Patents Assigned to Celanese International Corporation
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Publication number: 20250066281Abstract: Disclosed is a method for removing acetaldehyde and other permanganate reducing compounds (PRCs) from a process stream in the methanol carbonylation process for making acetic acid. The method includes the steps of forming an azeotrope to reduce the boiling point of the acetaldehyde and other PRCs to facilitate separation of the acetaldehyde and other PRCs from the process. In one embodiment the azeotrope comprises butane and acetaldehyde.Type: ApplicationFiled: November 11, 2024Publication date: February 27, 2025Applicant: Celanese International CorporationInventor: Peter Hanik
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Patent number: 12202793Abstract: A method for catalytic vapor phase oxidation of methanol to formaldehyde may include: passing a feed stream comprising methanol and oxygen through a layered catalyst bed having a first layer comprising a first silver catalyst particles and a second layer comprising a second silver catalyst particles that are different than the first silver catalyst particles, wherein the feed stream passes through the first layer before the second layer, wherein the first silver catalyst particles has a greater reaction activity for converting methanol and oxygen to formaldehyde; and reacting the methanol and the oxygen in the presence of the catalysts to produce a product stream comprising formaldehyde.Type: GrantFiled: November 12, 2020Date of Patent: January 21, 2025Assignee: Celanese International CorporationInventors: Wensheng Chen, Justin Dodson, Steve Alexander, Monty Sinnreich, Randal Jendrzey
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Patent number: 12162830Abstract: Disclosed is a method for removing acetaldehyde and other permanganate reducing compounds (PRCs) from a process stream in the methanol carbonylation process for making acetic acid. The method includes the steps of forming an azeotrope to reduce the boiling point of the acetaldehyde and other PRCs to facilitate separation of the acetaldehyde and other PRCs from the process. In one embodiment the azeotrope comprises butane and acetaldehyde.Type: GrantFiled: April 1, 2020Date of Patent: December 10, 2024Assignee: Celanese International CorporationInventor: Peter Hanik
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Patent number: 12157812Abstract: A colorized and tribologically modified polyoxymethylene polymer composition is disclosed. The polyoxymethylene polymer composition is comprised of a polyoxymethylene polymer in combination with at least one tribological modifier. The tribological modifier may include a fluoropolymer. The polymer composition further contains at least one coloring agent in combination with a color stabilizer. The color stabilizer has been found to dramatically improve color consistency. Polymer articles molded from the polymer composition not only have excellent surface appearance but have excellent low friction characteristics when tested against aluminum.Type: GrantFiled: May 25, 2023Date of Patent: December 3, 2024Assignee: Celanese International CorporationInventors: Qamer Zia, Thomas Seelmann, Kirsten Markgraf
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Patent number: 12146052Abstract: A fiber reinforced thermoplastic polymer composition is disclosed that contains at least one mold release agent. The mold release agent can comprise a polar material and/or a non-polar material. In one embodiment, both a polar wax and a non-polar wax are used. The polymer composition may also contain one or more tribological modifiers. The tribological modifier may comprise an ultra-high molecular weight silicone.Type: GrantFiled: April 20, 2022Date of Patent: November 19, 2024Assignee: CELANESE INTERNATIONAL CORPORATIONInventors: Qamer Zia, Kirsten Markgraf, Dirk Zierer, Patrick Nickolay
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Publication number: 20240368320Abstract: An aqueous copolymer dispersion is obtained by a multi-stage emulsion polymerization process comprising polymerizing in a reaction zone in a first polymerization stage a first monomer composition comprising at least 88 wt % of a viny I ester of a C1 to C18 carboxylic acid and up to 12 wt % ethylene to produce a first stage polymer having Tg>20° C.; and polymerizing in the reaction zone, in a second polymerization stage and in the presence of the first stage polymer, a second monomer composition comprising a vinyl ester of a C1 to C18 carboxylic acid and a C2 to C8 alkyl ester of (meth)acrylic acid to produce a second stage polymer having Tg?20° C. Each of the polymerization stages is conducted in the presence of a stabilizing system comprising at least 0.1 wt % of a protective colloid and at least 0.05 wt % of an ionic surfactant.Type: ApplicationFiled: July 19, 2024Publication date: November 7, 2024Applicant: Celanese International CorporationInventors: Kerstin Wenzel, Narayan Raman, Tsz Ming Tsang, James Martin
