Abstract: A low toxic, biodegradable, water soluble and dispersant series of corrosion inhibitors are described. The method of inhibiting corrosion in aqueous medium by incorporating the inhibitor in PPM is provided. The corrosion inhibitor compromises an acrylic acid and chloroacetic acid adduct of 2-substituted imidazolines or primary, secondary or tertiary amines with carbon chain of twelve to twenty-two saturated or unsaturated carbon atoms. The molar ratio of acrylic acid to chloroacetic acid was methodically changed while keeping the concentration of imidazoline or the amine a constant. The product is made water soluble by raising the pH to 8-9 at the end of the synthesis by adding aqueous sodium hydroxide.
Abstract: A metal salt removal procedure for use with a crude oil flow is disclosed. A small amount of water, and a caustic in the range of 7-12 pH, and preferably 9-12 pH, are injected to form water bubbles surrounded by oil. An ethylene oxide reacted with polypropylene glycol at 350° F. or so yields a water soluble demulsifier added at the rate of a few ppm to the water in oil mix. The added reaction product, a polyol, enables metal salt isolation in the water.
Abstract: The present invention provides compositions of oil-soluble inhibitors suitable for use in inhibiting oil field scale formation. The compositions comprise an acid form of a known scale inhibitor and a tertiary alkyl primary amine. These compositions possess advantages over conventional compositions used for inhibiting oil field scale.
Type:
Grant
Filed:
July 27, 1999
Date of Patent:
April 30, 2002
Assignee:
Champion Technologies, Inc.
Inventors:
James M. Reizer, Michael G. Rudel, Curtis D. Sitz, Rex M. S. Wat, Harry Montgomerie
Abstract: The present disclosure is concerned with inhibiting corrosion in metal, usually steel, equipment which is exposed to oil field production flow including gases, oil, water, and sand. It is injected into the aqueous stream and carried with it to contact and coat the metal surfaces. It includes a corrosion inhibitor including at least one sulfur amine based on the equation:R--X(C.sub.2 H.sub.4 NZ).sub.n C.sub.2 H.sub.4 NYIn which R is a C12-36 hydrocarbon;X is an amide-CO--NH-- or 5 membered cyclic imidazoline ring;Z is H or Y; Y is SO.sub.2 ;and .sub.n is an integer from 1 to 8.
Abstract: A corrosion inhibitor comprising a dispersant, an imidazoline, an amide, an alkyl pyridine and a heavy aromatic solvent. The resultant blend effectively inhibits corrosion of flow lines containing low pH mixtures of hydrocarbons, water, and acid gases.
Abstract: A corrosion inhibitor comprising a dispersant, an imidazoline, an amide, an alkyl pyridine and a heavy aromatic solvent. The resultant blend effectively inhibits corrosion of flow lines containing low pH mixtures of hydrocarbons, water, and acid gases.
Abstract: The invention is an effective, easy to produce, and economical corrosion inhibitor which can be used in a variety of environments. The corrosion inhibitor of the present invention is the salt of certain tertiary amines. The corrosion inhibitor is the reaction product of one or more tertiary amines and certain carboxylic acids, preferably a mixture of mercaptocarboxylic and carboxylic acids.
Abstract: The present invention relates to a specific type of phosphate ester that is as effective or more effective than corrosion inhibitors available in the past. In accordance with the invention, these corrosion inhibitors are highly effective alone or when blended with other specific compounds for protection of ferrous metals against attack by a corrosive environment. More particularly, the inhibitors of the present invention are the reaction products of ethoxylated, propoxylated, or butoxylated alcohols or phenols with phosphating agents.
Abstract: The present invention relates to blends of individual corrosion inhibitors with phosphate esters for protection of ferrous metals against attack by a corrosive environment. These blends are synergistically more effective than each of the individual corrosion inhibitors. The phosphate esters of the present invention are the reaction products of ethoxylated, propoxylated, or butoxylated alcohols or phenols with phosphating agents. Other corrosion inhibitors suitable for blending with the phosphate esters include fatty amines, poly amides, imidazolines, poly imidazolines, quaternary amines, poly quats and dimer, trimer, and polymeric acids. Phosphate esters may comprise any portion of the total amount of corrosion inhibitors in the blend, but the preferred concentration is from about 5 to about 50 weight percent phosphate ester. The corrosion inhibitor blends may be diluted to any concentration with solvents or other fluids as necessary for particular applications.
Abstract: The present invention relates to a method and a solution for use in downhole drilling to reduce the torque necessary to rotate the drill string. The solution comprises a sulfonate according to the formula (RSO.sub.3).sub.x Me.sup.x, where R is selected from the group consisting of an alkyl group, an aryl group, an alkylaryl group, and mixtures thereof having a molecular weight between about 280 and about 650, x is the number of (RSO.sub.3) groups, and Me.sup.x is a metal ion having a valence x. The solution is pumped down a drill string as a slug in order to coat solids which accumulate in the well and allow them to be removed along with the drilling fluid.
Abstract: In testing for pipeline corrosion, a test loop is provided. The loop has three parallel legs, each having a corrosion test cell. The three parallel legs provide flow at different velocities. Corrosion inhibitor is injected and data is collected from the test cells so that the correlation between fluid flow temperature, pressure and valocity of the fluid flow.