Abstract: A compound represented by the following formula: ##STR1## wherein R is a C.sub.3 -C.sub.24 olefinically unsaturated organic radical having functionality which renders the nitrogen atom electron deficient, the olefinic unsaturation functionality being polymerizable,R.sup.1 is hydrogen or a C.sub.1 -C.sub.4 alkyl radical, orR and R.sup.1 together with the nitrogen atom can form an olefinically unsaturated 5 to 7-member ring which has functionality that renders the nitrogen atom electron deficient and the olefinic unsaturation functionality is polymerizable,R.sup.2 and R.sup.3 are hydrogen, a C.sub.1 -C.sub.4 alkyl or acyl radical, orR.sup.2 and R.sup.3 together are a C.sub.2 -C.sub.4 alkylene group,R.sup.4 is hydrogen or a C.sub.1 -C.sub.4 alkyl, acyl, ester, amide or acid group, andn is an integer from 1 to 10, provided n is not 1 when R is (meth)acryloyl, R.sup.2 and R.sup.3 are methyl and R.sup.1 and R.sup.4 are hydrogen.Under acidic conditions the above compounds having R.sup.
Type:
Grant
Filed:
July 30, 1985
Date of Patent:
September 1, 1987
Assignee:
Air Products and Chemicals, Inc.
Inventors:
Robert K. Pinschmidt, Jr., Dale D. Dixon, William F. Burgoyne, Jr.
Abstract: The gaseous effluent from oxidation of organic material with oxygen-rich gas, which effluent contains CO.sub.2 (and possible CO) and unreacted residual oxygen, is compressed and charged to a PSA system for selective removal of the CO.sub.x, the thus purified oxygen-rich product from the PSA system being recycled to the oxidation reaction. In the PSA system comprised of a plurality of adsorption columns operated in parallel, each column in turn undergoes the steps of: (1) selective adsorption of CO.sub.2 from the feed gas; (2) depressuring to near ambient level; (3) purging with air to remove sorbed CO.sub.2 ; and (4) repressuring with part of the recycled effluent from step (1).
Abstract: Enhanced oil recovery from a crude oil reservoir is promoted following primary oil production, by subjecting the reservoir to water flooding, discontinuing the water flooding, preferably when the remaining oil is at an OIP level above 0.10, and then subjecting the reservoir to fireflooding with gas having an O.sub.2 content of at least 50%, preferably above 85%.
Type:
Grant
Filed:
May 16, 1986
Date of Patent:
September 1, 1987
Assignee:
Air Products and Chemicals, Inc.
Inventors:
George W. Roberts, James G. Hansel, Goutam H. Shahani
Abstract: A fluoroolefin copolymer having an inherent viscosity of from 0.05 to 2.0 dl/g and composed of(I) 10 to 70 mole % of monomeric units derived from a fluoroolefin represented by the general formula ##STR1## wherein X is H, Cl, F, CF.sub.3, OCF.sub.3 or OC.sub.3 F.sub.7, (II) 5 to 60 mole % of monomeric units derived from a vinyl carboxylate represented by the general formula ##STR2## wherein R.sub.1 represents an aliphatic, aromatic or alicyclic hydrocarbon group having 1 to 17 carbon atoms,(III) 5 to 70 mole % of monomeric units derived from a vinyl ether having an alkyl group with 1 to 8 carbon atoms, and(IV) 0 to 30 mole % of monomeric units derived from a hydroxyl-containing vinyl ether represented by the general formula ##STR3## wherein R.sub.2 represents an alkylene group having 1 to 6 carbon atoms.
Abstract: An activation energy-curable resin composition comprising as an essential ingredient a resin obtained by reacting (a) the reaction product of a novolac epoxy compound and an unsaturated monocarboxylic acid with (b) the reaction product of a diisocyanate and a poly(meth)acrylate having one hydroxyl group for each molecule.
Abstract: A method and product for concentrating metal values from their ores employing alkyl mercaptans as collector additives in froth flotation, wherein there is provided a mixture of (I) a collector selected from the class consisting of at least one of (A) an alkyl xanthogen alkyl formate compound having the general formula: ##STR1## wherein R is a branched or straight chain alkyl substituent having 1 to 6 carbon atoms and R' is selected from the class consisting of one of ethyl and methyl; and (B) a dialkyl thionocarbamate compound having the formula: ##STR2## wherein Y is a branched or straight chain alkyl substituent having 1 to 6 carbon atoms and Y' is selected from the class consisting of one of ethyl and ethyl; and (II) an alkyl mercaptan having the formula:Z--SHwherein Z is a branched or straight chain alkyl substituent having 4 to 16 carbon atoms. Isobutyl xanthogen ethyl formate, N-methyl-O-ethyl thionocarbamate and dodecyl mercaptan are illustrative.
Abstract: This invention relates to the treatment of the common cold either by ameliorating the symptoms of the common cold or by preventing the rhinoviruses from causing colds or by preventing the cold symptoms from worsening. The invention includes the treatment of the common cold or head cold in mammals, especially man, and describes methods of treatment and pharmaceutical compositions for use in carrying out such treatments.
Abstract: An epoxy resin composition comprising an epoxy resin and a curing agent for said resin and optionally a curing accelerator, the improvement of which the epoxy resin is an epoxy resin obtained by reacting dihydroxynaphthalene of formula ##STR1## with epichlorohydrin.
Abstract: A novel polymeric binder for use in an antifouling paint includes an acrylic or methacrylic ester monomer having selected substituted aryl or arylalkyl substituent groups in the ester moiety so that the ester is hydrolyzable at a suitable rate in seawater, and a copolymerizable ethylenically unsaturated monomer unit.
