Patents Assigned to Changchun Institute of Applied Chemistry Chinese Academy of Science
  • Publication number: 20150231273
    Abstract: A CDDP complex is formed by complexation of CDDP and a polymer having a structure of Formula (I). The CDDP complex has good biocompatibility and is degradable. A side chain of the polymer is grafted with polyethylene glycol, which gives the CDDP complex good dissolvability. When dissolved in an aqueous medium, the CDDP is protected by a hydrophilic polyethylene glycol chain segment and a hydrophobic amino acid chain segment, which can effectively avoid a sudden release of the CDDP due to the influence of the blood circulation system after intravenous injection, thus improving the stability of the CDDP complex. A carboxyl group contained in the CDDP complex has pH value sensitivity and tends to be deprotonated in a low pH environment, which is advantageous for promoting the release of a drug, and improving the efficiency of the drug.
    Type: Application
    Filed: March 26, 2013
    Publication date: August 20, 2015
    Applicant: CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCE
    Inventors: Zhaohui Tang, Haiyang Yu, Wantong Song, Mingqiang Li, Xiuli Zuang, Xuesi Chen
  • Patent number: 9045689
    Abstract: The invention relates to a yellow light afterglow material and a preparation method thereof as well as an LED illuminating device using the same. The yellow light afterglow material comprises the chemical formula of aY2O3.bAl2O3.cSiO2:mCe.nB.xNa.yP, where a, b, c, m, n, x and y are coefficients, and a is not less than 1 but not more than 2, b is not less than 2 but not more than 3, c is not less than 0.001 but not more than 1, m is not less than 0.0001 but not more than 0.6, n is not less than 0.0001 but not more than 0.5, x is not less than 0.0001 but not more than 0.2, and y is not less than 0.0001 but not more than 0.5; wherein Y, Al and Si are substrate elements, and Ce, B, Na and P are activators. The yellow light afterglow material is prepared by the following steps: weighing oxides of elements or materials which can generate oxides at high temperature by molar ratio as raw materials, evenly mixing and then sintering the raw materials at 1200-1700° in a reducing atmosphere.
    Type: Grant
    Filed: November 9, 2009
    Date of Patent: June 2, 2015
    Assignees: SICHUAN SUNFOR LIGHT CO., LTD., CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES
    Inventors: Hongjie Zhang, Ming Zhang, Chengyu Li, Kun Zhao, Hao Zhang
  • Publication number: 20140364580
    Abstract: The invention provides a metal alkoxide complex of Formula (I), wherein X, M, R1, R2, R3, m, n, y and z are as defined in the Description. The invention also provides a catalyst composition comprising the metal alkoxide complex and a hydroxy-containing compound, wherein the molar ratio of the metal alkoxide complex to the hydroxy-containing compound is 1:01-1000. The invention also provides a production method of poly-?- caprolactone or polyactide, wherein an ?-caprolactone monomer or a lactide monomer is reacted in the presence of the metal alkoxide complex or catalyst composition to obtain poly-?-caprolactone or polylactide. The metal alkoxide complex and the catalyst composition thereof can be used to catalyze the synthesis of poly-?- caprolactone or polylactide with a high efficiency.
    Type: Application
    Filed: September 11, 2012
    Publication date: December 11, 2014
    Applicant: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
    Inventors: Dongmei Cui, Xinli Liu, Bo Liu, Shihui Li, Dongtao Liu, Chunji Wu
  • Publication number: 20140170039
    Abstract: The present invention relates to a process of separating and purifying thorium by solvent extraction, comprising: 1) mixing a thorium enrichment with an inorganic acid to produce a feed; 2) mixing a neutral phosphorus extractant with an organic solvent to obtain an organic phase; 3) extracting from the feed with the organic phase to obtain a loaded organic phase; 4) scrubbing the loaded organic phase with a scrubbing solution and then back-extracting thorium with a stripping solution to obtain a thorium solution; 5) mixing the thorium solution with an oxalate to obtain a precipitate, which is then sintered to obtain thorium oxide. The present process allows to increase the purity of thorium from 80%-99% to 99.99% or more with a yield of more than 98%.
