Patents Assigned to Chemetall GmbH
  • Patent number: 11958989
    Abstract: Described herein is a method for treatment of at least one surface of a substrate at least partially made of aluminum and/or an aluminum alloy, including at least a step of contacting said surface with an acidic aqueous composition (A) including one or more metal compounds (M) selected from the group of titanium compounds, zirconium compounds, and hafnium compounds and one or more linear polymers (P) containing (m1) N,N-dimethyl (meth)acryl amide, (m2) vinylphosphonic acid, and (m3) (meth)acrylic acid in form of their polymerized monomeric units, the one or more linear polymers (P) being included in the acidic aqueous composition (A) in an amount of 50 to 5000 ppm. Also described herein is an acidic aqueous composition (A), a master batch to produce the acidic aqueous composition (A), a method of using the acidic aqueous composition (A) for treating surfaces, and substrates comprising the treated surfaces.
    Type: Grant
    Filed: September 5, 2019
    Date of Patent: April 16, 2024
    Assignees: Rhodia Operations, Chemetall GmbH
    Inventors: Lars Sebralla, Nawel Souad Khelfallah, Axel Schoene, Marie-Pierre Labeau, Guillaume Gody
  • Patent number: 11686000
    Abstract: Described herein is an aqueous, chromium-free composition for a pretreatment of aluminum surfaces, which includes at least one water-soluble phosphorus compound, at least one water-soluble zirconium compound, at least one water-soluble titanium compound, and at least one water-soluble molybdenum compound, a phosphorus compound content being in a range from 15 to 50 mg/l (calculated as phosphorus), a zirconium compound content being in a range from 400 to 600 mg/l (calculated as metal), a titanium compound content being in a range from 85 to 400 mg/l (calculated as metal), and a molybdenum compound content being in a range from 40 to 150 mg/l (calculated as metal). Also described herein are a corresponding method and a correspondingly pretreated component or strip.
    Type: Grant
    Filed: October 25, 2017
    Date of Patent: June 27, 2023
    Assignee: CHEMETALL GMBH
    Inventors: Heiko Hellmers, Thomas Wendel, Norbert Maurus
  • Patent number: 11643731
    Abstract: The present invention relates to a method for substantially nickel-free phosphating of a metallic surface, wherein a metallic surface is treated one after the other with the following compositions: i) with an alkaline, aqueous cleaner composition which comprises at least one water-soluble silicate, and ii) with an acidic, aqueous, substantially nickel-free phosphating composition which comprises zinc ions, manganese ions and phosphate ions. The invention also relates to the above cleaner composition itself and also to a metallic surface phosphate-coated by the above method, and to the use of said surface.
    Type: Grant
    Filed: August 28, 2018
    Date of Patent: May 9, 2023
    Assignee: CHEMETALL GMBH
    Inventors: Olaf Dahlenburg, Thomas Kolberg, Lisa Seider
  • Patent number: 11505705
    Abstract: The invention relates to a method for coating surfaces, to a corresponding coating, and to the use of the objects coated in accordance with said method. The invention relates to a method for coating metal surfaces of substrates, comprising or consisting of the following steps: I. providing a substrate having a cleaned metal surface, II. contacting and coating metal surfaces with an aqueous composition in the form of a dispersion and/or suspension, IX. optionally rinsing the organic coating, and X. drying and/or baking the organic coating or XI. optionally drying the organic coating and coating with a coating composition of the same type or a further coating composition before a drying process and/or baking process, wherein in step II the coating is performed with an aqueous composition in the form of a dispersion and/or suspension containing 2.5 to 45 wt % of at least one non-ionic stabilized binder and 0.1 to 2.0 wt % of a gelling agent, wherein the aqueous composition has a pH value in the range of 0.
    Type: Grant
    Filed: August 31, 2018
    Date of Patent: November 22, 2022
    Assignee: CHEMETALL GMBH
    Inventors: Daniel Wasserfallen, Michael Schwamb, Aliaksandr Frenkel, Vera Sotke, Wolfgang Bremser, Martin Droll, Oliver Seewald, Ron Eilinghoff, Stephanie Gerold, Evgenija Niesen, Lars Schachtsiek, Manuel Traut
  • Patent number: 11492707
    Abstract: Provided herein is a method for specifically adjusting the electrical conductivity of a conversion coating, wherein a metallic surface or a conversion-coated metallic surface is treated with an aqueous composition which comprises at least one kind of metal ions selected from the group consisting of the ions of molybdenum, copper, silver, gold, palladium, tin, and antimony and/or at least one electrically conductive polymer selected from the group consisting of the polymer classes of the polyamines, polyanilines, polyimines, polythiophenes, and polypryrols.
