Patents Assigned to Chemische Fabrik Stockhausen & Cie
  • Patent number: 4528350
    Abstract: The invention relates to a process for the preparation of .alpha.,.beta.-unsaturated N-substituted carboxylic acid amides, novel .alpha.,.beta.-unsaturated N-substituted carboxylic acid amides, a process for the polymerization of these novel .alpha.,.beta.-unsaturated N-substituted carboxylic acid amides, including the polymers, and the use of these polymers as sedimentation, flocculating, dewatering and retention aids, as additives for mineral oils, and as ion exchangers.The .alpha.,.beta.-unsaturated N-substituted carboxylic acid amides are prepared by transamidation of .beta.-hydroxy or .beta.-alkoxy carboxylic acid amides with primary amines and heating of the N-substituted .beta.-hydroxy or .beta.-alkoxy carboxylic acid amides obtained as intermediate products in the vapor phase in the presence of catalysts. Primary amines are preferably used in the conversion which have no hydrogen beta to the amino group.These .alpha.,.beta.
    Type: Grant
    Filed: July 11, 1983
    Date of Patent: July 9, 1985
    Assignee: Chemische Fabrik Stockhausen & Cie
    Inventors: Bernhard Goossens, Erich Kuster, Kurt Dahmen, Eduard Barthell
  • Patent number: 4408073
    Abstract: The invention relates to a process for the preparation of .alpha., .beta.-unsaturated N-substituted carboxylic acid amides, novel .alpha., .beta.-unsaturated N-substituted carboxylic acid amides, a process for the polymerization of these novel .alpha., .beta.-unsaturated N-substituted carboxylic acid amides, including the polymers, and the use of these polymers as sedimentation, flocculating, dewatering and retention aids, as additives for mineral oils, and as ion exchangers.The .alpha., .beta.-unsaturated N-substituted carboxylic acid amides are prepared by transamidation of .beta.-hydroxy or .beta.-alkoxy carboxylic acid amides with primary amines and heating of the N-substituted .beta.-hydroxy or .beta.-alkoxy carboxylic acid amides obtained as intermediate products in the vapor phase in the presence of catalysts. Primary amines are preferably used in the conversion which have no hydrogen beta to the amino group.These .alpha.,.beta.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: October 4, 1983
    Assignee: Chemische Fabrik Stockhausen & Cie
    Inventors: Bernhard Goossens, Erich Kuster, Kurt Dahmen, Eduard Barthell
  • Patent number: 4340525
    Abstract: An additive for deep-well cement slurries comprising a water-soluble anionic copolymer having a molecular weight from about 50,000 to 500,000 and comprising about 1 to 60 mole % of anionic structural units and about 99 to 40 mole % of nonanionic structural units. A preferred additive comprises a terpolymer of acrylamide, sodium acrylate and sodium vinylsulphonate. The additives retard the setting action of the slurry, stabilize the slurry, prevent the swelling of readily hydratable clays and are resistant to electrolytes which would accelerate setting and seepage of water from the slurry.
    Type: Grant
    Filed: March 19, 1981
    Date of Patent: July 20, 1982
    Assignee: Chemische Fabrik Stockhausen & Cie
    Inventors: Wolfgang Hubner, Otto Schroers, Hans J. Sladeck
  • Patent number: 4297468
    Abstract: The invention relates to new cross-linked copolymers containing carboxyl groups and especially useful as thickening agents for aqueous and organic solvents, which copolymers contain(A) 20 to 100% by weight of olefinically unsaturated carboxylic acids,(B) 0 to 80% by weight of at least one mono-olefinically unsaturated monomer copolymerizable with the components A and C, and(C) 0.1 to 4% by weight, calculated on the total quantity of monomers, of allyl monomer of the general formula ##STR1## in which n=0, 1 or 2,m=1, 2 or 3, wherein n+m=3,R.sub.1 =hydrogen, or an alkyl, alkoxyalkyl, haloalkyl, cycloalkyl, aryl, alkaryl, aralkyl or alkenyl radical, andR.sub.2 and R.sub.3, which may be the same or different, each represents hydrogen or an allyl, alkyl, cycloalkyl, aryl, aralkyl or alkaryl radical,wherein at least two of the radicals R.sub.1, R.sub.2 and R.sub.3 must be an allyl radical or a substituted allyl radical.
    Type: Grant
    Filed: May 16, 1979
    Date of Patent: October 27, 1981
    Assignee: Chemische Fabrik Stockhausen & Cie
    Inventors: Miroslay Chmelir, Kurt Dahmen
  • Patent number: 4281186
    Abstract: The invention relates to acrylyl or methacrylyl ureas containing novel quaternary groups of the formula ##STR1## wherein X is hydrogen or a methyl group,R is a lower alkyl radical having from 1 to 4 carbon atoms,m is 0 or 1,n is an integer between 1 and 4, andZ is a salt-forming anion.The compounds are prepared from the corresponding halogen-substituted ureas by reaction with trialkylamines, preferably in a solvent. Because of their double bond, they can be polymerized to homopolymers and copolymers which are suited for use as flocculating, precipitating, dewatering and retention aids.