Type:
Grant
Filed:
January 29, 1985
Date of Patent:
August 18, 1987
Assignee:
M&T Chemicals Inc.
Inventors:
David B. Russell, Melvin H. Gitlitz, Howard H. Leiner, Mo A. Khuddus, Abe Berger
Abstract: The method for extracting hydrogen from a gas stream containing hydrogen with or without other gases by a sorption-desorption process using as the hydrogen sorber a pellet bed of a porous, metallurgically bonded, heat-ballasted hydridable mixture comprising a major proportion of a heat-ballast material and a minor proportion of a hydridable metallic material.
Type:
Grant
Filed:
February 26, 1986
Date of Patent:
August 18, 1987
Assignees:
Ergenics, Inc., Air Products and Chemicals, Inc.
Inventors:
Paul D. Goodell, Ernest L. Huston, Peter S. Rudman, Gary D. Sandrock
Abstract: This invention relates to a polyimide powder in use for adhesion and/or coat forming and to a method of preparing said powder, wherein polyamic-acid is chemically imidized which is obtained by reacting tetracarboxylic acid dianhydride with diamine in organic solvents.This invention further relates to a method for adhesion and coat forming by using said polyimide powder.This invention still further relates to a method for preparing prepreg by using said polyimide powder, and a method for adhesion and preparing molded laminates by using said prepreg.
Abstract: A pressure swing adsorption process is provided for the direct production from ambient air of a moderately enriched oxygen product gas. The production of a product gas having an oxygen concentration of 23 to 30% is effected by a three step cycle wherein (1) the feed air is charged to a bed of nitrogen selective adsorbent until the bed is brought from atmospheric pressure to a pressure in the range of up to 10 atmospheres, (2) reducing the bed pressure to an intermediate level by withdrawal of oxygen enriched product gas therefrom and (3) finally venting the bed to restore atmospheric pressure. By an alternative mode including a fourth step of purging the bed following the venting step, a product of 23 to 45% oxygen concentration is obtained.
Abstract: Process and apparatus are set forth for ascertaining and controlling the flammability of produced gas from an in-situ combustion enhanced petroleum production well whereby the produced oil is sampled, the produced gas is periodically sampled, the temperature, pressure and produced gas flow rate are sensed, and a moderant gas is added to the production well to avoid flammability when the sampled and sensed parameters indicate a flammability condition exists.
Abstract: A process for producing m-hydroxybenzyl alcohol which comprises electrolytically reducing m-hydroxybenzoic acid in an acidic aqueous solution at a temperature of 20.degree. to 70.degree. while m-hydroxybenzyl alcohol is present always in the electrolytic solution. The constant presence of m-hydroxybenzyl alcohol is effected by (1) continuously adding m-hydroxybenzoic acid to the electrolytic solution in an amount corresponding to that consumed as the electrolytic reaction proceeds, or (2) by continuously adding m-hydroxybenzoic acid and the acidic aqueous solution to the electrolytic solution.
Abstract: A photosensitive image-forming material having a photosensitive layer, said photosensitive layer comprising a photosensitive resin resulting from the reaction of a hydroxyl-containing polyester precursor composed of dicarboxylic acid units derived from a dicarboxylic acid having a photosensitive unsaturated double bond adjacent to an aromatic ring and glycol units with a chain extender having in the molecule at least two functional groups capable of reacting with the hydroxyl groups of the polyester precursor.
Abstract: An improved method of recovering sulfur from a hydrogen sulfide-containing gas stream which removes water concurrently with the condensation of sulfur and which can be operated at high pressure.
Abstract: This invention relates to urethane linked mixtures of 2,4- and 2,6-toluenediisocyanates (ULTDI dimers) having low melting points and to a method of forming these systems. The urethane linked toluenediisocyanates containing from 45-90% of the 2,4- and 10-55% of the 2,6- isomer by weight are formed by reacting two moles of an appropriate isomer mix of toluenediisocyanate, with one mole of a specific alkylene glycol, e.g., 1,2-butanediol, diethylene glycol or dipropylene glycol under conditions such that essentially only one of the isocyanate groups on a toluenediisocyanate molecule reacts with a hydroxyl group of the glycol. Conditions are controlled such that the urethane linked toluenediisocyanates are formed. The resulting product, which has two unreacted isocyanate groups, is suited for producing a variety of elastomers including polyurethane polyurethane/urea or polyurea elastomers.
Type:
Grant
Filed:
July 8, 1986
Date of Patent:
July 28, 1987
Assignee:
Air Products and Chemicals, Inc.
Inventors:
Barton Milligan, William E. Starner, Roland E. Grandin, Jeremiah P. Casey
Abstract: The present invention relates to an opaque binder system containing a core-shell polymer and polymeric binder. The system is prepared and blended in-situ and demonstrates improvement in contrast ratio and scrub properties over corresponding compositions wherein the core-shell polymer is separately produced and subsequently blended with a binder polymer.
Abstract: Polymer compositions containing minor proportions of polyvalent metal or amine salts of 5,5-bis-(bromomethyl)-2-hydroxy-2-oxo-1,3,2-dioxaphosphorinane. Aluminum, calcium and melamine salts are preferred.
Abstract: Polymer compositions containing minor proportions of polyvalent metal or amine salts of 5,5-bis-(bromomethyl)-2-hydroxy-2-oxo-1,3,2-dioxaphosphorinane. Aluminum, calcium and melamine salts are preferred.