Patents Assigned to Celanese International Corporation
  • Publication number: 20250066281
    Abstract: Disclosed is a method for removing acetaldehyde and other permanganate reducing compounds (PRCs) from a process stream in the methanol carbonylation process for making acetic acid. The method includes the steps of forming an azeotrope to reduce the boiling point of the acetaldehyde and other PRCs to facilitate separation of the acetaldehyde and other PRCs from the process. In one embodiment the azeotrope comprises butane and acetaldehyde.
    Type: Application
    Filed: November 11, 2024
    Publication date: February 27, 2025
    Applicant: Celanese International Corporation
    Inventor: Peter Hanik
  • Patent number: 12202793
    Abstract: A method for catalytic vapor phase oxidation of methanol to formaldehyde may include: passing a feed stream comprising methanol and oxygen through a layered catalyst bed having a first layer comprising a first silver catalyst particles and a second layer comprising a second silver catalyst particles that are different than the first silver catalyst particles, wherein the feed stream passes through the first layer before the second layer, wherein the first silver catalyst particles has a greater reaction activity for converting methanol and oxygen to formaldehyde; and reacting the methanol and the oxygen in the presence of the catalysts to produce a product stream comprising formaldehyde.
    Type: Grant
    Filed: November 12, 2020
    Date of Patent: January 21, 2025
    Assignee: Celanese International Corporation
    Inventors: Wensheng Chen, Justin Dodson, Steve Alexander, Monty Sinnreich, Randal Jendrzey
  • Patent number: 12162830
    Abstract: Disclosed is a method for removing acetaldehyde and other permanganate reducing compounds (PRCs) from a process stream in the methanol carbonylation process for making acetic acid. The method includes the steps of forming an azeotrope to reduce the boiling point of the acetaldehyde and other PRCs to facilitate separation of the acetaldehyde and other PRCs from the process. In one embodiment the azeotrope comprises butane and acetaldehyde.
    Type: Grant
    Filed: April 1, 2020
    Date of Patent: December 10, 2024
    Assignee: Celanese International Corporation
    Inventor: Peter Hanik
  • Patent number: 12157812
    Abstract: A colorized and tribologically modified polyoxymethylene polymer composition is disclosed. The polyoxymethylene polymer composition is comprised of a polyoxymethylene polymer in combination with at least one tribological modifier. The tribological modifier may include a fluoropolymer. The polymer composition further contains at least one coloring agent in combination with a color stabilizer. The color stabilizer has been found to dramatically improve color consistency. Polymer articles molded from the polymer composition not only have excellent surface appearance but have excellent low friction characteristics when tested against aluminum.
    Type: Grant
    Filed: May 25, 2023
    Date of Patent: December 3, 2024
    Assignee: Celanese International Corporation
    Inventors: Qamer Zia, Thomas Seelmann, Kirsten Markgraf
  • Patent number: 12146052
    Abstract: A fiber reinforced thermoplastic polymer composition is disclosed that contains at least one mold release agent. The mold release agent can comprise a polar material and/or a non-polar material. In one embodiment, both a polar wax and a non-polar wax are used. The polymer composition may also contain one or more tribological modifiers. The tribological modifier may comprise an ultra-high molecular weight silicone.
    Type: Grant
    Filed: April 20, 2022
    Date of Patent: November 19, 2024
    Assignee: CELANESE INTERNATIONAL CORPORATION
    Inventors: Qamer Zia, Kirsten Markgraf, Dirk Zierer, Patrick Nickolay
  • Publication number: 20240368320
    Abstract: An aqueous copolymer dispersion is obtained by a multi-stage emulsion polymerization process comprising polymerizing in a reaction zone in a first polymerization stage a first monomer composition comprising at least 88 wt % of a viny I ester of a C1 to C18 carboxylic acid and up to 12 wt % ethylene to produce a first stage polymer having Tg>20° C.; and polymerizing in the reaction zone, in a second polymerization stage and in the presence of the first stage polymer, a second monomer composition comprising a vinyl ester of a C1 to C18 carboxylic acid and a C2 to C8 alkyl ester of (meth)acrylic acid to produce a second stage polymer having Tg?20° C. Each of the polymerization stages is conducted in the presence of a stabilizing system comprising at least 0.1 wt % of a protective colloid and at least 0.05 wt % of an ionic surfactant.
    Type: Application
    Filed: July 19, 2024
    Publication date: November 7, 2024
    Applicant: Celanese International Corporation
    Inventors: Kerstin Wenzel, Narayan Raman, Tsz Ming Tsang, James Martin
  • Patent number: 12110370
    Abstract: A polyester polymer composition is disclosed containing reinforcing fibers and having improved adhesion to elastomeric materials while also being formulated for medical applications and/or food service applications. The polyester polymer composition can contain a blend of different polyester polymers and can be free of hindered phenolic antioxidants. The polyester polymer composition can be used in overmolding applications in which the composition is initially molded into a polymer component and then overmolded with an elastomeric material. The elastomeric material can contain a copolyester elastomer and can serve as a sealing member.