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Patent number: 12110370Abstract: A polyester polymer composition is disclosed containing reinforcing fibers and having improved adhesion to elastomeric materials while also being formulated for medical applications and/or food service applications. The polyester polymer composition can contain a blend of different polyester polymers and can be free of hindered phenolic antioxidants. The polyester polymer composition can be used in overmolding applications in which the composition is initially molded into a polymer component and then overmolded with an elastomeric material. The elastomeric material can contain a copolyester elastomer and can serve as a sealing member.Type: GrantFiled: August 29, 2022Date of Patent: October 8, 2024Assignee: Celanese International CorporationInventors: Qamer Zia, Kirsten Markgraf, Dirk Zierer, Patrick Nickolay
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Patent number: 12103209Abstract: A system and process for injection molding polymer articles is described. The system and process are designed to reduce gate blush. In one embodiment, an injection molding device injects a molten polymer composition into a mold cavity adjacent to an interior curved surface on the mold. The flow of the polymer material is parallel to a line that is tangent to the curved surface.Type: GrantFiled: October 30, 2023Date of Patent: October 1, 2024Assignee: CELANESE INTERNATIONAL CORPORATIONInventors: Kent R Miller, Michael P. Kowalski, Bruce M. Mulholland
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Patent number: 12100859Abstract: A polymer composition for producing gel extruded articles is described. The polymer composition contains polyethylene particles combined with a plasticizer and one or more shutdown reducing additives. The shutdown reducing additives decrease the shutdown temperature of polymer articles made from the polymer composition. In one embodiment, the polymer composition is used to form a porous membrane for use of a battery separator.Type: GrantFiled: April 30, 2021Date of Patent: September 24, 2024Assignee: Celanese International CorporationInventors: Christian Ohm, Kirsten Markgraf
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Patent number: 12091525Abstract: The present disclosure is directed to a polyacetal, or polyoxymethylene (POM), base composition which contains an additive package containing additives suitable for food processing applications. Polyacetal or polyoxymethylene polymers are of the class of polymers containing —CH2O-repeat units, useful for molding all different types of products and articles. Of particular advantage, POM produced according to the present disclosure may demonstrate low formaldehyde emissions, extractables, or both, when measured by standard methods without containing any formaldehyde scavenger packages.Type: GrantFiled: May 30, 2019Date of Patent: September 17, 2024Assignee: CELANESE INTERNATIONAL CORPORATIONInventors: Qamer Zia, Kai-Uwe Toennes, Kirsten Markgraf
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Patent number: 12071496Abstract: An aqueous copolymer dispersion is obtained by a multi-stage emulsion polymerization process comprising polymerizing in a reaction zone in a first polymerization stage a first monomer composition comprising at least 88 wt % of a vinyl ester of a C1 to C18 carboxylic acid and up to 12 wt % ethylene to produce a first stage polymer having Tg>20° C.; and polymerizing in the reaction zone, in a second polymerization stage and in the presence of the first stage polymer, a second monomer composition comprising a vinyl ester of a C1 to C18 carboxylic acid and a C2 to C8 alkyl ester of (meth)acrylic acid to produce a second stage polymer having Tg?20° C. Each of the polymerization stages is conducted in the presence of a stabilizing system comprising at least 0.1 wt % of a protective colloid and at least 0.05 wt % of an ionic surfactant.Type: GrantFiled: February 27, 2020Date of Patent: August 27, 2024Assignee: Celanese International CorporationInventors: Kerstin Wenzel, Narayan Raman, Tsz Ming Tsang, James Martin
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Patent number: 11981757Abstract: A high molecular weight polyethylene polymer is formulated so that the polymer is capable of being injection molded. The polyethylene polymer has a Viscosity Number of greater than about 400 ml/g and has a melt flow rate of greater than about 0.9 g/10 min. The polyethylene polymer is of high purity and is particularly well suited for producing medical products.Type: GrantFiled: March 23, 2020Date of Patent: May 14, 2024Assignee: CELANESE INTERNATIONAL CORPORATIONInventors: Christina Schmid, Rainer Walkenhorst
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Publication number: 20240150630Abstract: Adhesives comprising an aqueous polymer dispersion, at least one cross-linker, and optional additives, are provided for film lamination. The adhesives comprise a polymer dispersion comprising at least one salt, at least one ethylenically unsaturated monomer with at least one keto or aldehyde group, and at least one compound with at least two functional groups that are capable to react with the keto or aldehyde groups. The adhesives advantageously provide a strong connection between a transparent plastic film or foil and a substrate such as paper or cardboard while being safer and cheaper.Type: ApplicationFiled: March 21, 2022Publication date: May 9, 2024Applicant: Celanese International CorporationInventor: Matthias JUNK