    Type: Grant
    Filed: December 18, 1979
    Date of Patent: July 28, 1981
    Assignee: Chemische Fabrik Stockhausen & Cie
    Inventors: Erich Kuster, Kurt Dahmen, Eduard Barthell
  • Patent number: 4256800
    Abstract: The antistatic composition for application to flat fibrous articles such as textiles, carpets, fabrics and the like which comprises a salt of a polymeric acid with an amine of the general formula ##STR1## wherein A=H, --OR.sub.2, ##STR2## R.sub.1 =H, a lower alkyl radical, a hydroxyalkyl, aminoalkyl, polyalkylene imine or polyalkylene glycol ether radical;R.sub.2 =H, a lower alkyl radical, a hydroxyalkyl, aminoalkyl, polyalkylene imine or polyalkylene glycol ether radical;R.sub.3 =H, a lower alkyl radical, a hydroxyalkyl, aminoalkyl, polyalkylene imine or polyalkylene glycol ether radical;R.sub.
    Type: Grant
    Filed: January 18, 1978
    Date of Patent: March 17, 1981
    Assignee: Chemische Fabrik Stockhausen & Cie
    Inventors: Dolf Stockhausen, Reinmar Peppmoller
  • Patent number: 4237067
    Abstract: Process for the manufacture of .alpha.,.beta.-unsaturated N-substituted carboxylic acid amides of the general formula ##STR1## in which R.sup.1 represents H or CH.sub.3R.sup.2 represents H or CH.sub.3, andY represents a divalent straight-chain or branched organic radical having 2-30 carbon atoms, andR.sup.3 represents H or the radical of an amine of the formula --N(R.sup.4)(R.sup.5), in which R.sup.4 and R.sup.5 represent alkyl radicals having 1 to 4 carbon atoms,by reacting .beta.-substituted carboxylic acid amides of the formula ##STR2## in which Z represents OH or the radical R.sup.6 O--, in which R.sup.6 is an alkyl radical having 1 to 4 carbon atoms,with amines of the general formulaH.sub.2 N--(Y)--R.sub.3 IIIat temperatures in the range of 100.degree. to 200.degree. C., preferably 120.degree. to 175.degree. C., with the elimination of ammonia, and heating the resulting N-substituted .beta.-hydroxycarboxylic or .beta.
    Type: Grant
    Filed: May 3, 1979
    Date of Patent: December 2, 1980
    Assignee: Chemische Fabrik Stockhausen & Cie.
    Inventors: Erich Kuster, Bernhard Goossens, Eduard Barthell, Kurt Dahmen
  • Patent number: 4208184
    Abstract: As a leather fatting agent a solution, emulsion or dispersion of a pulverulent, free-flowing form product derived from a substance having a liquid or pasty consistency, especially fatty, oil and waxy substances, especially those prepared by drying aqueous solutions or dispersions containing these substances together with carrier compositions having the dry weight analysis of from 0.1 to 35% inorganic or organic salts, 0.1 to 90% albumin or albumin derivatives and 0.
    Type: Grant
    Filed: December 28, 1978
    Date of Patent: June 17, 1980
    Assignee: Chemische Fabrik Stockhausen & Cie
    Inventors: Rudolf Nowak, Kurt Dahmen, Eduard Barthell
  • Patent number: 4113685
    Abstract: A flocculation, sedimentation, dehydration or retention composition comprising a stable dispersion of about 10 to 50% concentration by weight of a polymeric Mannich base in a mixture of water, a water-insoluble liquid and an emulsifier all present as a water-in-oil emulsion, the Mannich base comprising an NH-active polymer carrying carbonamide groups at least about 10% of which carry radicals of a reaction therewith of formaldehyde and a primary or secondary alkyl- or hydroxyalkyl-amine wherein the alkyl groups have up to about 18 carbon atoms, and a stabilizing amount of a water-soluble salt of a mono- or multivalent amine, alone or in admixture with a mono- or multivalent amine or ammonia, or of an ammonium salt of a mineral acid and ammonia, or of a carboxylic acid amide. The amine of the Mannich base is preferably dimethylamine or diethylamine and is used in approximately the same molar amount as the formaldehyde.
    Type: Grant
    Filed: May 3, 1976
    Date of Patent: September 12, 1978
    Assignee: Chemische Fabrik Stockhausen & Cie
    Inventors: Wolfgang Hubner, Eduard Barthell, Kurt Dahmen
  • Patent number: 4093542
    Abstract: A flocculation, sedimentation, dehydration or retention composition comprising a dispersion of about 10 to 50% concentration by weight of a polymeric Mannich base in a mixture of water and a water-insoluble liquid, the Mannich base comprising an H-active polymer carrying radicals of a reaction with formaldehyde and a primary or secondary alkyl- or hydroxyalkylamine wherein the alkyl groups have up to about 18 carbon atoms. The amine is preferably dimethylamine or diethylamine and is used in approximately the same molar amount as the formaldehyde. The polymer preferably comprises acrylamide units and the polymerization may be effected either before or after reaction with the formaldehyde and amine.
    Type: Grant
    Filed: January 2, 1975
    Date of Patent: June 6, 1978
    Assignee: Chemische Fabrik Stockhausen & Cie
    Inventors: Kurt Dahmen, Wolfgang Hubner, Eduard Barthell