Patents Assigned to Centrotherm Photovoltaics AG
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Patent number: 10115851Abstract: Solar cell (11; 21; 31) having a dielectric coating arranged on a back side of the solar cell (11; 21; 31) which is at least partly covered by at least one planar contact (12; 22; 32), a boundary line (14; 24; 34) of the at least one planar contact (12; 22; 32) having at least one recess (16a, 16b; 26a, 26b, 26c), and method for producing same.Type: GrantFiled: October 14, 2011Date of Patent: October 30, 2018Assignees: Centrotherm Photovoltaics AG, RCT Solutions GMBHInventors: Andreas Teppe, Adolf Muenzer, Jan Schoene, Mathias Hein, Peter Winter
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Patent number: 10024719Abstract: A measuring object for use in a heating apparatus for the thermal treatment of substrates is described, wherein the measuring object is the substrate to be treated or an object which in use has a substantially known temperature relation to the substrate to be treated, wherein the measuring object comprises a surface having at least one surface area, which acts as a measuring surface for an optical temperature measurement. A predetermined structure in the form of a plurality of recessions is formed in the surface area, in order to influence the emissivity of the surface area.Type: GrantFiled: June 13, 2014Date of Patent: July 17, 2018Assignee: CENTROTHERM PHOTOVOLTAICS AGInventors: Dieter Zernickel, Steffen Mueller
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Patent number: 9865485Abstract: An apparatus and method determines the location of wafer boat plate elements having a plurality of plate elements arranged substantially parallel to each other. At least three sensors are moved along travel paths perpendicular to the plate elements, wherein at least a first travel path is above, at least a second travel path is below the wafer boat and at third travel path is laterally spaced from the first or second travel paths above or below the wafer boat. During this movement the position of the sensors along a respective travel path is determined continuously, and it is determined, in which position a respective plate element enters the measuring area of a sensor and exits the same. A distance between a sensor and an edge of a plate element is measured and the location of a respective plate element is determined by means of the sensor signals.Type: GrantFiled: April 27, 2011Date of Patent: January 9, 2018Assignee: CENTROTHERM PHOTOVOLTAICS AGInventors: Daniel Knopfle, Andreas Hartmann, Ottmar Graf
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Patent number: 9711388Abstract: A substrate holder having a plate element for receiving a substrate includes at least one recess in a first side and spacers in the at least one recess. At least one opening is fluidly connected to the recess and is connectable to an external gas delivery/exhaust unit. At least one notch or channel radially surrounds the recess. At least one opening is fluidly connected to the notch or channel and is connectable to an external gas delivery/exhaust unit. A circumferential web radially surrounds the recess and is located between the recess and the notch or channel. A first circumferential contact surface is formed on the upper side of the web and radially surrounds the recess, such that a substrate abutting against the first contact surface forms an enclosed chamber with the recess. A second circumferential contact surface radially surrounds the notch or channel.Type: GrantFiled: November 11, 2013Date of Patent: July 18, 2017Assignee: Centrotherm Photovoltaics AGInventors: Johann Georg Reichart, Wilhelm Kegel, Günther Kummer, Reinhold Obst, Wilfried Lerch
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Patent number: 9252011Abstract: A method for forming an oxide layer on a substrate is described, wherein a plasma is generated adjacent to at least one surface of the substrate by means of microwaves from a gas containing oxygen, wherein the microwaves are coupled into the gas by a magnetron via at least one microwave rod, which is arranged opposite to the substrate and comprises an outer conductor and an inner conductor. During the formation of the oxide layer, the mean microwave power density is set to P=0.8-10 W/cm2, the plasma duration is set to t=0.1 to 600 s, the pressure is set to p=2.67-266.64 Pa (20 to 2000 mTorr) and a distance between substrate surface and microwave rod is set to d=5-120 mm. The above and potentially further process conditions are matched to each other such that the substrate is held at a temperature below 200° C. and an oxide growth is induced on the surface of the substrate facing the plasma.Type: GrantFiled: July 12, 2012Date of Patent: February 2, 2016Assignee: Centrotherm Photovoltaics AGInventors: Juergen Niess, Wilfried Lerch, Wilhelm Kegel, Alexander Gschwandtner
