Patents Assigned to Chemetall GmbH
  • Patent number: 11958989
    Abstract: Described herein is a method for treatment of at least one surface of a substrate at least partially made of aluminum and/or an aluminum alloy, including at least a step of contacting said surface with an acidic aqueous composition (A) including one or more metal compounds (M) selected from the group of titanium compounds, zirconium compounds, and hafnium compounds and one or more linear polymers (P) containing (m1) N,N-dimethyl (meth)acryl amide, (m2) vinylphosphonic acid, and (m3) (meth)acrylic acid in form of their polymerized monomeric units, the one or more linear polymers (P) being included in the acidic aqueous composition (A) in an amount of 50 to 5000 ppm. Also described herein is an acidic aqueous composition (A), a master batch to produce the acidic aqueous composition (A), a method of using the acidic aqueous composition (A) for treating surfaces, and substrates comprising the treated surfaces.
    Type: Grant
    Filed: September 5, 2019
    Date of Patent: April 16, 2024
    Assignees: Rhodia Operations, Chemetall GmbH
    Inventors: Lars Sebralla, Nawel Souad Khelfallah, Axel Schoene, Marie-Pierre Labeau, Guillaume Gody
  • Patent number: 11434573
    Abstract: Described herein is an aqueous composition for removing cryolitic deposits from plants or parts of plants which serve for the conversion treatment of metal surfaces, said composition including a) at least one mineral acid, and b) at least one dicarboxylic acid of the formula HOOC—(CH2)x—COOH, where x is 0 to 3 and no borate-containing compounds have been added to the composition. Also described herein is a corresponding method for removing cryolitic deposits.
    Type: Grant
    Filed: December 7, 2018
    Date of Patent: September 6, 2022
    Assignee: Chemetall GmbH
    Inventor: Anna Verena Mohr
  • Patent number: 11401428
    Abstract: Aqueous coating compositions are provided. The aqueous compositions include at least one type of organic polymer particles having an average particle size of 10 to 1000 nm, including isocyanate-reactive polymers (A), one or more ketoxime- and/or pyrazole-blocked polyisocyanates (B) including at least one aromatic hydrocarbyl radical or at least one cycloaliphatic hydrocarbyl radical, at least one polyanionic polymer (C), at least one complex fluoride (D) selected from the group consisting of hexa- or tetrafluorides of metallic elements of groups IVb, Vb and VIb of the Periodic Table of the Elements, and at least one aminosilane (E), wherein the aqueous coating compositions have a pH of 3 to 5, and have a total solids content of 5% to 35% by weight. Also provided are processes for producing these aqueous coating compositions, processes for coating metal ion-releasing surfaces with the aqueous coating compositions, and coatings obtained therefrom.
    Type: Grant
    Filed: July 20, 2018
    Date of Patent: August 2, 2022
    Assignee: Chemetall GmbH
    Inventors: Aliaksandr Frenkel, Ron Eilinghoff, Martin Droll
  • Patent number: 11346002
    Abstract: The present invention relates to an acidic aqueous composition for coating metallic surfaces, particularly of aluminium materials, that comprises, besides water and optionally further components, a) at least one compound selected from the group consisting of organoalkoxysilanes, organosilanols, polyorganosilanols, organosiloxanes and polyorganosiloxanes, b) at least one compound selected from the group consisting of titanium, zirconium, hafnium and aluminium compounds and silicon complex fluoride, and c) at least one copolymer which is stable at least in a segment of the pH range below 6 and which comprises, in alternating configuration, monomer units containing at least one carboxylic and/or phosphonic acid group and monomer units containing no acid group. The invention further relates to a corresponding coating method and to the use of the substrates coated by this method.