    Type: Grant
    Filed: April 7, 2016
    Date of Patent: November 8, 2022
    Assignee: CHEMETALL GMBH
    Inventors: Olaf Dahlenburg, Frank Hollmann, Michael Droege, Thomas Kolberg, Lisa Schmeier
  • Patent number: 11460065
    Abstract: Described herein is a method for filling seal caps and a corresponding automated device for filling seal caps. The method for filling seal caps includes carrying out the filling of the seal caps using an automated process, wherein positioning a filling unit and/or positioning the seal caps by means of movement in an XYZ coordinate system as well as filling the seal caps is automated, and wherein the seal caps are positioned on a support plate.
    Type: Grant
    Filed: July 25, 2017
    Date of Patent: October 4, 2022
    Assignee: CHEMETALL GMBH
    Inventor: Heinz Burock
  • Patent number: 11441226
    Abstract: Described herein is an improved process for an anticorrosion pretreatment of a metallic surface including steel, galvanized steel, aluminum, magnesium and/or a zinc-magnesium alloy, wherein the metallic surface is brought into contact with an aqueous composition A including a) from 0.01 to 0.5 g/l of a copolymer and the metallic surface is brought into contact with an acidic aqueous composition B including b1) a compound selected from the group consisting of titanium, zirconium and hafnium compounds, wherein the metallic surface is brought into contact i) firstly with the composition A and then with the composition B, ii) firstly with the composition B and then with the composition A and/or iii) simultaneously with the composition A and the composition B. Also described herein is a corresponding aqueous composition A, an aqueous concentrate for producing this composition, a correspondingly coated metallic surface and a method of using a correspondingly coated metallic substrate.
    Type: Grant
    Filed: June 21, 2017
    Date of Patent: September 13, 2022
    Assignee: CHEMETALL GMBH
    Inventors: Stefan Birkenheuer, Carina Hecker, Oliver Sauer, Daniel Schatz
  • Patent number: 11434573
    Abstract: Described herein is an aqueous composition for removing cryolitic deposits from plants or parts of plants which serve for the conversion treatment of metal surfaces, said composition including a) at least one mineral acid, and b) at least one dicarboxylic acid of the formula HOOC—(CH2)x—COOH, where x is 0 to 3 and no borate-containing compounds have been added to the composition. Also described herein is a corresponding method for removing cryolitic deposits.
    Type: Grant
    Filed: December 7, 2018
    Date of Patent: September 6, 2022
    Assignee: Chemetall GmbH
    Inventor: Anna Verena Mohr
  • Patent number: 11401428
    Abstract: Aqueous coating compositions are provided. The aqueous compositions include at least one type of organic polymer particles having an average particle size of 10 to 1000 nm, including isocyanate-reactive polymers (A), one or more ketoxime- and/or pyrazole-blocked polyisocyanates (B) including at least one aromatic hydrocarbyl radical or at least one cycloaliphatic hydrocarbyl radical, at least one polyanionic polymer (C), at least one complex fluoride (D) selected from the group consisting of hexa- or tetrafluorides of metallic elements of groups IVb, Vb and VIb of the Periodic Table of the Elements, and at least one aminosilane (E), wherein the aqueous coating compositions have a pH of 3 to 5, and have a total solids content of 5% to 35% by weight. Also provided are processes for producing these aqueous coating compositions, processes for coating metal ion-releasing surfaces with the aqueous coating compositions, and coatings obtained therefrom.
    Type: Grant
    Filed: July 20, 2018
    Date of Patent: August 2, 2022
    Assignee: Chemetall GmbH
    Inventors: Aliaksandr Frenkel, Ron Eilinghoff, Martin Droll
  • Patent number: 11389823
    Abstract: A method for coating metallic surfaces of substrates with surfaces of aqueous (coating) compositions in the form of a dispersion and/or a suspension containing at least one stabilized binder and a gelling agent, the cations having been dissolved out of the metallic surface of the substrate in a pretreatment stage and/or during the contacting. The invention further relates to such a coating based on an ionogenic gel, in which the coating is formed by a process further described herein.