    Type: Application
    Filed: February 26, 2013
    Publication date: June 19, 2014
    Applicant: Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
    Inventor: Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
  • Publication number: 20130221870
    Abstract: An Alternate Current (AC) white Light-Emitting Diode (LED) device is provided, which belongs to the technical field of white LED manufacturing. The problem to be solved by the present invention is to low-costly overcome a series of deficiencies such as the stroboflash of an AC driven LED, and the heat dissipation difficulty caused by an integrated packaging of multiple LEDs. A white LED unit includes an LED chip and a light emitting material that can emit light when being excited by the LED chip. The luminous lifetime of the light emitting material is 1-100 ms. The LED chip only comprises one PN junction. The light emitted by the LED chip is mixed with the light emitted by the light emitting material to form white light. The white LED unit is driven by AC with a frequency not more than 100 Hz. The white LED device of prevent invention uses the single PN junction chip, rather than the prior integrated packaged AC multi-LED chip.
    Type: Application
    Filed: March 1, 2011
    Publication date: August 29, 2013
    Applicants: CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES, SICHUAN SUNFOR LIGHT CO., LTD.
    Inventors: Hongjie Zhang, Ming Zhang, Chengyu Li, Kun Zhao, Dongming Li, Li Zhang
  • Patent number: 8394901
    Abstract: An isoprene or butadiene cis 1,4-selective polymerization catalyst system together with its polymerization method is provided. This catalyst system is composed of NCN-imine pincer type rare earth metal complex of formula [2,6-(CH?N—R1)2-4-R2-1-C6H2]LnX2(THF)n and alkylating reagent. In an hydrocarbon solvent or under bulk conditions, at a polymerization temperature in a range of ?20-120° C., the conjugated diene is polymerized by using the catalyst system, to produce polyisoprene and polybutadiene having controllable number-average molecular weight, molecular weight distribution of 3.0 or less than, and cis 1,4-content of 95% or more, even 99% or more. The crude rubber and vulcanized rubber of the polyisoprene have high strength, stretching crystallization capability and transparency.
    Type: Grant
    Filed: April 28, 2009
    Date of Patent: March 12, 2013
    Assignee: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
    Inventors: Dongmei Cui, Xinli Liu, Dongtao Liu, Wei Gao, Shihui Li, Lingfang Wang, Zhichao Zhang
  • Patent number: 8350072
    Abstract: The invention provides a method for producing soluble neodymium chloride complex using neodymium chloride aqueous solution as raw material, thereby avoiding the use of anhydrous neodymium chloride, simplifying the synthesis process and reducing the cost for synthesizing neodymium chloride complex. The neodymium chloride complex produced by this method is soluble not only in polar solvent, but also in nonpolar solvent. Such neodymium chloride complex also has good dissolvability in aliphatic hydrocarbon solvent which has relatively weaker solution power, and even in aliphatic hydrocarbon solvent with 6 or less carbon atoms which has even lower solution power. Since neodymium chloride complex is soluble in aliphatic hydrocarbon solvent, its transportation may be conducted, which is convenient for industrial application and contributes to improve the utilization efficiency of rare earth.
    Type: Grant
    Filed: November 2, 2010
    Date of Patent: January 8, 2013
    Assignee: CHangchun Institute of Applied Chemistry Chinese Academy of Sciences
    Inventors: Jifu Bi, Xuequan Zhang, Liansheng Jiang, Hongguang Cai, Bei Wang, Chunyu Zhang, Lihua Na, Quanquan Dai, Changliang Fan
  • Publication number: 20120181566
    Abstract: The invention relates to a yellow light afterglow material and a preparation method thereof as well as an LED illuminating device using the same. The yellow light afterglow material comprises the chemical formula of aY2O3.bAl2O3.cSiO2:mCe.nB.xNa.yP, where a, b, c, m, n, x and y are coefficients, and a is not less than 1 but not more than 2, b is not less than 2 but not more than 3, c is not less than 0.001 but not more than 1, m is not less than 0.0001 but not more than 0.6, n is not less than 0.0001 but not more than 0.5, x is not less than 0.0001 but not more than 0.2, and y is not less than 0.0001 but not more than 0.5; wherein Y, Al and Si are substrate elements, and Ce, B, Na and P are activators. The yellow light afterglow material is prepared by the following steps: weighing oxides of elements or materials which can generate oxides at high temperature by molar ratio as raw materials, evenly mixing and then sintering the raw materials at 1200-1700° in a reducing atmosphere.
