Patents Assigned to CHANGZHOU UNIVERSITY
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Publication number: 20250087778Abstract: A method for preparing a supported catalyst, including mixing waste lithium battery cathode material and biomass uniformly to obtain a mixture, then putting the mixture into a tube furnace for nitrogen purging, and then heating and calcining to obtain a solid sample after carbothermal reduction treatment; hydrothermal stirring the solid sample, followed by filtration to recover a residue, and drying the residue to obtain a mixed sample of Co3O4, TiO2, and biochar, labeled as TCO; ultrasonically dispersing the attapulgite in an acid solution, stirring in a water bath at 80° C.Type: ApplicationFiled: November 25, 2024Publication date: March 13, 2025Applicant: CHANGZHOU UNIVERSITYInventors: Xiazhang LI, Taoli HUHE, Jiyi ZENG, Shixiang ZUO, Xuhua YE, Xiaofei YIN, Chao YAO, Haoguan GUI
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Publication number: 20250074777Abstract: A method for preparing two-dimensional sheet-like Li4SiO4 sorbent, including: obtaining LiCoO2 by performing discharging, aluminum foil stripping, and sieving on waste lithium battery cathode material, and drying; obtaining biomass by freeze-drying waste biomass, and grinding and sieving the freeze-dried waste biomass; mixing LiCoO2 and the biomass uniformly to obtain a mixture, and putting the mixture into a tube furnace for nitrogen purging, heating and calcination, and carbothermal reduction to obtain a solid sample, hydrothermal stirring the solid sample, followed by filtering, and evaporating to obtain Li2CO3; ultrasonically dispersing the attapulgite in an acid solution, and stirring in a water bath at 80° C.Type: ApplicationFiled: November 19, 2024Publication date: March 6, 2025Applicant: CHANGZHOU UNIVERSITYInventors: Xiazhang LI, Taoli HUHE, Shixiang ZUO, Xiaofei YIN, Xiaoshan MENG, Chao YAO, Bingying GAO
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Patent number: 12227879Abstract: A method for preparing a monodomain liquid crystal elastomer smart fiber incudes: during cross-linking process of the liquid crystal elastomer, drawing of liquid crystal elastomer fibers with uniform diameter from a polymer solution when the viscosity of the cross-linked polymer solution increases to a point where filaments can be drawn; heating by an infrared lamp to form filamentous liquid crystal elastomer fiber; natural air drying to remove excess solvent in the fiber; and stretching and collection of the fiber, followed by placement of the fiber, whereby the monodomain liquid crystal elastomer smart fiber is obtained.Type: GrantFiled: July 11, 2023Date of Patent: February 18, 2025Assignees: Changzhou University, Yangzhou University, Yangzhou Technology Innovation Research Center for Carbon Neutrality of Yangzhou UniversityInventors: Ningyi Yuan, Xu Dong, Lvzhou Li, Jianning Ding, Xiaoshuang Zhou, Yaoyao Jiang
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Patent number: 12202748Abstract: The present disclosure relates to a desalination system of photovoltaic direct-driven membrane capacitive deionization. The system includes a photovoltaic direct-driven group and a municipal power grid-connected group. The photovoltaic direct-driven group includes a photovoltaic power collection unit, a power storage unit, a direct-driven power monitoring unit, a voltage adjustment unit, and a membrane capacitive deionization water purification unit. The municipal power grid-connected group includes a grid-connected control unit, a grid busbar unit, and an intelligent detection unit.Type: GrantFiled: August 1, 2022Date of Patent: January 21, 2025Assignees: CHANGZHOU UNIVERSITY, JIANGSU MAYMUSE ENVIRONMENTAL TECHNOLOGY CO. LTDInventors: Yi Zhang, Yihan Zhang, Min Shen, Jianfeng Jiang, Shi Bu
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Patent number: 12145140Abstract: The present disclosure provides a honeycomb catalyst for catalytic oxidative degradation of VOCs prepared by an ultrasonic double-atomization process.Type: GrantFiled: March 22, 2024Date of Patent: November 19, 2024Assignee: CHANGZHOU UNIVERSITYInventors: Xiazhang Li, Chao Yao, Shixiang Zuo, Xuhua Ye, Fengqin Wu, Haoguan Gui, Guanghui Lu, Liang Wang, Zeyue Xu
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Patent number: 12104140Abstract: The present disclosure relates to a polymerizable surfactant with reducibility and a preparation method thereof. The acid anhydride is reacted with a long-chain fatty alcohol to obtain an intermediate of an anhydride monoester, and then the obtained intermediate is reacted with the hydrochloride of dimethylaminohalogenated alkane, and a polymerizable surfactant with reducibility is obtained by post-processing. The polymerizable surfactant can not only play a role as a reactive emulsifier and copolymerize with monomers to obtain a soap-free emulsion, but also form a redox initiation system with peroxide, and conduct redox emulsion polymerization at room temperature.Type: GrantFiled: June 12, 2023Date of Patent: October 1, 2024Assignee: CHANGZHOU UNIVERSITYInventors: Wenyan Huang, Li Jiang, Bibiao Jiang, Qimin Jiang, Hongjun Yang, Xiaoqiang Xue, Qiujie Sun