    Type: Grant
    Filed: February 27, 2015
    Date of Patent: July 19, 2022
    Assignee: CHEMETALL GMBH
    Inventors: Wolfgang Bremser, Martin Droll, Oliver Seewald, Evgenija Niesen-Warkentin, Lars Schachtsiek, Manuel Traut, Michael Schwamb, Daniel Wasserfallen, Vera Sotke, Aliaksandr Frenkel, Ron Eilinghoff, Stephanie Gerold, Nawel Khelfallah
  • Patent number: 11346002
    Abstract: The present invention relates to an acidic aqueous composition for coating metallic surfaces, particularly of aluminium materials, that comprises, besides water and optionally further components, a) at least one compound selected from the group consisting of organoalkoxysilanes, organosilanols, polyorganosilanols, organosiloxanes and polyorganosiloxanes, b) at least one compound selected from the group consisting of titanium, zirconium, hafnium and aluminium compounds and silicon complex fluoride, and c) at least one copolymer which is stable at least in a segment of the pH range below 6 and which comprises, in alternating configuration, monomer units containing at least one carboxylic and/or phosphonic acid group and monomer units containing no acid group. The invention further relates to a corresponding coating method and to the use of the substrates coated by this method.
    Type: Grant
    Filed: December 15, 2015
    Date of Patent: May 31, 2022
    Assignee: Chemetall GmbH
    Inventors: Lars Sebralla, Stefan Birkenheuer, Manfred Walter, Nawel Souad Khelfallah
  • Patent number: 11293102
    Abstract: A method of treating the surface of a metal base which is conducted prior to cationic electrodeposition coating and is used for improving throwing power in the cationic electrodeposition coating; a metallic material treated by the surface treatment method; and a method of coating this metallic material.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: April 5, 2022
    Assignee: CHEMETALL GMBH
    Inventors: Toshio Inbe, Hiroshi Kameda, Masanobu Futsuhara, Kazuto Akiyama
  • Patent number: 11261531
    Abstract: Provided herein is a method for pretreating aluminum materials, particularly aluminum wheels, wherein an aluminum material is successively i) cleaned and subsequently rinsed, ii) optionally subjected to alkaline pickling and subsequently rinsed, iii) optionally contacted with an aqueous composition comprising at least one mineral acid, iv) optionally rinsed and v) contacted with an acidic aqueous composition comprising a) at least one compound selected from the group consisting of titanium, zirconium and hafnium compounds and b) at least one linear terpolymer prepared by controlled radical polymerisation and comprising vinylphosphonic acid monomeric units, hydroxylethyl- and/or hydroxylpropyl-(meth)acrylate monomeric units and (meth)acrylic acid monomeric units, vi) optionally rinsed, vii) optionally contacted with another aqueous composition, viii) optionally rinsed and ix) optionally dried.
    Type: Grant
    Filed: September 11, 2018
    Date of Patent: March 1, 2022
    Assignees: CHEMETALL GMBH, RHODIA OPERATIONS
    Inventors: Lars Sebralla, Nawel Souad Khelfallah, Manfred Walter, Marie-Pierre Labeau, Guillaume Gody
  • Patent number: 11261337
    Abstract: A coating, a method for coating surfaces, and the coated surfaces. The method includes providing a substrate with a cleaned metal surface; contacting and coating the metal surface with an aqueous composition having a ph of from 0.5 to 7.0 and in the form of a dispersion and/or a suspension; optionally rinsing the organic coating; and drying and/or baking the organic coating, or optionally drying the organic coating and coating same with a similar or another coating composition thereto. The composition contains a complex fluoride in a quantity of 1.1 10?6 mol/l to 0.30 mol/l based on the cations. An anionic polyelectrolyte in a quantity of 0.01 to 5.0 wt % based on the total mass of the resulting mixture is added to an anionically stabilized dispersion made of film-forming polymers and/or a suspension made of film-forming inorganic particles.
    Type: Grant
    Filed: July 16, 2019
    Date of Patent: March 1, 2022
    Assignee: CHEMETALL GMBH
    Inventors: Daniel Wasserfallen, Michael Schwamb, Aliaksandr Frenkel, Vera Sotke, Wolfgang Bremser, Martin Droll, Ron Eilinghoff, Stephanie Gerold, Evgenija Niesen, Lars Schachtsiek, Manuel Traut, Oliver Seewald
  • Patent number: 11142654
    Abstract: A composition for applying a clear or translucent and colorless or nearly colorless emissive coating on a metallic surface comprising in a dispersion a) 50 to 300 g/L of at least one of clear or translucent organic polymeric substances of a binder, and b) 30 to 300 g/L of sheet silicate pigments having a TE value for the thermal emissivity of at least 0.40, having a particle size distribution of which d50 is in the range of 0.3 to 80 ?m. Processes for applying the composition and elements prepared therefrom are also disclosed.