    Type: Application
    Filed: November 9, 2009
    Publication date: July 19, 2012
    Applicants: CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES, SICHUAN SUNFOR LIGHT CO., LTD.
    Inventors: Hongjie Zhang, Ming Zhang, Chengyu Li, Kun Zhao, Hao Zhang
  • Patent number: 8119702
    Abstract: The present invention provides a resin composition consisting of a functionalized polypropylene (PP) and a functionalized styrenic thermoplastic elastomer (TPS). The functionalized PP is a PP grafted with N-vinyl pyrrolidone (NVP) and glycidyl methacrylate (GMA), and the functionalized TPS is a TPS grafted with acrylamide or methacrylamide. The functionalized PP and the functionalized TPS are subjected to melt blending to obtain the resin composition with a slight cross-linking structure due to the reaction between GMA and acrylamide or methacrylamide, therefore the resin composition presents good physical properties. Besides, the resin composition without additional plasticizer or other small molecular organic compounds can be utilized in blood bags, blood transfusion and collection apparatuses, etc. Thus, it does not release small molecular substances which are of potential harm to human body during use.
    Type: Grant
    Filed: September 27, 2010
    Date of Patent: February 21, 2012
    Assignee: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
    Inventors: Shifang Luan, Jinghua Yin, Zhongzhi Li, Jianwei Wang, E Zhang, Huawei Yang
  • Publication number: 20110288236
    Abstract: The present invention provides a resin composition consisting of a functionalized polypropylene (PP) and a functionalized styrenic thermoplastic elastomer (TPS). The functionalized PP is a PP grafted with N-vinyl pyrrolidone (NVP) and glycidyl methacrylate (GMA), and the functionalized TPS is a TPS grafted with acrylamide or methacrylamide. The functionalized PP and the functionalized TPS are subjected to melt blending to obtain the resin composition with a slight cross-linking structure due to the reaction between GMA and acrylamide or methacrylamide, therefore the resin composition presents good physical properties. Besides, the resin composition without additional plasticizer or other small molecular organic compounds can be utilized in blood bags, blood transfusion and collection apparatuses, etc. Thus, it does not release small molecular substances which are of potential harm to human body during use.
    Type: Application
    Filed: September 27, 2010
    Publication date: November 24, 2011
    Applicant: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
    Inventors: Shifang Luan, Jinghua Yin, Zhongzhi Li, Jianwei Wang, E Zhang, Huawei Yang
  • Publication number: 20110160473
    Abstract: The invention provides a method for producing soluble neodymium chloride complex using neodymium chloride aqueous solution as raw material, thereby avoiding the use of anhydrous neodymium chloride, simplifying the synthesis process and reducing the cost for synthesizing neodymium chloride complex. The neodymium chloride complex produced by this method is soluble not only in polar solvent, but also in nonpolar solvent. Such neodymium chloride complex also has good dissolvability in aliphatic hydrocarbon solvent which has relatively weaker solution power, and even in aliphatic hydrocarbon solvent with 6 or less carbon atoms which has even lower solution power. Since neodymium chloride complex is soluble in aliphatic hydrocarbon solvent, its transportation may be conducted, which is convenient for industrial application and contributes to improve the utilization efficiency of rare earth.
    Type: Application
    Filed: November 2, 2010
    Publication date: June 30, 2011
    Applicant: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
    Inventors: Jifu Bi, Xuequan Zhang, Liansheng Jiang, Hongguang Cai, Bei Wang, Chunyu Zhang, Lihua Na, Quanquan Dai, Changliang Fan
  • Patent number: 7871855
    Abstract: This invention relates to the use of axial substituted phthalocyanine compound as a semiconductor layer between the source/drain electrodes of organic thin-film transistor. The centre ligand of the axial substituted phthalocyanine compound is an atom with 3 valences or higher, and the axial ligands are chlorine, fluorine, or oxygen which can be connected with the centre ligands of axial substituted phthalocyanine compounds. Crystalline Film with high quality can be prepared on an organic substrate from the axial substituted phthalocyanine compound using vapor deposition process. These crystalline films have high carrier mobility, rich energy level, and stable performances and are easy for integrated process. The field effect mobility and the on/off Ratio of the organic thin-film transistor are 0.01 cm2/Vs or more and higher than 105, respectively.