    Type: Grant
    Filed: December 15, 2015
    Date of Patent: May 31, 2022
    Assignee: Chemetall GmbH
    Inventors: Lars Sebralla, Stefan Birkenheuer, Manfred Walter, Nawel Souad Khelfallah
  • Patent number: 11142654
    Abstract: A composition for applying a clear or translucent and colorless or nearly colorless emissive coating on a metallic surface comprising in a dispersion a) 50 to 300 g/L of at least one of clear or translucent organic polymeric substances of a binder, and b) 30 to 300 g/L of sheet silicate pigments having a TE value for the thermal emissivity of at least 0.40, having a particle size distribution of which d50 is in the range of 0.3 to 80 ?m. Processes for applying the composition and elements prepared therefrom are also disclosed.
    Type: Grant
    Filed: November 3, 2010
    Date of Patent: October 12, 2021
    Assignee: Chemetall GmbH
    Inventors: Noel Smith, Charles J. Gruszka, Aaron Thompson, Michael Deemer
  • Patent number: 11142655
    Abstract: The invention relates to a process for coating metallic surfaces with a composition containing silane/silanol/siloxane/polysiloxane, wherein, in addition to a) at least one compound selected from silanes, silanols, siloxanes and polysiloxanes, b) at least one compound containing titanium, hafnium, zirconium, aluminium and/or boron, and c) at least one type of cation selected from cations of metals of subgroups 1 to 3 and 5 to 8, including lanthanides, and of main group 2 of the periodic table of the elements, and/or at least one corresponding compound, the composition contains at least one substance d) selected from: d1) silicon-free compounds having at least one amino, urea and/or ureido group in each case, d2) anions of nitrite and/or compounds having at least one nitro group, d3) compounds based on peroxide, and d4) phosphorus-containing compounds, anions of at least one phosphate and/or anions of at least one phosphonate, as well as e) water, and f) optionally also at least one organic solvent.
    Type: Grant
    Filed: January 14, 2011
    Date of Patent: October 12, 2021
    Assignee: Chemetall GmbH
    Inventors: Thomas Kolberg, Manfred Walter, Peter Schubach
  • Patent number: 11124674
    Abstract: A method for curing a mixture of a matrix and a curing agent based on sulfur-containing polymers on command and so rapidly that a tack-free surface results. A method for coating a substrate with the composition and of curing a sealant is also provided. The matrix and curing agent containing sulfur-containing polymers. The mixture is an uncured mixture with an isocyanate content, and the matrix is uncured and contains a mercaptan-terminated base polymer based on at least one polyether, polythioether, polysulfide or copolymers thereof. The uncured matrix, the curing agent, or both contain at least one photoinitiator based on sterically-inhibited tertiary amines. The mixture cures in the temperature range of ?10 to +70° C. after the high-energy actinic radiation is applied. Corresponding matrices A, mixtures B, curing agents, sealant systems, and substrates, e.g., aircraft are contemplated.
    Type: Grant
    Filed: June 19, 2019
    Date of Patent: September 21, 2021
    Assignee: Chemetall GmbH
    Inventors: Miroslav Kralev, Björn Sievers, Peter Bons, Francisco Diez
  • Patent number: 11124884
    Abstract: An aqueous composition for reducing corrosive removal of material in pickling of metallic surfaces comprising bare and/or galvanized steel. The composition includes a mixture of a compound of the formula R1O—(CH2)x—C?C—(CH2)y—OR2 in which R1 and R2 are both H, and a compound of the formula R1O—(CH2)x—C?C—(CH2)y—OR2 in which R1 and R2 are each, independently of one another, an HO—(CH2)w— group with w?2. X and y are each, independently of one another, from 1 to 4 in each of the two compounds of the formula R1O—(CH2)x—C?C—(CH2)y—OR2. A process for pickling a metallic surface with reduced corrosive removal of material is disclosed.
    Type: Grant
    Filed: April 28, 2017
    Date of Patent: September 21, 2021
    Assignee: Chemetall GmbH
    Inventor: Anna Verena Mohr
  • Patent number: 11124880
    Abstract: Described herein is a method for phosphating of a metallic surface, wherein a metallic surface, optionally after cleaning and/or activation, is first treated with an acidic, aqueous, substantially nickel-free phosphating composition that includes zinc ions, manganese ions, iron(III) ions and phosphate ions, and is thereafter optionally rinsed and/or dried. Also described herein are a corresponding phosphating composition and a correspondingly phosphate-coated metallic surface.