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Publication number: 20150368789Abstract: A method and an arrangement for providing chalcogens as thin layers on substrates, in particular on planar substrates prepared with precursor layers and composed of any desired materials, preferably on substrates composed of float glass, is achieved by forming an inlet- and outlet-side gas curtain for an oxygen-tight closure of a transport channel in a vapour deposition head, introducing an inert gas into the transport channel for displacing atmospheric oxygen, introducing one or more substrates to be coated, the substrates being temperature-regulated to a predetermined temperature, into the transport channel, introducing a chalcogen vapour/carrier gas mixture from a source into the transport channel at the vapour deposition head above the substrates and forming a selenium layer on the substrates by PVD at a predetermined pressure, and removing the substrates after a predetermined process time has elapsed.Type: ApplicationFiled: August 12, 2015Publication date: December 24, 2015Applicant: CENTROTHERM PHOTOVOLTAICS AGInventors: Dieter SCHMID, Reinhard LENZ, Robert Michael HARTUNG
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Patent number: 9214367Abstract: The application describes an apparatus and a method for the thermal treatment of substrates, in particular thin film substrates for photovoltaic applications. The apparatus comprises at least one substrate carrier for supporting a substrate, a heating unit having at least one heating element for heating a substrate located on the substrate carrier and at least one heating element carrier for supporting the at least one heating element. The heating element carrier is designed to allow a local change in distance between the substrate carrier and the heating element, so as to be able to provide locally different heating intensities. In the method such a change in distance is carried out during the thermal treatment.Type: GrantFiled: December 16, 2011Date of Patent: December 15, 2015Assignee: Centrotherm Photovoltaics AGInventors: Oliver Pursche, Peter Volk
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Patent number: 8907253Abstract: In a method for producing a I-III-VI compound semiconductor layer, a substrate is provided with a coating which has a metallic precursor layer. The coating is kept, for the duration of a process time, at temperatures of at least 350 degrees C. and the metallic precursor layer, in the presence of a chalcogen at an ambient pressure of between 500 mbar and 1500 mbar, is converted into a compound semiconductor layer. The coating is kept at temperatures for the duration of an activation time which attain at least an activation barrier temperature, whereby as the activation barrier temperature a value of at least 600° C. is selected.Type: GrantFiled: October 27, 2010Date of Patent: December 9, 2014Assignee: Centrotherm Photovoltaics AGInventors: Immo Koetschau, Dieter Schmid
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Publication number: 20140051265Abstract: The application describes an apparatus and a method for the thermal treatment of substrates, in particular thin film substrates for photovoltaic applications. The apparatus comprises at least one substrate carrier for supporting a substrate, a heating unit having at least one heating element for heating a substrate located on the substrate carrier and at least one heating element carrier for supporting the at least one heating element. The heating element carrier is designed to allow a local change in distance between the substrate carrier and the heating element, so as to be able to provide locally different heating intensities. In the method such a change in distance is carried out during the thermal treatment.Type: ApplicationFiled: December 16, 2011Publication date: February 20, 2014Applicant: Centrotherm Photovoltaics AGInventors: Oliver Purshce, Peter Volk
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Patent number: 8460468Abstract: A device for doping, deposition or oxidation of semiconductor material at low pressure in a process tube, is provided with a tube closure as well as devices for supplying and discharging process gases and for generating a negative pressure in the process tube. A closure of the process chamber that is gas tight with respect to the process gases and the vacuum tight seal of the end of the tube closure are spatially separated from each other in relation to the atmosphere and are arranged on a same side of the process tube in such a manner that a bottom of a stopper, sealing the process chamber, rests against a sealing rim of the process tube and the tube closure end is sealed vacuum tight by a collar, which is attached to the process tube and against which a door rests sealingly.Type: GrantFiled: August 1, 2012Date of Patent: June 11, 2013Assignee: Centrotherm Photovoltaics AGInventors: Alexander Piechulla, Claus Rade, Robert Michael Hartung