    Type: Grant
    Filed: January 17, 2008
    Date of Patent: January 18, 2011
    Assignee: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
    Inventors: Donghang Yan, De Song, Feng Zhu, Bo Yu
  • Patent number: 7744814
    Abstract: Methods for producing a magnesium-rare earth intermediate alloy, which belongs to the technical field of molten salt electrolytic metallurgical technology. In one embodiment, the method comprises subjecting magnesium chloride, lanthanum praseodymium cerium chloride and potassium chloride to an electrolysis, and adding additional lanthanum praseodymium cerium chloride and magnesium chloride during the electrolysis. In the electrolysis process, neither metal magnesium nor rare earth metal is used, only the chlorides of rare earths and magnesium are used and the rare earth ions and the magnesium ions are co-electrodeposited on the cathode, so as to obtain the intermediate alloy having a melting point close to the eutectic temperature of the rare earth and magnesium. The method has various advantages including but not limited to high operability, simple process and equipment, stable quality of product by mass production and easy for commercial scale production.
    Type: Grant
    Filed: December 23, 2008
    Date of Patent: June 29, 2010
    Assignee: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
    Inventors: Jian Meng, Daqing Fang, Deping Zhang, Jiacheng Shen, Dingxiang Tang, Hongjie Zhang
  • Patent number: 7723449
    Abstract: The present invention relates to a catalyst for synthesizing a polypropylene with a wide molecular weight distribution and use of the same. The catalyst comprises magnesium halide, titanium-containing compound, and an organic phosphate type electron donor compound. By the catalyst according to the present invention, a propylene polymer with a wide molecular weight distribution, easily controllable isotacticity and good processing properties can be synthesized.
    Type: Grant
    Filed: July 3, 2008
    Date of Patent: May 25, 2010
    Assignee: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
    Inventors: Chunyu Zhang, Hongguang Cai, Bin Chen, Yuping Yuan, Qiaofeng Zhang, Weimin Dong, Xuequan Zhang
  • Patent number: 7708937
    Abstract: A high-strength, high-toughness, weldable and deformable rare earth magnesium alloy comprised of 0.7˜1.7% of Ym, 5.5˜6.4% of Zn, 0.45˜0.8% of Zr, 0.02% or less of the total amount of impurity elements of Si, Fe, Cu and Ni, and the remainder of Mg, based on the total weight of the alloy. During smelting, Y, Ho, Er, Gd and Zr are added in a manner of Mg—Y-rich, Mg—Zr intermediate alloys into a magnesium melt; Zn is added in a manner of pure Zn, and at 690˜720° C., a round bar was cast by a semi-continuous casting or a water cooled mould, then an extrusion molding was performed at 380˜410° C. after cutting. Before the extrusion, the alloy is treated by the solid-solution treatment at 480˜510° C. for 2˜3 hours, however, the alloy can also be extrusion molded directly without the solid-solution treatment.
    Type: Grant
    Filed: April 17, 2008
    Date of Patent: May 4, 2010
    Assignee: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
    Inventors: Jian Meng, Daqing Fang, Deping Zhang, Dingxiang Tang, Huayi Lu, Lianshan Zhao, Wei Sun, Xin Qiu, Hongjie Zhang
  • Publication number: 20090263271
    Abstract: A high-strength, high-toughness, weldable and deformable rare earth magnesium alloy comprised of 0.7˜1.7% of Ym, 5.5˜6.4% of Zn, 0.45˜0.8% of Zr, 0.02% or less of the total amount of impurity elements of Si, Fe, Cu and Ni, and the remainder of Mg, based on the total weight of the alloy. During smelting, Y, Ho, Er, Gd and Zr are added in a manner of Mg—Y-rich, Mg—Zr intermediate alloys into a magnesium melt; Zn is added in a manner of pure Zn, and at 690˜720° C., a round bar was cast by a semi-continuous casting or a water cooled mould, then an extrusion molding was performed at 380˜410° C. after cutting. Before the extrusion, the alloy is treated by the solid-solution treatment at 480˜510° C. for 2˜3 hours, however, the alloy can also be extrusion molded directly without the solid-solution treatment.
