions. In a preferred variant, the water may also contain water soluble catalyst treated lignite. The catalyst is prepared by a process including the steps of admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. The preparation of the novel catalyst and the water soluble catalyst treated lignite is described in detail hereinafter.
    Type: Grant
    Filed: November 8, 1976
    Date of Patent: September 26, 1978
    Assignee: CAW Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4092145
    Abstract: Cut flowers are intimately contacted with water containing a catalytically effective amount of a novel catalyst to prolong their life or beauty. In a preferred variant, the water may also contain water soluble catalyst treated lignite. The catalyst is prepared by a process including the steps of admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. The preparation of the novel catalyst and the water soluble catalyst treated lignite is described in detail hereinafter.
    Type: Grant
    Filed: December 14, 1976
    Date of Patent: May 30, 1978
    Assignee: Caw Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4084938
    Abstract: Solid carbonaceous fossil fuels such as coal, lignite and peat are treated with an aqueous medium containing a novel catalyst to remove undesirable constituents and produce valuable products. The catalyst is prepared by steps including admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of dissolved water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle-forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. In one variant, combustible sulfur and nitrogen compounds and alkali metal ash are removed, and the resulting treated fuel may be used in urban areas where strict air pollution regulations must be met.
    Type: Grant
    Filed: July 7, 1975
    Date of Patent: April 18, 1978
    Assignee: Caw Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4067712
    Abstract: Plants are grown in soil which has been intimately contacted with water containing a catalytically effective amount of a novel catalyst to improve the fertility thereof. In a preferred variant, the water which is intimately contacted with the soil may also contain catalyst treated lignite. Plants grown in the treated soil are more vigorous and resistant to disease or adverse environmental conditions. The yields are higher in instances where the plants are grown commercially for food or fiber, and the plants have a more pleasing appearance in instances where they are grown for decorative purposes.
    Type: Grant
    Filed: December 10, 1976
    Date of Patent: January 10, 1978
    Assignee: CAW Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4067713
    Abstract: Soil is intimately contacted with water containing a catalytically effective amount of a novel catalyst to improve the fertility thereof. In a preferred variant, the water which is intimately contacted with the soil may also contain catalyst treated lignite. Plants grown in the treated soil are more vigorous and resistant to disease or adverse environmental conditions. The yields are higher in instances where the plants are grown commercially for food or fiber, and the plants have a more pleasing appearance in instances where they are grown for decorative purposes.
    Type: Grant
    Filed: December 10, 1976
    Date of Patent: January 10, 1978
    Assignee: CAW Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4067715
    Abstract: The roots of plants being transplanted are intimately contacted with water containing a catalytically effective amount of a novel catalyst. In a preferred variant, the water may also contain water soluble catalyst treated lignite. The catalyst is prepared by a process including the steps of admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. The preparation of the novel catalyst and the water soluble catalyst treated lignite is described in detail hereinafter. The transplanted plants grow more vigorously and are more resistant to disease and/or adverse environmental conditions.
    Type: Grant
    Filed: December 14, 1976
    Date of Patent: January 10, 1978
    Assignee: CAW Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4067714
    Abstract: Plants are watered with water containing a catalytically effective amount of a novel catalyst to promote growth, yield and/or beauty. The watered plants are more vigorous and resistant to disease and/or adverse environmental conditions. In a preferred variant, the water may also contain water soluble catalyst treated lignite. Plant nutrients may be present in the water and fed to the plants at the time of watering. The catalyst is prepared by a process including the steps of admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles.
    Type: Grant
    Filed: December 13, 1976
    Date of Patent: January 10, 1978
    Assignee: CAW Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4061734
    Abstract: Tissue in warm blooded animals which is damaged and/or infected is treated by administering a therapeutically effective amount of a composition containing a novel catalyst and water soluble catalyst treated lignite. The treatment is also effective in relieving stress and/or shock. In a further variant, warm blooded animals having damaged and/or infected tissue are treated with a composition containing therapeutically effective amounts of at least one antibiotic, the novel catalyst, and the catalyst treated lignite. Novel compositions are provided which contain therapeutic amounts of at least one antibiotic, the catalyst, and the catalyst treated lignite. The novel catalyst and the catalyst treated lignite are prepared by processes described in detail hereinafter.
    Type: Grant
    Filed: October 18, 1976
    Date of Patent: December 6, 1977
    Assignee: CAW Industries, Inc.
    Inventor: John Wesley Willard
  • Patent number: 4059691
    Abstract: The incidence of infectious disease in livestock is reduced and/or stress is relieved by providing the livestock with drinking water containing a catalytically effective amount of a unique catalyst. In a preferred variant, the drinking water may also contain lignite which has been pretreated with the catalyst until it is soluble. The catalyst is prepared by a process including the steps of admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. The preparation of the novel catalyst and the water soluble catalyst treated lignite is described in detail hereinafter.
    Type: Grant
    Filed: November 1, 1976
    Date of Patent: November 22, 1977
    Assignee: Caw Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4029770
    Abstract: Tissue in warm blooded animals which is damaged and/or infected is treated by administering a therapeutically effective amount of a novel catalyst or synergist. The treatment is effective in relieving stress and/or shock. In a further variant warm blooded animals having damaged and/or infected tissue are treated with a composition containing a therapeutically effective amount of at least one antibiotic and the catalyst or synergist. Novel therapeutic compositions are provided which contain at least one antibiotic and an effective amount of the catalyst or synergist.
    Type: Grant
    Filed: August 6, 1976
    Date of Patent: June 14, 1977
    Assignee: CAW Industries, Inc.
    Inventor: John W. Willard, Sr.
  • Patent number: 3984540
    Abstract: Tissue in warm blooded animals which is damaged and/or infected is treated by administering a therapeutically effective amount of a novel catalyst or synergist. The treatment is effective in relieving stress and/or shock. In a further variant warm blooded animals having damaged and/or infected tissue are treated with a composition containing a therapeutically effective amount of at least one antibiotic and the catalyst or synergist. Novel therapeutic compositions are provided which contain at least one antibiotic and an effective amount of the catalyst or synergist.
    Type: Grant
    Filed: March 26, 1974
    Date of Patent: October 5, 1976
    Assignee: CAW Industries, Inc.
    Inventor: John W. Willard, Sr.
  • Patent number: 3951778
    Abstract: Bituminous sands are intimately contacted with an aqueous medium containing a catalytically effective amount of a novel catalyst to separate the bitumin at temperatures below the decomposition point of valuable hydrocarbons contained therein. Usually the temperatures of separation are not higher than 100.degree.C and preferably are about 40.degree.-90.degree.C. The catalyst used in practicing the present invention may be prepared by steps including admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of dissolved water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle-forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst containing micelles.
    Type: Grant
    Filed: March 26, 1974
    Date of Patent: April 20, 1976
    Assignee: CAW Industries, Inc.
    Inventor: John W. Willard, Sr.
  • Patent number: 3931031
    Abstract: Improved surface active compositions are provided which contain a surface active agent and a catalytically effective amount of a novel catalyst. The catalyst is prepared by steps including admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of dissolved water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle-forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. The improved surface active compositions are especially useful as laundry detergents, dish washing detergents, and general household and industrial cleansers.
    Type: Grant
    Filed: August 16, 1973
    Date of Patent: January 6, 1976
    Assignee: CAW Industries, Inc.
    Inventor: John W. Willard, Sr.