Patents Assigned to CELANESE SALES GERMANY GMBH
  • Patent number: 11827760
    Abstract: A fiber reinforced polyester polymer composition is disclosed that contains at least one tribological modifier. The tribological modifier may comprise an ultra-high molecular weight silicone alone or in combination with polyytetrafluoroethylene particles. The composition not only has excellent tensile properties but also can produce a low friction surface.
    Type: Grant
    Filed: January 14, 2022
    Date of Patent: November 28, 2023
    Assignee: Celanese Sales Germany GmbH
    Inventors: Qamer Zia, Kirsten Markgraf, Dirk Zierer
  • Patent number: 11780995
    Abstract: A polymer composition for producing gel extruded articles is described. The polymer composition contains polyethylene particles combined with a plasticizer. The polyethylene particles are particularly selected so that the particles rapidly form a homogeneous gel-like material when combined with the plasticizer during gel processing. In one embodiment, the polyethylene used to produce the particles has a relatively low bulk density. Alternatively or in addition, the particles can have a carefully controlled particle size distribution. Polymer articles such as fibers and films can be produced having little to no imperfections.
    Type: Grant
    Filed: December 21, 2020
    Date of Patent: October 10, 2023
    Assignee: Celanese Sales Germany GmbH
    Inventors: Christian Ohm, Rainer Walkenhorst, Patrick Scheibe
  • Patent number: 11407957
    Abstract: A tribologically modified polyoxymethylene polymer composition is disclosed. The polyoxymethylene polymer composition is comprised of a polyoxymethylene polymer in combination with a tribological modifier system. The tribological modifier system may include the combination of a fluoropolymer with a high density polyethylene, such as an oxidized high density polyethylene. The particular formulation provides a synergistic blend of properties. For instance, the polymer composition not only has an excellent surface appearance when molded into articles but has excellent low friction characteristics when tested against aluminum.
    Type: Grant
    Filed: January 17, 2020
    Date of Patent: August 9, 2022
    Assignee: Celanese Sales Germany GmbH
    Inventors: Qamer Zia, Kirsten Markgraf
  • Patent number: 11401416
    Abstract: A polyamide composition comprising a polyamide; a plurality of inorganic fibers; and a flame retardant system comprising a zinc phosphinate and a nitrogen-containing polyphosphate is provided. At thicknesses of from about 0.4 to about 3.2 millimeters, the composition exhibits a Glow Wire Ignition Temperature of about 775° C. or more as determined in accordance with IEC-60695-2-13:2010; a Glow Wire End Product Temperature (without flame) of about 750° C. or more as determined in accordance with IEC-60335-1:2010; a Glow Wire Flammability Index of about 850° C. or more as determined in accordance with IEC-60695-2-12:2010; a V0 rating as determined in accordance with UL94; and/or a comparative tracking index of about 550 volts or more as determined in accordance with IEC 60112:2003.
    Type: Grant
    Filed: October 17, 2018
    Date of Patent: August 2, 2022
    Assignee: Celanese Sales Germany GmbH
    Inventors: Guglielmo Pasetti, Holger Brandt
  • Patent number: 11384238
    Abstract: A polymer composition is described well suited for being combined with relatively short fibers. The fibers, for instance, can have a mean fiber length of less than 1,000 microns, such as less than 700 microns, such as less than 500 microns. The polymer formulation allows for intimate mixing with the fibers without having to use a sizing agent. In one embodiment, the composition contains a polybutylene terephthalate polymer combined with a thermoplastic polymer having lower crystallinity.
    Type: Grant
    Filed: February 8, 2019
    Date of Patent: July 12, 2022
    Assignee: Celanese Sales Germany GmbH
    Inventors: Dirk Zierer, Patrick Nickolay, Tim Feuerstack
  • Patent number: 11292882
    Abstract: A polymer composition for producing gel extruded articles is described. The polymer composition contains polyethylene particles combined with a plasticizer and an acid scavenger. In accordance with the present disclosure, the acid scavenger is an inorganic compound that is insoluble in the plasticizer and/or any extractions solvents used during the process. In one embodiment, the acid scavenger is a magnesium aluminum hydroxide carbonate.