    Type: Application
    Filed: April 17, 2008
    Publication date: October 22, 2009
    Applicant: CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES
    Inventors: Jian Meng, Daqing Fang, Deping Zhang, Dingxiang Tang, Huayi Lu, Lianshan Zhao, Wei Sun, Xin Qiu, Hongjie Zhang
  • Patent number: 7597971
    Abstract: The present invention relates to a thermal barrier coating material having the chemical composition of (1?n)CeO2-nZrO2-0.5R2O3, where n is in the range of 0.9?n?0 and R is selected from a group consisting of Nd, Sm, Eu, Gd, Tb and combinations of at least two among them. It possesses a thermal expansion coefficient higher than 12×10?6 K?1 from ambient temperature up to 1200° C. and superior to those of the presently widely-used thermal barrier coating materials. Even if it is subjected to long time calcinations at 1400° C. or is quenched to room temperature, it can still maintain the stable crystal structure. In addition, its thermal expansion trend matches quite well with that of the bond coating alloy. This is beneficial to the elimination of thermal stress generated between the substrate and the ceramic top coating during the thermal cycle and can significantly improve the thermal shock resistance of the coating.
    Type: Grant
    Filed: September 2, 2005
    Date of Patent: October 6, 2009
    Assignee: Changchun Institute of Applied Chemistry Chinese Academy of Science
    Inventors: Hui Dai, Jiayan Li, Xueqiang Cao, Jian Meng
  • Patent number: 7582543
    Abstract: The present invention provides a process for producing a nanosemiconductor luminous material on a liquid-liquid interface, comprising the steps of: a) an oxide of a Group IIB metal and a carboxylic acid with 2-18 carbon atoms or an oleic acid reacting with each other in a solvent at 150-300° C. for 5-30 min, wherein the mol ratio of the oxide to the acid being 1˜5:5˜1; b) adding trioctylphosphine oxide and trioctylphosphine with a mol ratio of trioctylphosphine oxide to trioctylphosphine of 10˜1:1˜10 and a mol ratio of the total mol numbers of trioctylphosphine oxide to the oxide of 10˜1:1˜10; c) adding an aqueous solution of at least one alkaline/alkaline earth metal chalcogenide in a mol ratio of the chalcogenide to the oxide of 10˜1:1˜10; and d) reacting at 20-100° C. for 0.5˜10 h to obtain a sol containing a semiconductor nanoparticle. The produced semiconductor nanoparticle can emit a wavelength-adjustable visible light under a UV lamp.
    Type: Grant
    Filed: March 7, 2005
    Date of Patent: September 1, 2009
    Assignee: Changchun Institute of Applied Chemistry Chinese Academy of Science
    Inventors: Daocheng Pan, Shichun Jiang, Lijia An, Bingzheng Jiang, Xiangling Ji
  • Patent number: 7579091
    Abstract: This invention relates to a white electroluminescent polymeric material and preparation thereof. Based on the physical idea that white light emission can be achieved by regulating the relative luminous intensities of blue- and orange-light emitting units located in a single polymer molecule, the present invention provides three types (main chain type, pendant chain type, and terminal group type) of high efficiency and stable white electroluminescent polymeric material systems.
    Type: Grant
    Filed: January 26, 2005
    Date of Patent: August 25, 2009
    Assignee: Changchun Institute of Applied Chemistry Chinese Academy of Science
    Inventors: Lixiang Wang, Guoli Tu, Jianxin Cao, Jun Liu, Dongge Ma, Xia Bin Jing, Fosong Wang
  • Publication number: 20090116993
    Abstract: This invention relates to an AE series heat resistant compression casting magnesium alloy containing cerium and lanthanum and the composition ingredients and the weight percentage thereof are as follows: Al: 3%˜5%, Ce: 0.4%˜2.6%, La: 0.4%˜2.6%, Mn: 0.2%˜0.6%, and the remainder is magnesium. The raw material of cerium lanthanum mixture of rare earth used is the residual, cheap and overstocked cerium lanthanum mixture of rare earth obtained from common cerium rich mixture of rare earth after the Nd, Rr with high value and good market have been separated. The mechanical performance of this invention at room temperature and high temperature excels that of AE 44 and AZ 91 alloys, and the minimum creep rate of 1.82×10-9 S-1 and the creep percentage elongation in 100 h of 0.17% at the condition of 200° C. and 70 MPa excel these of AE 44 alloy.
    Type: Application
    Filed: June 4, 2008
    Publication date: May 7, 2009
    Applicant: CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES
    Inventors: Jian Meng, Jinghuai Zhang, Dingxiang Tang, Deping Zhang, Daqing Fang