    Type: Grant
    Filed: January 18, 2017
    Date of Patent: September 21, 2021
    Assignee: Chemetall GmbH
    Inventors: Olaf Dahlenburg, Lisa Schmeier
  • Patent number: 10738383
    Abstract: Described herein is a method for substantially nickel-free phosphating of a metallic surface, wherein a metallic surface, optionally after cleaning and/or activation, is first treated with an acidic aqueous phosphating composition that includes zinc ions, manganese ions, and phosphate ions, and is optionally rinsed and/or dried, and is thereafter treated with an aqueous after-rinse composition that includes at least one kind of metal ion selected from the group consisting of the ions of molybdenum, copper, silver, gold, palladium, tin, antimony, titanium, zirconium, and hafnium and/or at least one polymer selected from the group consisting of the polymer classes of the polyamines, polyethyleneamines, polyanilines, polyimines, polyethyleneimines, polythiophenes, and polypryroles and also mixtures and copolymers thereof, with both the phosphating composition and the after-rinse composition being substantially nickel-free.
    Type: Grant
    Filed: April 7, 2016
    Date of Patent: August 11, 2020
    Assignee: Chemetall GmbH
    Inventors: Olaf Dahlenburg, Frank Hollmann, Lisa Schmeier
  • Publication number: 20190330745
    Abstract: Described herein is an improved process for an anticorrosion pretreatment of a metallic surface including steel, galvanized steel, aluminum, magnesium and/or a zinc-magnesium alloy, wherein the metallic surface is brought into contact with an aqueous composition A including a) from 0.01 to 0.5 g/l of a copolymer and the metallic surface is brought into contact with an acidic aqueous composition B including b1) a compound selected from the group consisting of titanium, zirconium and hafnium compounds, wherein the metallic surface is brought into contact i) firstly with the composition A and then with the composition B, ii) firstly with the composition B and then with the composition A and/or iii) simultaneously with the composition A and the composition B. Also described herein is a corresponding aqueous composition A, an aqueous concentrate for producing this composition, a correspondingly coated metallic surface and a method of using a correspondingly coated metallic substrate.
    Type: Application
    Filed: June 21, 2017
    Publication date: October 31, 2019
    Applicant: Chemetall GmbH
    Inventors: Stefan BIRKENHEUER, Carina HECKER, Oliver SAUER, Daniel SCHATZ
  • Patent number: 10400135
    Abstract: A coating, a method for coating surfaces, and the coated surfaces. The method includes providing a substrate with a cleaned metal surface; contacting and coating the metal surface with an aqueous composition having a ph of from 0.5 to 7.0 and in the form of a dispersion and/or a suspension; optionally rinsing the organic coating; and drying and/or baking the organic coating, or optionally drying the organic coating and coating same with a similar or another coating composition thereto. The composition contains a complex fluoride in a quantity of 1.1 10?6 mol/l to 0.30 mol/l based on the cations. An anionic polyelectrolyte in a quantity of 0.01 to 5.0 wt % based on the total mass of the resulting mixture is added to an anionically stabilized dispersion made of film-forming polymers and/or a suspension made of film-forming inorganic particles.
    Type: Grant
    Filed: November 25, 2013
    Date of Patent: September 3, 2019
    Assignee: Chemetall GmbH
    Inventors: Daniel Wasserfallen, Michael Schwamb, Aliaksandr Frenkel, Vera Sotke, Wolfgang Bremser, Martin Droll, Oliver Seewald, Ron Eilinghoff, Stephanie Gerold, Evgenija Niesen, Lars Schachtsiek, Manuel Traut
  • Patent number: 10392705
    Abstract: Methods for treatment shaped bodies are described herein. The methods generally include contacting at least one shaped body with an aqueous acidic composition to form a conversion layer on a surface of the at least one shaped body, wherein the surface includes iron or steel and a carbon content in a range of 0 to 2.06 wt. % and a chrome content in a range of 0 to <10 wt. % and wherein the surface is optionally galvanized or alloy galvanized. The aqueous acidic composition includes water; from 2 to 500 g/L oxalic acid; and from 0.01 to 20 g/L of at least one catalyst based on guanidine, nitrate or combinations thereof, wherein a pickling removal of the aqueous acidic composition is in a range of 1 to 6 g/m2.