    Type: Grant
    Filed: August 29, 2022
    Date of Patent: October 8, 2024
    Assignee: Celanese International Corporation
    Inventors: Qamer Zia, Kirsten Markgraf, Dirk Zierer, Patrick Nickolay
  • Patent number: 12103209
    Abstract: A system and process for injection molding polymer articles is described. The system and process are designed to reduce gate blush. In one embodiment, an injection molding device injects a molten polymer composition into a mold cavity adjacent to an interior curved surface on the mold. The flow of the polymer material is parallel to a line that is tangent to the curved surface.
    Type: Grant
    Filed: October 30, 2023
    Date of Patent: October 1, 2024
    Assignee: CELANESE INTERNATIONAL CORPORATION
    Inventors: Kent R Miller, Michael P. Kowalski, Bruce M. Mulholland
  • Patent number: 12100859
    Abstract: A polymer composition for producing gel extruded articles is described. The polymer composition contains polyethylene particles combined with a plasticizer and one or more shutdown reducing additives. The shutdown reducing additives decrease the shutdown temperature of polymer articles made from the polymer composition. In one embodiment, the polymer composition is used to form a porous membrane for use of a battery separator.
    Type: Grant
    Filed: April 30, 2021
    Date of Patent: September 24, 2024
    Assignee: Celanese International Corporation
    Inventors: Christian Ohm, Kirsten Markgraf
  • Patent number: 12091525
    Abstract: The present disclosure is directed to a polyacetal, or polyoxymethylene (POM), base composition which contains an additive package containing additives suitable for food processing applications. Polyacetal or polyoxymethylene polymers are of the class of polymers containing —CH2O-repeat units, useful for molding all different types of products and articles. Of particular advantage, POM produced according to the present disclosure may demonstrate low formaldehyde emissions, extractables, or both, when measured by standard methods without containing any formaldehyde scavenger packages.
    Type: Grant
    Filed: May 30, 2019
    Date of Patent: September 17, 2024
    Assignee: CELANESE INTERNATIONAL CORPORATION
    Inventors: Qamer Zia, Kai-Uwe Toennes, Kirsten Markgraf
  • Patent number: 12071496
    Abstract: An aqueous copolymer dispersion is obtained by a multi-stage emulsion polymerization process comprising polymerizing in a reaction zone in a first polymerization stage a first monomer composition comprising at least 88 wt % of a vinyl ester of a C1 to C18 carboxylic acid and up to 12 wt % ethylene to produce a first stage polymer having Tg>20° C.; and polymerizing in the reaction zone, in a second polymerization stage and in the presence of the first stage polymer, a second monomer composition comprising a vinyl ester of a C1 to C18 carboxylic acid and a C2 to C8 alkyl ester of (meth)acrylic acid to produce a second stage polymer having Tg?20° C. Each of the polymerization stages is conducted in the presence of a stabilizing system comprising at least 0.1 wt % of a protective colloid and at least 0.05 wt % of an ionic surfactant.
    Type: Grant
    Filed: February 27, 2020
    Date of Patent: August 27, 2024
    Assignee: Celanese International Corporation
    Inventors: Kerstin Wenzel, Narayan Raman, Tsz Ming Tsang, James Martin
  • Patent number: 11981757
    Abstract: A high molecular weight polyethylene polymer is formulated so that the polymer is capable of being injection molded. The polyethylene polymer has a Viscosity Number of greater than about 400 ml/g and has a melt flow rate of greater than about 0.9 g/10 min. The polyethylene polymer is of high purity and is particularly well suited for producing medical products.
    Type: Grant
    Filed: March 23, 2020
    Date of Patent: May 14, 2024
    Assignee: CELANESE INTERNATIONAL CORPORATION
    Inventors: Christina Schmid, Rainer Walkenhorst
  • Publication number: 20240150630
    Abstract: Adhesives comprising an aqueous polymer dispersion, at least one cross-linker, and optional additives, are provided for film lamination. The adhesives comprise a polymer dispersion comprising at least one salt, at least one ethylenically unsaturated monomer with at least one keto or aldehyde group, and at least one compound with at least two functional groups that are capable to react with the keto or aldehyde groups. The adhesives advantageously provide a strong connection between a transparent plastic film or foil and a substrate such as paper or cardboard while being safer and cheaper.
    Type: Application
    Filed: March 21, 2022
    Publication date: May 9, 2024
    Applicant: Celanese International Corporation
    Inventor: Matthias JUNK
  • Patent number: 11976177
    Abstract: A polymer composition for producing gel extruded articles is described. The polymer composition contains polyethylene particles combined with a plasticizer and one or more strength enhancing additives. Polymer articles made in accordance with the present disclosure have enhanced strength properties. In one embodiment, the polymer composition is used to form a porous membrane for use as a separator in electronic devices.