    Type: Grant
    Filed: March 21, 2019
    Date of Patent: April 5, 2022
    Assignee: Celanese Sales Germany GmbH
    Inventors: Christian Ohm, Dominik Schreiber
  • Patent number: 11015031
    Abstract: The present disclosure is generally directed to a fiber reinforced polyoxymethylene polymer composition having extremely low formaldehyde emission characteristics. The polymer composition generally contains reinforcing fibers in an amount from 3% to 70% by weight. The reinforcing fibers are combined with a polyoxymethylene polymer having a relatively high melt volume flow rate. The polymer composition can also contain a coupling agent for better integrating the reinforcing fibers into the polymer matrix. In addition to low emission properties, the polymer composition of the present disclosure displays excellent mechanical properties.
    Type: Grant
    Filed: June 13, 2018
    Date of Patent: May 25, 2021
    Assignee: Celanese Sales Germany GmbH
    Inventor: Kirsten Markgraf
  • Patent number: 10933593
    Abstract: Polymer compositions containing polyethylene particles having a multi-modal molecular weight distribution are disclosed. The polymer compositions are well suited to producing porous substrates through a sintering process. Formulations made according to the present disclosure can produce porous substrates having improved flexibility demonstrated by an increased flexural strength while still retaining excellent pressure drop characteristics.
    Type: Grant
    Filed: August 30, 2018
    Date of Patent: March 2, 2021
    Assignee: Celanese Sales Germany GmbH
    Inventors: Lars Koelling, Christina Schmid, Christian Meermann
  • Patent number: 10875991
    Abstract: A polymer composition for producing gel extruded articles is described. The polymer composition contains polyethylene particles combined with a plasticizer. The polyethylene particles are particularly selected so that the particles rapidly form a homogeneous gel-like material when combined with the plasticizer during gel processing. In one embodiment, the polyethylene used to produce the particles has a relatively low bulk density. Alternatively or in addition, the particles can have a carefully controlled particle size distribution. Polymer articles such as fibers and films can be produced having little to no imperfections.
    Type: Grant
    Filed: August 17, 2018
    Date of Patent: December 29, 2020
    Assignee: Celanese Sales Germany GmbH
    Inventors: Christian Ohm, Rainer Walkenhorst, Patrick Scheibe
  • Patent number: 10829467
    Abstract: A process for producing a cyclic acetal is disclosed. According to the process, a formaldehyde source is combined with an aprotic compound and contacted with a heterogeneous catalyst which causes the formaldehyde source to convert into a cyclic acetal such as trioxane. The catalyst, for instance, may comprise a solid catalyst such as an ion exchange resin. In one embodiment, the process is used for converting anhydrous formaldehyde gas to trioxane. The anhydrous formaldehyde gas may be produced form an aqueous formaldehyde solution by an extractive distillation. The aprotic compound and the formaldehyde solution may be extracted from the reaction product and recycled into the process.
    Type: Grant
    Filed: March 28, 2019
    Date of Patent: November 10, 2020
    Assignee: Celanese Sales Germany GmbH
    Inventors: Joni Sianturi, Hanno Hueckstaedt, Matthias Göring, Damian Feord, Stanley Leonard
  • Patent number: 10731027
    Abstract: The present invention relates to a molding composition, a process for manufacturing the molding composition, and molded parts obtainable from the molding composition. The molding composition can contain at least one polyoxymethylene having terminal OH-groups, at least one polyisocyanate coupling agent, at least one reinforcing fiber, and at least one formaldehyde scavenger. The moldings produced from the molding composition are distinguished by their improved mechanical properties while having low formaldehyde emissions and excellent tensile strength while having a good flex fatigue and creep performance.
