Patents Assigned to Chemische Fabrik Stockhausen GmbH
  • Patent number: 6235296
    Abstract: The present invention relates to hydrous, liquid, paste- or cream-like skin cleaning agents for the removal of strongly adhering soil, comprising anionic and/or amphoteric and/or non-ionogenic surfactants as washing-active substances, thickeners, at least one abrasive, and, optionally, adjuvants for the regulation of consistency, appearance, odor, and stability, such as pigments, fragrances, stabilizers, and preservatives, which skin cleaning agents are characterized by the fact that they comprise di-n-butyl adipate and/or di-isopropyl adipate as the exclusive solvents. These agents are obtained by homogeneously mixing the components, optionally under heating of the mixture. If a C8-C16 fatty alcohol which acts as consistency regulator is added, heating of the component mixture may be omitted. Besides, the addition of the fatty alcohol increases the detergent action.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: May 22, 2001
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Günter Daniel, Volker Rosenberger, Beatrice Brücher
  • Patent number: 6228964
    Abstract: A water-soluble, powdered, cationic polyelectrolyte comprising a copolymer of acrylamide and dimethylaminopropylacrylamide which is essentially free of bifunctional compounds and in which a) the dimethylaminopropylacrylamide is quaternized; b) the quotient of the intrinsic viscosity of the copolymers divided by the molar ratio of acrylamide to dimethylaminopropylacrylamide is greater than 200; and c) the proportion of the cationic monomers in the polymer is between 4 and 80 mol-%, the copolymer having been obtained by copolymerization of acrylamide and quaternized dimethylaminopropylacrylamide said quaternized dimethylaminopropylacrylamide having been obtained by the reaction of dimethylaminopropylacrylamide with a quaternizing agent in the absence of acrylamide.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: May 8, 2001
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Hans-Georg Hartan, Alfons Landscheidt
  • Patent number: 6120759
    Abstract: An anhydrous skin cleansing agent comprising a surfactant, organic solvent and water-insoluble abrasive as active components and a water-swellable organic polymer as a soil carrier and abrasive.
    Type: Grant
    Filed: August 22, 1991
    Date of Patent: September 19, 2000
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventor: Gunter Bouillon
  • Patent number: 6103358
    Abstract: The present invention relates to layered bodies consisting of at least one plastic foam and/or latex foam layer and particulate, superabsorbent polymers for the absorption of water and aqueous liquids, which bodies comprise the superabsorber on, between, or below the foamed plastic and/or latex layer in a quantitatively and/or locally predetermined and fixed areal configuration at a quantity ratio of plastic and/or latex foam to the superabsorber of 1:500 to 50:1. The plastic/latex foam may comprise fillers, pigments and/or synthetic fibers. The layered bodies have an increased absorption capacity for water and aqueous liquids; in particular under load. They are manufactured by spreading out the foam, applying the superabsorber in the predetermined quantity ratio, optionally by using a stencil, and by fixing it by means of a heat treatment.
    Type: Grant
    Filed: January 6, 1998
    Date of Patent: August 15, 2000
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Helmut Bruggemann, Kurt Dahmen
  • Patent number: 5847031
    Abstract: A polymer composition, in particular an active substance-containing depot material composition or an absorbent composition are disclosed which substantially consist of a water-soluble and/or water-swellable polymer based on polysaccharides as the main component, and a water-swellable, synthetic polymer as further component, used as polymeric components, and of a matrix material for the prevention of separation and gel blocking, an ionic or covalent cross-linking agent, as well as of an anti-blocking agent. Additionally their production and use as well as (animal) hygiene items and chemico-technical products are disclosed which comprise these polymer compositions, these active-substance-containing depot material compositions, or the absorbent compositions.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: December 8, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Helmut Klimmek, Uwe Gunther, Helmut Bruggemann
  • Patent number: 5830956
    Abstract: The present invention relates to biodegradable polymers built-up ofa) monoethylenically unsaturated dicarboxylic acids and/or the salts thereof,b) monoethylenically unsaturated monocarboxylic acids and/or the salts thereof,c) monounsaturated monomers which, after hydrolysis, can be converted to monomers with a hydroxyl group covalently bonded to the C-C-chain, and, optionally,d) further radically copolymerizable monomers,with the sum of the monomers according to a) to d) amounting to 100%.The present invention further relates to a process of producing said polymers by radical polymerization and hydrolysis in aqueous medium, and to the use of said polymers as additive or cobuilder in detergents and cleaning agents, in the pretreatment of cotton, as bleaching stabilizers, as auxiliary agent in textile printing and in the manufacture of leather, as well as in the inhibition of water hardness and as dispersing agent.