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Patent number: 12104031Abstract: Embodiments of the present disclosure provide a method of modifying a surface of a film with an inverse miniemulsion, the method comprising: preparing an inverse miniemulsion loaded with a precursor, and then configuring an alkaline miniemulsion, and finally preparing an oxide nanocrystal surface-modified film by a solvothermal process. Embodiments of the present disclosure drive an oxide nanocrystal precursor preloaded in the inverse miniemulsion to migrate to the surface of the film during a solvent thermal treatment by utilizing a pH-responsive polymer that changes the nature of the polymer in the presence of a change in pH, resulting in the formation of the oxide nanocrystal modification on the film surface. The functional film materials modified by the embodiments of the present disclosure have potential applications in the fields of semiconductor, photosensitivity and photoluminescence.Type: GrantFiled: May 9, 2024Date of Patent: October 1, 2024Assignee: CHANGZHOU UNIVERSITYInventor: Zhenqian Zhang
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Patent number: 12098452Abstract: A method for preparing a graphene/copper composite deformed copper-chromium-zirconium alloy layered strip is provided.Type: GrantFiled: April 7, 2024Date of Patent: September 24, 2024Assignee: CHANGZHOU UNIVERSITYInventors: Wei Wei, Libo Yao, Kunxia Wei, Xulong An, Dandan Wang
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Publication number: 20240297301Abstract: Silicon-based composite material is provided, comprising a co-blended material having a porous structure, a sodium bismuth titanate (Bi0.5Na0.5) TiO3 piezoelectric material encapsulated on the surface of the co-blended material, and the co-blended material comprising a co-blended porous Si/C material and a multi-walled carbon nanotube. The silicon-based composite material has a porous structure that provides a multi-path transport channel for lithium ions and provides an effective buffer space for the volume expansion of the silicon; the conductive network constituted by the multi-walled carbon nanotubes CNTs is conducive to enhanced electron transfer which enables excellent reaction kinetics; the network structure composed of CNTs helps lithium ions to maintain structural stability in the process of de-embedded lithium, which in turn maintains high capacity at high currents and has high stability. The external stimulation of the sodium bismuth titanate (Bi0.5Na0.Type: ApplicationFiled: April 22, 2024Publication date: September 5, 2024Applicant: CHANGZHOU UNIVERSITYInventors: Yurong REN, Hongshun ZHAO, Jianbin LI
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Publication number: 20240287270Abstract: Embodiments of the present disclosure provide a method of modifying a surface of a film with an inverse miniemulsion, the method comprising: preparing an inverse miniemulsion loaded with a precursor, and then configuring an alkaline miniemulsion, and finally preparing an oxide nanocrystal surface-modified film by a solvothermal process. Embodiments of the present disclosure drive an oxide nanocrystal precursor preloaded in the inverse miniemulsion to migrate to the surface of the film during a solvent thermal treatment by utilizing a pH-responsive polymer that changes the nature of the polymer in the presence of a change in pH, resulting in the formation of the oxide nanocrystal modification on the film surface. The functional film materials modified by the embodiments of the present disclosure have potential applications in the fields of semiconductor, photosensitivity and photoluminescence.Type: ApplicationFiled: May 9, 2024Publication date: August 29, 2024Applicant: CHANGZHOU UNIVERSITYInventor: Zhenqian ZHANG
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Patent number: 12071360Abstract: Devices for controlling to remove food waste digestion foam are provided. The device includes a digestion tank. The digestion tank includes two hermetically sealed boxes. Each of the two boxes is opened with a liquid inlet connected to an interior of each of the two boxes. A conveying mechanism is connected between the two boxes. The conveying mechanism conveys a gas in the two boxes in a reciprocal manner. The gas in the two boxes is conveyed in the reciprocal manner through the conveying mechanism to generate a pressure difference between the two boxes distributed left and right to remove the foam, which adopts physical defoaming without adding any reagent, is cost-effective and efficient, and does not affect an anaerobic reaction process due to addition of a chemical defoaming agent. The entire device has a simple structure and is easy to operate, and the process is controllable.Type: GrantFiled: August 24, 2023Date of Patent: August 27, 2024Assignee: CHANGZHOU UNIVERSITYInventors: Mingguo Peng, Jianfeng Ma, Yang Qu, Linqiang Mao, Erdeng Du, Fang Zhu, Weibing Zhu, Dongxiao Shi, Qiuya Zhang, Yanqiu Zhang, Lu Zheng