    Type: Grant
    Filed: October 16, 2014
    Date of Patent: August 27, 2019
    Assignee: Chemetall GmbH
    Inventors: Benjamin Güttler, Ralf Schneider, Frank Hollmann, Gorka De Luis Garcia, Iñaki Nieves Quintana, Martin Orben, Norbert Schwinke-Kruse
  • Patent number: 10378120
    Abstract: A method for coating metallic surfaces with aqueous compositions, wherein a silane-based aqueous composition containing at least one silane and/or a related silicon-containing compound and optionally additional components is treated further, for example, at temperatures above 70° C., in a pretreatment step without drying the coating, by using at least one aqueous rinse step after this pretreatment step and then performing an electrodeposition coating, in which at least one surfactant is added at least in the last rinse step of the aqueous rinse steps. Coated metallic surfaces are also described.
    Type: Grant
    Filed: October 23, 2012
    Date of Patent: August 13, 2019
    Assignee: Chemetall GmbH
    Inventors: Thomas Kolberg, Peter Schubach, Manfred Walter, Carola Komp, Michael Dröge
  • Patent number: 10370562
    Abstract: A method for curing a mixture of a matrix and a curing agent based on sulfur-containing polymers on command and so rapidly that a tack-free surface results. A method for coating a substrate with the composition and of curing a sealant is also provided. The matrix and curing agent containing sulfur-containing polymers. The mixture is an uncured mixture with an isocyanate content, and the matrix is uncured and contains a mercaptan-terminated base polymer based on at least one polyether, polythioether, polysulfide or copolymers thereof. The uncured matrix, the curing agent, or both contain at least one photoinitiator based on sterically-inhibited tertiary amines. The mixture cures in the temperature range of ?10 to +70° C. after the high-energy actinic radiation is applied. Corresponding matrices A, mixtures B, curing agents, sealant systems, and substrates, e.g., aircraft are contemplated.
    Type: Grant
    Filed: April 9, 2013
    Date of Patent: August 6, 2019
    Assignee: Chemetall GmbH
    Inventors: Miroslav Kralev, Björn Sievers, Peter Bons, Francisco Diez
  • Patent number: 10280513
    Abstract: The invention relates to a method for coating surfaces, to a corresponding coating, and to the use of the objects coated according to said method. According to the invention, the method has or consists of the following steps: I. providing a substrate with a cleaned surface, II. contacting and coating the surfaces with an aqueous composition in the form of a dispersion and/or suspension, VI. if necessary rinsing the organic coating, and VII. drying and/or baking the organic coating or VIII. if necessary drying the organic coating and carrying out a coating process using a similar or additional coating composition prior to a drying and/or baking process, wherein between step I and step II, the coating process is carried out using an aqueous composition in the form of a dispersion and/or suspension on the basis of a colloidal silicate sol, which incorporates multivalent metal cations, or a silane- or silicate-modified polymer and if necessary a rinsing process is carried out.
    Type: Grant
    Filed: July 16, 2014
    Date of Patent: May 7, 2019
    Assignee: Chemetall GmbH
    Inventors: Daniel Wasserfallen, Michael Schwamb, Aliaksandr Frenkel, Vera Sotke, Wolfgang Bremser, Martin Droll, Oliver Seewald, Ron Eilinghoff, Stephanie Gerold, Evgenija Niesen, Lars Schachtsiek, Manuel Traut, Philipp Klöpzig
  • Patent number: 10174214
    Abstract: The invention relates to a detergent for gentle removal of inks as used for marking in a roll mill, and to markers as used in production for temporary marking. According to the invention, the problem is solved by a detergent which permits the gentle removal of inks or markers from metallic surfaces in the form of a concentrate or a cleaning bath solution containing at least one water-immiscible solvent in an amount of 4 to 200 g/l, at least one anionic and/or nonionic surfactant in an amount of 8-300 g/l, at least one complexing agent in an amount of 1-100 g/l, at least one buffer substance in an amount of 1-100 g/l and at least one water-miscible solvent in an amount of 4-200 g/l in water.