    Type: Grant
    Filed: March 31, 2016
    Date of Patent: August 4, 2020
    Assignee: Celanese Sales Germany GmbH
    Inventors: Kirsten Markgraf, Lowell Larson
  • Patent number: 10538717
    Abstract: A tribologically modified polyoxymethylene polymer composition is disclosed. The polyoxymethylene polymer composition is comprised of a polyoxymethylene polymer in combination with a tribological modifier system. The tribological modifier system may include the combination of a fluoropolymer with a high density polyethylene, such as an oxidized high density polyethylene. The particular formulation provides a synergistic blend of properties. For instance, the polymer composition not only has an excellent surface appearance when molded into articles but has excellent low friction characteristics when tested against aluminum.
    Type: Grant
    Filed: October 10, 2017
    Date of Patent: January 21, 2020
    Assignee: Celanese Sales Germany GmbH
    Inventors: Qamer Zia, Kirsten Markgraf
  • Patent number: 10479954
    Abstract: A tribologically modified polyoxymethylene polymer composition is disclosed. The polyoxymethylene polymer composition is comprised of a polyoxymethylene polymer and at least one tribological modifier. The tribological modifier may comprise at least one tribological modifier comprising an ultra-high molecular weight silicone having a kinematic viscosity of greater than 100,000 mm2 s?1. The composition may exhibit a dynamic coefficient of friction against a counter-material of from about 0.01 to about 0.15. The polyoxymethylene polymer compositions provide polymer articles with improved tribological properties and mechanical properties.
    Type: Grant
    Filed: June 21, 2018
    Date of Patent: November 19, 2019
    Assignee: Celanese Sales Germany GmbH
    Inventors: Qamer Zia, Oliver Juenger, Jos Bastiaens, Kirsten Markgraf
  • Patent number: 10196577
    Abstract: A tribologically modified polyoxymethylene polymer composition is disclosed. The polyoxymethylene polymer composition is comprised of a polyoxymethylene polymer and at least one tribological modifier. The tribological modifier may comprise an ultra-high molecular weight silicone having a kinematic viscosity of greater than 100,000 mm2 s?1. When tested against itself, the composition of the present disclosure exhibits an extremely low dynamic coefficient of friction and produces no discernible noise over a very broad temperature range, such as from ?20° C. to 60° C.
    Type: Grant
    Filed: September 30, 2016
    Date of Patent: February 5, 2019
    Assignee: Celanese Sales Germany GmbH
    Inventors: Qamer Zia, Peter Raab, Kirsten Markgraf
  • Patent number: 10030208
    Abstract: A tribologically modified polyoxymethylene polymer composition is disclosed. The polyoxymethylene polymer composition is comprised of a polyoxymethylene polymer and at least one tribological modifier. The tribological modifier may comprise at least one tribological modifier comprising an ultra-high molecular weight silicone having a kinematic viscosity of greater than 100,000 mm2s?1. The composition may exhibit a dynamic coefficient of friction against a counter-material of from about 0.01 to about 0.15. The polyoxymethylene polymer compositions provide polymer articles with improved tribological properties and mechanical properties.
    Type: Grant
    Filed: October 10, 2014
    Date of Patent: July 24, 2018
    Assignee: Celanese Sales Germany GmbH
    Inventors: Qamer Zia, Oliver Juenger, Jos Bastiaens, Kirsten Markgraf
  • Patent number: 9951243
    Abstract: Disclosed are aqueous carpet-coating compositions suitable for use as binders or adhesives in carpet products. Such compositions, prior to being applied to carpet substrates and cured, comprise: A) a selected type of vinyl acetate/ethylene (VAE) copolymer dispersion which has been stabilized with emulsifiers and a cellulose ether-based protective colloid, and B) at least one carbon black based filler in the form of a dispersion/slurry with a solids content between 20 and 70%. These coating compositions exhibit especially desirable initial viscosity and viscosity stability characteristics. Carpet products which utilize such coating compositions to provide binder and/or adhesive layer within the carpet are also disclosed. Such carpet products can have desirable odor-controlling and odor-absorbing properties.