    Type: Grant
    Filed: June 30, 2021
    Date of Patent: May 7, 2024
    Assignee: CELANESE INTERNATIONAL CORPORATION
    Inventors: Christian Ohm, Fangfang Tao, Man Cheng Li
  • Patent number: 11939473
    Abstract: A thermoplastic vulcanizate composition comprises: (i) a dispersed phase of rubber that is at least partially cured; (ii) a continuous thermoplastic phase including at least one thermoplastic polymer; (iii) a first polysiloxane composition comprising a migratory siloxane polymer physically dispersed in a first thermoplastic material and (iv) a second polysiloxane composition comprising a non-migratory, siloxane polymer bonded to a second thermoplastic material.
    Type: Grant
    Filed: December 7, 2018
    Date of Patent: March 26, 2024
    Assignee: Celanese International Corporation
    Inventors: Prashant Bhadane, Chad Michael Houghton, Oscar Oansuk Chung, Eric Paul Jourdain, Hang Dong
  • Patent number: 11905494
    Abstract: A fabric detergent formulation is provided. The formulation comprises a preservative system that includes one or more sorbates in an amount of from about 0.01 wt. % to about 0.8 wt. % of the fabric detergent formulation; one or more anionic surfactants, wherein the weight ratio of the anionic surfactants to the sorbates is about 10 or more; and a solvent system that includes water in an amount of from about 50 wt. % to 100 wt. % of the fabric detergent formulation. The pH of the fabric detergent formulation is about 6.5 or more.
    Type: Grant
    Filed: February 3, 2021
    Date of Patent: February 20, 2024
    Assignee: Celanese International Corporation
    Inventors: Sylvia Nefkens, Aukje van Kooij
  • Patent number: 11905401
    Abstract: In an embodiment, a thermoplastic vulcanizate (TPV) composition is provided. The TPV composition includes a thermoplastic polyolefin; and an ethylene based copolymer rubber, wherein the ethylene based copolymer rubber has: a Mw of from 500,000 g/mol to 3,000,000 g/mol, a Mw/Mn of 4.0 or lower, and a g?vis of 0.90 or greater. In another embodiment, a TPV composition includes a thermoplastic phase and an ethylene-propylene-diene terpolymer, wherein the thermoplastic vulcanizate composition has: a hardness of from 20 Shore A to 60 Shore D; and a stress relaxation slope of ?1 to ?5 (l/min) as measured by an Elastocon stress relaxation instrument.
    Type: Grant
    Filed: April 25, 2022
    Date of Patent: February 20, 2024
    Assignee: Celanese International Corporation
    Inventors: Antonios K. Doufas, Krishnan Anantha Narayana Iyer, Eric P Jourdain, Michael J. Goncy, Kelly Kirkendall, Katya N. Reyna
  • Patent number: 11897996
    Abstract: A process for forming stabilizing paraformaldehyde can include heating a formaldehyde solution comprising 30 wt % or more formaldehyde to a temperature ranging from about 70° C. to about 130° C.; aging the formaldehyde solution for a sufficient amount of time to polymerize the formaldehyde and form paraformaldehyde; solidifying the paraformaldehyde; and contacting the formaldehyde solution before and/or during heating, the formaldehyde solution during aging, the paraformaldehyde, and/or the solidified paraformaldehyde with an ammonia and/or ammonia hydroxide stabilizer.
    Type: Grant
    Filed: September 5, 2019
    Date of Patent: February 13, 2024
    Assignee: Celanese International Corporation
    Inventors: John Leslie Ray, Jr., Kenneth Allen Windhorst, Martin Dominic Mancha
  • Patent number: 11814508
    Abstract: A polymer composition for producing gel extruded articles is described. The polymer composition contains polyethylene particles combined with a plasticizer. The polyethylene polymer has a narrow molecular weight distribution. Polymer articles made in accordance with the present disclosure have enhanced strength properties. In one embodiment, the polymer composition is used to form a porous membrane for use as a separator in electronic devices.
    Type: Grant
    Filed: August 24, 2021
    Date of Patent: November 14, 2023
    Assignee: CELANESE INTERNATIONAL CORPORATION
    Inventors: Christian Ohm, Arvind Yadav
  • Publication number: 20230348639
    Abstract: Aqueous copolymer dispersions are useful for incorporating into primer formulations. The aqueous copolymer dispersions comprise a vinyl acetate-based copolymer and have a particle size of less than or equal to 120 nanometers. The resulting primer formulations have good penetration in various substrates, and/or water resistance/binding properties.
    Type: Application
    Filed: April 8, 2020
    Publication date: November 2, 2023
    Applicant: Celanese International Corporation
    Inventors: Harmin MÜLLER, Matthias SEIB, Argiri TSAMI-SCHULTE, Bastiaan VAN VOORN