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Publication number: 20240254593Abstract: A method for preparing a graphene/copper composite deformed copper-chromium-zirconium alloy layered strip is provided.Type: ApplicationFiled: April 7, 2024Publication date: August 1, 2024Applicant: CHANGZHOU UNIVERSITYInventors: Wei WEI, Libo YAO, Kunxia WEI, Xulong AN, Dandan WANG
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Publication number: 20240240732Abstract: Embodiments of the present disclosure provide a protective device for a submarine pipeline, comprising an internal pipeline, a protective casing, and a support explosion-proof assembly; wherein the protective casing is disposed outside the internal pipeline, and a cavity body is disposed between the protective casing and the internal pipeline; the support explosion-proof assembly is disposed in the cavity body; the support explosion-proof assembly includes a plurality of support columns, the support columns are disposed in the cavity body, and one end of the support columns away from the protective casing supported on the internal pipeline, the plurality of the support columns disposed at intervals in a circumferential direction along the internal pipeline, and an explosion-proof baffle with elastic deformation capability is disposed between two adjacent support columns.Type: ApplicationFiled: November 15, 2023Publication date: July 18, 2024Applicant: CHANGZHOU UNIVERSITYInventors: Hong JI, Jie GUO, Ke YANG, Zhixiang XING, Juncheng JIANG, Yuchen LIU, Wencong SHEN
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Publication number: 20240226865Abstract: The present disclosure provides a honeycomb catalyst for catalytic oxidative degradation of VOCs prepared by an ultrasonic double-atomization process.Type: ApplicationFiled: March 22, 2024Publication date: July 11, 2024Applicant: CHANGZHOU UNIVERSITYInventors: Xiazhang LI, Chao YAO, Shixiang ZUO, Xuhua YE, Fengqin WU, Haoguan GUI, Guanghui LU, Liang WANG, Zeyue XU
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Publication number: 20240199769Abstract: The present disclosure discloses a method of a functional monomer in emulsion polymerization, belonging to the field of synthesis of functional monomers and methods of emulsion polymerization. The present disclosure obtains functional monomers TDMAMA and TDMAIA by synthesis, which may show different functions at different pH. By adjusting an H+/OH? content in an emulsion with an acid and alkali solution at a certain concentration, it is found that the functional monomers are both an emulsifier, a polymerizing monomer, and a reducing agent at a specific pH, at which the emulsion is stable, and may perform free-radical emulsion polymerization at room temperature, and high molecular weight polymer is obtained through a branched polymerization. When an H+ concentration is less than OH?, the emulsion is unstable and has flocculation, then the polymerization terminates, and emulsion breaking can be realized without adding an additional emulsion breaker.Type: ApplicationFiled: November 21, 2023Publication date: June 20, 2024Applicants: CHANGZHOU UNIVERSITY, CHANGSHU KANGSHIDE DECORATION MATERIALS TECHNOLOGY CO., LTD.Inventors: Wenyan HUANG, Ying ZHOU, Li JIANG, Bibiao JIANG, Jianxin ZHANG, Qimin JIANG, Hongjun YANG, Xiaoqiang XUE
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Patent number: 12011708Abstract: An organic frame material having a cobalt-containing isopoly-molybdic acid metal, a method of manufacturing the same, and applications thereof are provided. The organic frame material having a cobalt-containing isopoly-molybdic acid metal includes a three-dimensional network structure comprising cobalt ions coordinated with 2,3,5,6-tetrafluoro-bis (1,2,4-triazole-1-methyl) benzene ligands and trinuclear molybdate anions. The organic frame material having a cobalt-containing isopoly-molybdic acid metal has higher catalytic activity towards the bulk ring-opening of p-dioxanone. The resulting poly(p-dioxanone) has a weight average molecular weight exceeding 70,000 and is capable of being applied in the field of high polymer materials.Type: GrantFiled: July 26, 2022Date of Patent: June 18, 2024Assignee: Changzhou UniversityInventors: Mingyang He, Shengchun Chen, Qun Chen, Junfeng Qian, Meijun Wei, Chengpeng Zhang