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Publication number: 20130061924Abstract: In a method for producing a solar cell, a layer stack of dielectric layers is applied to a back of a solar cell substrate and the layer stack is heated and is held at temperatures of at least 700° C. during a time period of at least 5 minutes. The novel solar cell has a layer stack of dielectric layers on its back. At least one of the dielectric layers of the layer stack is densified so that its resistivity to firing-through of pastes with glass components is enhanced.Type: ApplicationFiled: March 3, 2011Publication date: March 14, 2013Applicant: CENTROTHERM PHOTOVOLTAICS AGInventors: Adolf Münzer, Andreas Teppe, Jan Schöne, Reinhold Schlosser, Steffen Keller
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Publication number: 20130025539Abstract: A device for doping, deposition or oxidation of semiconductor material at low pressure in a process tube, is provided with a tube closure as well as devices for supplying and discharging process gases and for generating a negative pressure in the process tube. A closure of the process chamber that is gas tight with respect to the process gases and the vacuum tight seal of the end of the tube closure are spatially separated from each other in relation to the atmosphere and are arranged on a same side of the process tube in such a manner that a bottom of a stopper, sealing the process chamber, rests against a sealing rim of the process tube and the tube closure end is sealed vacuum tight by a collar, which is attached to the process tube and against which a door rests sealingly.Type: ApplicationFiled: August 1, 2012Publication date: January 31, 2013Applicant: CENTROTHERM PHOTOVOLTAICS AGInventors: Alexander PIECHULLA, Claus Rade, Robert Michael Hartung
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Publication number: 20130014819Abstract: A method for doping a semiconductor substrate includes heating the semiconductor substrate by irradiation with laser radiation and at the same time diffusing dopant from a dopant source into the semiconductor substrate in heated regions. The semiconductor substrate is heated by the irradiation with laser radiation. A surface portion of the semiconductor substrate that is less than 10% of the total surface of all irradiated regions is melted and recrystallized. There is also provided a solar cell.Type: ApplicationFiled: March 3, 2011Publication date: January 17, 2013Applicant: CENTROTHERM PHOTOVOLTAICS AGInventors: Andreas Teppe, Matthias Geiger, Reinhold Schlosser, Adolf Muenzer, Jan Schoene, Joerg Isenberg, Tino Kuehn, Steffen Keller
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Publication number: 20120289033Abstract: In a method for producing a I-III-VI compound semiconductor layer, a substrate is provided with a coating which has a metallic precursor layer. The coating is kept, for the duration of a process time, at temperatures of at least 350 degrees C. and the metallic precursor layer, in the presence of a chalcogen at an ambient pressure of between 500 mbar and 1500 mbar, is converted into a compound semiconductor layer. The coating is kept at temperatures for the duration of an activation time which attain at least an activation barrier temperature, whereby as the activation barrier temperature a value of at least 600° C. is selected.Type: ApplicationFiled: October 21, 2010Publication date: November 15, 2012Applicant: CENTROTHERM PHOTOVOLTAICS AGInventors: Immo Koetschau, Dieter Schmid
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Method for the removal of doped surface layers on the back faces of crystalline silicon solar wafers
Patent number: 8211323Abstract: The invention relates to a method for the one-sided removal of a doped surface layer on rear sides of crystalline silicon solar wafers. In accordance with the object set, doped surface layers should be able to be removed from rear sides of such solar wafers in a cost-effective manner and with a handling which is gentle on the substrate. In addition, the front side should not be modified. In accordance with the invention, an etching gas is directed onto the rear side surface of silicon solar wafers with a plasma atmospheric pressure.Type: GrantFiled: June 14, 2006Date of Patent: July 3, 2012Assignees: Fraunhofer-Gesellschaft zur Forderung der Angewandten Forschung E.V., Centrotherm Photovoltaics AGInventors: Moritz Heintze, Rainer Moeller, Harald Wanka, Elena Lopez, Volkmar Hopfe, Ines Dani, Milan Rosina -