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Patent number: 11976177Abstract: A polymer composition for producing gel extruded articles is described. The polymer composition contains polyethylene particles combined with a plasticizer and one or more strength enhancing additives. Polymer articles made in accordance with the present disclosure have enhanced strength properties. In one embodiment, the polymer composition is used to form a porous membrane for use as a separator in electronic devices.Type: GrantFiled: June 30, 2021Date of Patent: May 7, 2024Assignee: CELANESE INTERNATIONAL CORPORATIONInventors: Christian Ohm, Fangfang Tao, Man Cheng Li
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Patent number: 11939473Abstract: A thermoplastic vulcanizate composition comprises: (i) a dispersed phase of rubber that is at least partially cured; (ii) a continuous thermoplastic phase including at least one thermoplastic polymer; (iii) a first polysiloxane composition comprising a migratory siloxane polymer physically dispersed in a first thermoplastic material and (iv) a second polysiloxane composition comprising a non-migratory, siloxane polymer bonded to a second thermoplastic material.Type: GrantFiled: December 7, 2018Date of Patent: March 26, 2024Assignee: Celanese International CorporationInventors: Prashant Bhadane, Chad Michael Houghton, Oscar Oansuk Chung, Eric Paul Jourdain, Hang Dong
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Patent number: 11905494Abstract: A fabric detergent formulation is provided. The formulation comprises a preservative system that includes one or more sorbates in an amount of from about 0.01 wt. % to about 0.8 wt. % of the fabric detergent formulation; one or more anionic surfactants, wherein the weight ratio of the anionic surfactants to the sorbates is about 10 or more; and a solvent system that includes water in an amount of from about 50 wt. % to 100 wt. % of the fabric detergent formulation. The pH of the fabric detergent formulation is about 6.5 or more.Type: GrantFiled: February 3, 2021Date of Patent: February 20, 2024Assignee: Celanese International CorporationInventors: Sylvia Nefkens, Aukje van Kooij
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Patent number: 11905401Abstract: In an embodiment, a thermoplastic vulcanizate (TPV) composition is provided. The TPV composition includes a thermoplastic polyolefin; and an ethylene based copolymer rubber, wherein the ethylene based copolymer rubber has: a Mw of from 500,000 g/mol to 3,000,000 g/mol, a Mw/Mn of 4.0 or lower, and a g?vis of 0.90 or greater. In another embodiment, a TPV composition includes a thermoplastic phase and an ethylene-propylene-diene terpolymer, wherein the thermoplastic vulcanizate composition has: a hardness of from 20 Shore A to 60 Shore D; and a stress relaxation slope of ?1 to ?5 (l/min) as measured by an Elastocon stress relaxation instrument.Type: GrantFiled: April 25, 2022Date of Patent: February 20, 2024Assignee: Celanese International CorporationInventors: Antonios K. Doufas, Krishnan Anantha Narayana Iyer, Eric P Jourdain, Michael J. Goncy, Kelly Kirkendall, Katya N. Reyna
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Patent number: 11897996Abstract: A process for forming stabilizing paraformaldehyde can include heating a formaldehyde solution comprising 30 wt % or more formaldehyde to a temperature ranging from about 70° C. to about 130° C.; aging the formaldehyde solution for a sufficient amount of time to polymerize the formaldehyde and form paraformaldehyde; solidifying the paraformaldehyde; and contacting the formaldehyde solution before and/or during heating, the formaldehyde solution during aging, the paraformaldehyde, and/or the solidified paraformaldehyde with an ammonia and/or ammonia hydroxide stabilizer.Type: GrantFiled: September 5, 2019Date of Patent: February 13, 2024Assignee: Celanese International CorporationInventors: John Leslie Ray, Jr., Kenneth Allen Windhorst, Martin Dominic Mancha
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Patent number: 11814508Abstract: A polymer composition for producing gel extruded articles is described. The polymer composition contains polyethylene particles combined with a plasticizer. The polyethylene polymer has a narrow molecular weight distribution. Polymer articles made in accordance with the present disclosure have enhanced strength properties. In one embodiment, the polymer composition is used to form a porous membrane for use as a separator in electronic devices.Type: GrantFiled: August 24, 2021Date of Patent: November 14, 2023Assignee: CELANESE INTERNATIONAL CORPORATIONInventors: Christian Ohm, Arvind Yadav
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Publication number: 20230348639Abstract: Aqueous copolymer dispersions are useful for incorporating into primer formulations. The aqueous copolymer dispersions comprise a vinyl acetate-based copolymer and have a particle size of less than or equal to 120 nanometers. The resulting primer formulations have good penetration in various substrates, and/or water resistance/binding properties.Type: ApplicationFiled: April 8, 2020Publication date: November 2, 2023Applicant: Celanese International CorporationInventors: Harmin MÜLLER, Matthias SEIB, Argiri TSAMI-SCHULTE, Bastiaan VAN VOORN