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Patent number: 12016244Abstract: An asymmetric organic photovoltaic acceptor material in an A-D-D?-A type is provided. A backbone containing noncovalent conformational lock is co-constructed with alkoxyindenothiophene and cyclopentadithiophene two-electron donor (D-D?) unit, and the ends are modified with fluorine- and chlorine-atom-substituted 3-(dicyanomethylidene)inden-1-one. The acceptor containing only a simple condensed ring has multiple advantages such as a coplanar backbone, low energy disorder, and J-aggregation tendency, and this type of asymmetric small-molecule acceptor has a controllably adjustable optical bandgap in the range of 1.30-1.45 eV, which is capable of combining with most donor materials to construct highly efficient binary bulk heterojunction organic solar cell. When the donor material is polymer PM6, the photoelectric conversion efficiency of the binary organic solar cells (OSCs) device is as high as 13.67%, with an open-circuit voltage (Voc) of 0.85 eV and energy loss (Eloss) is only 0.50 V.Type: GrantFiled: January 21, 2024Date of Patent: June 18, 2024Assignee: CHANGZHOU UNIVERSITYInventors: Weiguo Zhu, Jianing Zhu, Hua Tan, Mengbing Zhu, Rulin Hao
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Patent number: 12007304Abstract: The present disclosure relates to a device and a method for pipeline leakage detection. The device for pipeline leakage detection includes a metal powder storage box, a plurality of ribs, and a signal collection and processing device. The metal powder storage box is ring-shaped and made of insulating material, which is configured to be sleeved on a pipeline. Metal powder is stored inside of the metal powder storage box, and inner and outer peripheral walls of the metal powder storage box are of mesh structure, which allows the metal powder to be ejected from the metal powder storage box under the push of leakage fluid of the pipeline. The plurality of ribs are made of insulating material, which are distributed evenly along an outer peripheral wall of the metal powder storage box, and fixed on the metal powder storage box respectively, and a plurality of coils arranged in a layer are configured inside the plurality of ribs.Type: GrantFiled: June 7, 2023Date of Patent: June 11, 2024Assignee: CHANGZHOU UNIVERSITYInventors: Ke Yang, Guangyu Liu, Zhixiang Xing, Hong Ji
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Patent number: 12005428Abstract: An isopoly-vanadic acid coordination polymer catalyst, method of manufacturing the same, and application thereof are provided. The isopoly-vanadic acid coordination polymer catalyst has a chemical formula of [Co(atrz)(V2O6)]. The atrz is a 4-amino-1,2,4-triazole ligand, and [V2O6] is a binuclear vanadate anion. The isopoly-vanadic acid coordination polymer catalyst shows strong thermal stability, and it is easy to synthesize with high reproducibility. The isopoly-vanadic acid coordination polymer catalyst has a good catalytic activity towards the bulk ring-opening of p-dioxanone. The resulting poly(p-dioxanone) is stable and uniform. The high molecular weight of the resulting poly(p-dioxanone) has great potential in high polymer materials, in particular the field of medical high polymer materials.Type: GrantFiled: July 26, 2022Date of Patent: June 11, 2024Assignee: Changzhou UniversityInventors: Qun Chen, Zhenxiang Xia, Shengchun Chen, Mingyang He, Junfeng Qian, Meijun Wei
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Publication number: 20240188439Abstract: An asymmetric organic photovoltaic acceptor material in an A-D-D?-A type is provided. A backbone containing noncovalent conformational lock is co-constructed with alkoxyindenothiophene and cyclopentadithiophene two-electron donor (D-D?) unit, and the ends are modified with fluorine- and chlorine-atom-substituted 3-(dicyanomethylidene)inden-1-one. The acceptor containing only a simple condensed ring has multiple advantages such as a coplanar backbone, low energy disorder, and J-aggregation tendency, and this type of asymmetric small-molecule acceptor has a controllably adjustable optical bandgap in the range of 1.30-1.45 eV, which is capable of combining with most donor materials to construct highly efficient binary bulk heterojunction organic solar cell. When the donor material is polymer PM6, the photoelectric conversion efficiency of the binary organic solar cells (OSCs) device is as high as 13.67%, with an open-circuit voltage (Voc) of 0.85 eV and energy loss (Eloss) is only 0.50 V.Type: ApplicationFiled: January 21, 2024Publication date: June 6, 2024Applicant: CHANGZHOU UNIVERSITYInventors: Weiguo ZHU, Jianing ZHU, Hua TAN, Mengbing ZHU, Rulin HAO