    Type: Grant
    Filed: June 16, 2015
    Date of Patent: January 8, 2019
    Assignee: Chemetall GmbH
    Inventors: Peter Bons, Rüdiger Rein, Jörg Wörner, Miriam Corneli
  • Patent number: 10132759
    Abstract: The invention relates to fissure-detection agents for fault detection according to the penetration method of metallic and/or non-metallic components, which are a microemulsion comprising at least 10 wt. % of water A), at least 0.1 wt. % of at least one dye B), at least 5 wt. % of at least one substantially water-insoluble liquid phase C) and at least 2 wt. % of at least one surfactant D) selected from non-ionic, anionic and/or amphoteric surfactants, the sum of all constituents being 100 wt. %, wherein the fissure-detection agent has a mean particle size in the range of 1 to 250 nm and a transparency of at least 70% at 600 nm. The invention also relates to the production of said fissure-detection agents, to a process for their preparation or/and disposal, and their use.
    Type: Grant
    Filed: October 7, 2014
    Date of Patent: November 20, 2018
    Assignee: Chemetall GmbH
    Inventors: Peter Bons, Rüdiger Rein, Jörg Wörner, Finlay Aiston
  • Patent number: 10093809
    Abstract: The invention relates to a method for coating surfaces, to a corresponding coating, and to the use of the objects coated in accordance with said method. The invention relates to a method for coating metal surfaces of substrates, comprising or consisting of the following steps: I. providing a substrate having a cleaned metal surface, II. contacting and coating metal surfaces with an aqueous composition in the form of a dispersion and/or suspension, IX. optionally rinsing the organic coating, and X. drying and/or baking the organic coating or XI. optionally drying the organic coating and coating with a coating composition of the same type or a further coating composition before a drying process and/or baking process, wherein in step II the coating is performed with an aqueous composition in the form of a dispersion and/or suspension containing 2.5 to 45 wt % of at least one non-ionic stabilized binder and 0.1 to 2.0 wt % of a gelling agent, wherein the aqueous composition has a pH value in the range of 0.
    Type: Grant
    Filed: July 10, 2014
    Date of Patent: October 9, 2018
    Assignee: Chemetall GmbH
    Inventors: Daniel Wasserfallen, Michael Schwamb, Aliaksandr Frenkel, Vera Sotke, Wolfgang Bremser, Martin Droll, Oliver Seewald, Ron Eilinghoff, Stephanie Gerold, Evgenija Niesen, Lars Schachtsiek, Manuel Traut
  • Patent number: 10072338
    Abstract: The present invention provides a surface conditioning composition having a surface conditioning function that is even more superior as compared with conventional surface conditioning compositions. A surface conditioning composition is provided for use in surface conditioning of a metal prior to being subjected to a phosphate-based chemical conversion treatment, in which the surface conditioning composition has a pH of 3 to 12, and includes nearly spherical zinc phosphate particles having an average particle diameter from 0.05 ?m to 3 ?m, and in which the zinc phosphate particles are produced by mixing at least one kind of zinc compound particles selected from the group consisting of zinc oxide, zinc hydroxide, and basic zinc carbonate with phosphoric acid and/or condensed phosphoric acid to allow for their reaction in an acidic aqueous solution having a pH lower than 7, and dispersing and stabilizing by a dispersion means.
    Type: Grant
    Filed: March 7, 2012
    Date of Patent: September 11, 2018
    Assignee: Chemetall GmbH
    Inventors: Toshio Inbe, Yusuke Wada, Masanobu Futsuhara