    Type: Grant
    Filed: December 20, 2011
    Date of Patent: April 24, 2018
    Assignee: CELANESE SALES GERMANY GMBH
    Inventors: Harmin Mueller, Paul Stuart Wormald, Paolo Bavaj
  • Patent number: 9920483
    Abstract: The invention relates to copolymer dispersions, comprising: a copolymer of (a) a vinyl ester of an alkanoic acid having from 1 to 13 carbon atoms; (b) ethylene; (c) from 0.5 to 5 pphm of a first cross-linking co-monomer comprising an ethylenically unsaturated monomer comprising an epoxy group; and (d) from 0.55 to 2 pphm of a second functional co-monomer comprising an ethylenically unsaturated dicarboxylic acid, mono- or di-ester thereof or anhydride thereof wherein the copolymer is dispersed in an aqueous medium comprising a stabilizer. The dispersions advantageously provide surprisingly good adhesion characteristics to paper substrates.
    Type: Grant
    Filed: June 12, 2014
    Date of Patent: March 20, 2018
    Assignee: CELANESE SALES GERMANY GMBH
    Inventors: Yanzhong Pan, Cristiana Licheri, Nancy Coulson
  • Patent number: 9902785
    Abstract: In a multi-stage emulsion polymerization process, a first monomer composition comprising from about 60 weight percent to about 95 weight percent of at least one vinyl ester, and from about 5 weight percent to about 40 weight percent ethylene is polymerized in a first stage under ethylene pressure to produce a first stage product having a Tg of less than 20° C. Then, in a second stage, a second monomer composition comprising at least 95 weight percent of a meth(acrylic)ester or a mixture of at least two different (meth)acrylic esters is polymerized in the presence of said first stage product, wherein the (meth)acrylic ester(s) is selected such that the polymer produced by said second monomer composition has a Tg of 5 to 90° C.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: February 27, 2018
    Assignee: CELANESE SALES GERMANY GMBH
    Inventors: Lizandra Belmonte Rodrigues De Castro, Thomas Fichtner, Kerstin Gohr, Stephan Krieger
  • Patent number: 9676958
    Abstract: A copolymer dispersion is described comprising a copolymer derived from a monomer mixture comprising: (a) 88.5 to 94% by weight of at least one vinyl ester of a saturated carboxylic acid; (b) 5 to 10.5% by weight of ethylene; (c) 0.5 to 5% by weight of at least one ethylenically unsaturated acid and/or an anhydride thereof and/or a salt thereof; and (d) 0.5 to 5% by weight of at least one ethylenically unsaturated monomer having at least one crosslinkable functional unit. The weight ratio of vinylester units to ethylene units in the copolymer is between 89:11 and 94:6 and the dispersion is stabilized with at least 1% by weight of an emulsifier, wherein the amounts of monomers and emulsifier refer to the total amount of monomers in the copolymer.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: June 13, 2017
    Assignee: CELANESE SALES GERMANY GMBH
    Inventors: Stefan Nogai, Alistair McLennan
  • Patent number: RE48464
    Abstract: In one embodiment, the invention relates to processes for producing acesulfame potassium. In one embodiment, the process comprises the step of reacting a first reaction mixture to form an amidosulfamic acid salt such as a trialkyl ammonium amidosulfamic acid salt. The first reaction mixture comprises sulfamic acid, an amine, and smaller amounts, if any, acetic acid, e.g., less than 1 wt % (10000 wppm). In terms of ranges, the first reaction mixture may comprise from 1 wppm to 1 wt % acetic acid. The process further comprises the step of reacting the amidosulfamic acid salt with diketene to form an acetoacetamide salt. In preferred embodiments, the amidosulfamic acid salt formation reaction is conducted at pH levels from 5.5 to 7.0. The process further comprises the step of deriving the acesulfame-K from the acetoacetamide salt.
    Type: Grant
    Filed: February 13, 2017
    Date of Patent: March 16, 2021
    Assignee: Celanese Sales Germany GmbH
    Inventors: Michael J. Bayer, Stephan Brietzke, Peter Groer, Christoph Mollenkopf