Patent number: 8048208Abstract: A method and device for separation of chalcogens from waste gases in process installations are provided so that complete and reliable removal of chalcogens occurs continuously during nonstop operation of the process installation in the most effective manner possible. The process installation is connected via a pipeline to an input connector of the device for separation of chalcogens arranged outside of the process installation. The pipeline and the input connector have a heat connection to the process chamber. The device for separation of chalcogens is provided with an outlet connector as well as a gas outlet is equipped with a cooling device so that the input connector is excluded from cooling.Type: GrantFiled: September 11, 2008Date of Patent: November 1, 2011Assignee: Centrotherm Photovoltaics AGInventors: Dieter Schmid, Hans-Peter Voelk, Robert Michael Hartung
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Patent number: 8043946Abstract: A doping mixture for coating semiconductor substrates which are then subjected to a high temperature treatment to form a doped layer includes at least one p- or n-dopant, water and a mixture of two or more surfactants. At least one of the surfactants is nonionic. Also, provided are a method for producing such a doping mixture and the use thereof.Type: GrantFiled: May 31, 2006Date of Patent: October 25, 2011Assignees: Centrotherm Photovoltaics AG, Fraunhofer-Gesellschaft zur Forderung der Angewandten Forschung E.V.Inventors: Daniel Biro, Catherine Voyer, Harald Wanka, Jörg Koriath
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Publication number: 20110214727Abstract: A method for manufacturing a solar cell via a two-stage doping includes the steps of forming an oxide layer, which can be penetrated by a first dopant, on at least one part of the surface of a solar cell substrate, forming an opening in the oxide layer in at least one high-doping region by removing the oxide layer in this high-doping region and diffusing the first dopant into the at least one high-doping region of the solar cell substrate through the opening. The first dopant is diffused into the solar cell substrate through the oxide layer. The diffusing-in through the openings and through the oxide layer takes place at the same time in a common diffusion step and the solar cell substrate is diffused in the common diffusion step in an at least partially hydrophilic state.Type: ApplicationFiled: November 9, 2009Publication date: September 8, 2011Applicant: CENTROTHERM PHOTOVOLTAICS AGInventors: Ainhoa Esturo-Breton, Matthias Geiger, Steffen Keller, Reinhold Schlosser, Catharine Voyer, Johannes Maier, Martin Breselge, Adolf Muenzer, Tobias Friess, Tino Kuehn
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Publication number: 20110017283Abstract: A method deposits a layer of an indium chalcogenide onto a substrate. The method includes the steps of: providing an indium source in a reaction zone, providing a gaseous source of a chalcogen in the reaction zone, and heating the substrate. Thereby in the reaction zone, at a pressure of approximately atmospheric ambient pressure, the indium originating from the indium source and the chalcogen originating from the source of a chalcogen are converted to an indium chalcogenide being deposited onto the surface of the substrate.Type: ApplicationFiled: July 26, 2010Publication date: January 27, 2011Applicant: CENTROTHERM PHOTOVOLTAICS AGInventors: ANDREAS KAMPMANN, IMMO KÖTSCHAU, DIETER SCHMID, DAVID WILLIAM SHEEL
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Patent number: 7850819Abstract: The invention relates to a plasma reactor with high productivity for surface coating or modification of objects and/or substrates by plasma processes in a processing chamber, preferably as vacuum processes at reduced pressure, having an entrance lock to the processing chamber and an exit lock. The invention is to create a plasma reactor of high productivity, which, with uniformly high productivity, will make possible a rapid simple and selective cleaning of the plasma sources and adjacent parts of the processing chamber. According to the invention, two plasma sources (1, 2) are provided, each alternately couplable to a reaction chamber (7) or a re-etching chamber (8). The plasma sources (1, 2) are fixed for this purpose to an alternating means (6) in such manner that the plasma sources (1, 2) are positionable by a rotatory motion of the alternating means (6) in the reaction chamber (7) or the re-etching chamber (8).Type: GrantFiled: April 18, 2005Date of Patent: December 14, 2010Assignee: Centrotherm Photovoltaics AGInventors: Harald Wanka, Johann Georg Reichart, Hans-Peter Voelk