    Type: Grant
    Filed: November 3, 2010
    Date of Patent: October 12, 2021
    Assignee: Chemetall GmbH
    Inventors: Noel Smith, Charles J. Gruszka, Aaron Thompson, Michael Deemer
  • Patent number: 11142655
    Abstract: The invention relates to a process for coating metallic surfaces with a composition containing silane/silanol/siloxane/polysiloxane, wherein, in addition to a) at least one compound selected from silanes, silanols, siloxanes and polysiloxanes, b) at least one compound containing titanium, hafnium, zirconium, aluminium and/or boron, and c) at least one type of cation selected from cations of metals of subgroups 1 to 3 and 5 to 8, including lanthanides, and of main group 2 of the periodic table of the elements, and/or at least one corresponding compound, the composition contains at least one substance d) selected from: d1) silicon-free compounds having at least one amino, urea and/or ureido group in each case, d2) anions of nitrite and/or compounds having at least one nitro group, d3) compounds based on peroxide, and d4) phosphorus-containing compounds, anions of at least one phosphate and/or anions of at least one phosphonate, as well as e) water, and f) optionally also at least one organic solvent.
    Type: Grant
    Filed: January 14, 2011
    Date of Patent: October 12, 2021
    Assignee: Chemetall GmbH
    Inventors: Thomas Kolberg, Manfred Walter, Peter Schubach
  • Patent number: 11124674
    Abstract: A method for curing a mixture of a matrix and a curing agent based on sulfur-containing polymers on command and so rapidly that a tack-free surface results. A method for coating a substrate with the composition and of curing a sealant is also provided. The matrix and curing agent containing sulfur-containing polymers. The mixture is an uncured mixture with an isocyanate content, and the matrix is uncured and contains a mercaptan-terminated base polymer based on at least one polyether, polythioether, polysulfide or copolymers thereof. The uncured matrix, the curing agent, or both contain at least one photoinitiator based on sterically-inhibited tertiary amines. The mixture cures in the temperature range of ?10 to +70° C. after the high-energy actinic radiation is applied. Corresponding matrices A, mixtures B, curing agents, sealant systems, and substrates, e.g., aircraft are contemplated.
    Type: Grant
    Filed: June 19, 2019
    Date of Patent: September 21, 2021
    Assignee: Chemetall GmbH
    Inventors: Miroslav Kralev, Björn Sievers, Peter Bons, Francisco Diez
  • Patent number: 11124884
    Abstract: An aqueous composition for reducing corrosive removal of material in pickling of metallic surfaces comprising bare and/or galvanized steel. The composition includes a mixture of a compound of the formula R1O—(CH2)x—C?C—(CH2)y—OR2 in which R1 and R2 are both H, and a compound of the formula R1O—(CH2)x—C?C—(CH2)y—OR2 in which R1 and R2 are each, independently of one another, an HO—(CH2)w— group with w?2. X and y are each, independently of one another, from 1 to 4 in each of the two compounds of the formula R1O—(CH2)x—C?C—(CH2)y—OR2. A process for pickling a metallic surface with reduced corrosive removal of material is disclosed.
    Type: Grant
    Filed: April 28, 2017
    Date of Patent: September 21, 2021
    Assignee: Chemetall GmbH
    Inventor: Anna Verena Mohr
  • Patent number: 11124880
    Abstract: Described herein is a method for phosphating of a metallic surface, wherein a metallic surface, optionally after cleaning and/or activation, is first treated with an acidic, aqueous, substantially nickel-free phosphating composition that includes zinc ions, manganese ions, iron(III) ions and phosphate ions, and is thereafter optionally rinsed and/or dried. Also described herein are a corresponding phosphating composition and a correspondingly phosphate-coated metallic surface.
    Type: Grant
    Filed: January 18, 2017
    Date of Patent: September 21, 2021
    Assignee: Chemetall GmbH
    Inventors: Olaf Dahlenburg, Lisa Schmeier
  • Patent number: 11059070
    Abstract: Described herein is an apparatus for dynamic metering of sealant volumes, and also described herein is a corresponding method. The apparatus of the invention includes two containers for sealant components; a first drive, which is connected to two devices, each of which is able to convey one of the sealant components from its container; a drive controller; a mixing unit for mixing the sealant components conveyed from the containers, having an opening for applying the sealant to a component; and also, additionally, a compensating container with a compensating volume; and a second drive, which is connected to a piston which reaches into the compensating volume of the compensating container. The compensating container in this arrangement is connected to the mixing unit. The first drive and the second drive can be dynamically controlled jointly by the drive controller.
    Type: Grant
    Filed: September 5, 2017
    Date of Patent: July 13, 2021
    Assignee: CHEMETALL GMBH
    Inventor: Heinz Burock