    Type: Grant
    Filed: August 23, 1995
    Date of Patent: November 3, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Dolf Stockhausen, Frank Krause, Helmut Klimmek
  • Patent number: 5830445
    Abstract: The present invention is directed to an abrasive for use in a skin cleansing agent. The abrasive comprises a bleached flour obtained from a natural shell, kernel or mixture thereof. A preferred bleaching agent is hydrogen peroxide. The natural shells and/or kernels may be, for example, walnut shells, almond shells, hazelnut shells, olive kernels, cherry kernels, apricot kernels or mixtures thereof.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: November 3, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Gunter Bouillon, Gunter Daniel, Horst Denzer, Reinmar Peppmoller, Martin Franzen
  • Patent number: 5783616
    Abstract: The present invention relates to water-soluble, acid-groups-containing graft copolymers which are at least partially biodegradable and are based on sugars and monoethylenically unsaturated carboxylic acids, sulfonic acids and/or phosphonic acids or the salts of said acids as well as optional further monomers. The present invention further relates to a process for producing the graft copolymers at temperatures of up to 200.degree. C. by means of radical polymerization initiators, in that a total mixture of 5-60%-wt. mono-, di- and oligosaccharides, the derivatives thereof or the mixtures thereof, and 95-40%-wt. of a monomer mixture comprising at least one monoethylenically unsaturated carboxylic acid, at least one monoethylenically unsaturated sulfonic acid, one monoethylenically unsaturated sulfuric acid ester and/or vinylphosphonic acid or the salts of said acids with monovalent cations, as well as optional further monomers is polymerized.
    Type: Grant
    Filed: April 4, 1997
    Date of Patent: July 21, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Frank Krause, Helmut Klimmek
  • Patent number: 5763067
    Abstract: The present invention relates to layered bodies consisting of at least one plastic foam and/or latex foam layer and particulate, superabsorbent polymers for the absorption of water and aqueous liquids, which bodies comprise the superabsorber on, between, or below the foamed plastic and/or latex layer in a quantitatively and/or locally predetermined and fixed area, configuration at a quantity ratio of plastic and/or latex foam to the superabsorber of 1:500 to 50:1. The plastic/latex foam may comprise fillers, pigments and/or synthetic fibers. The layered bodies have an increased absorption capacity for water and aqueous liquids, in particular under load. They are manufactured by spreading out the foam, applying the superabsorber in the predetermined quantity ratio, optionally by using a stencil, and by fixing it by means of a heat treatment.
    Type: Grant
    Filed: November 22, 1996
    Date of Patent: June 9, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Helmut Bruggemann, Kurt Dahmen
  • Patent number: 5736595
    Abstract: A polymer composition, a process for the production of a polymer composition, in particular of an absorbent, are disclosed which substantially consist of a special component A based on renewable polysaccharide raw materials, a special component B consisting of a water-soluble polymer, a matrix material, an ionic and/or covalent cross-linking agent, or an anti-blocking agent, which is obtainable in that the water-swellable polymer is brought together with the polysaccharide polymer, that these are dried and ground then, the other components are added, and mixing up to homogeneity is effected followed by a heat treatment, and that during the addition of the cross-linking agent, after said heat treatment, the same is optionally fixed by the matrix by means of a final heat treatment.Additionally the use of this polymer composition and (animal) hygiene items and chemico-technical products are disclosed which comprise a previously manufactured polymer composition.
    Type: Grant
    Filed: November 3, 1995
    Date of Patent: April 7, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Uwe Gunther, Helmut Klimmek, Helmut Bruggemann
  • Patent number: 5733576
    Abstract: A process for the production of absorbing agents for water, aqueous solutions and body liquids consisting of at least two components A and B, whereby component A comprises a water-swellable, synthetic polymer or copolymer and component B comprises a natural or synthetic polymeric compound which at normal temperature is a pourable powder and is partially soluble or insoluble in water. Component B is added to component A in dry or partially swollen form during component A's production process after a monomer conversion of at least 30%, preferably at least 60% is attained, and is then mixed with the polymer gel of component A and subsequently dried.
    Type: Grant
    Filed: November 21, 1994
    Date of Patent: March 31, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventor: Miroslav Chmelir
  • Patent number: 5721295
    Abstract: A polymer composition, in particular an absorbent composition or an active substance-containing depot material are disclosed which substantially consist of a water-soluble and/or water-swellable polymer based on polysaccharides as the main component, and of a water-swellable polymer as further component, used as polymeric components, and of a matrix material for the prevention of separation and gel blocking, an ionic or covalent cross-linking agent, a reactive additive, as well as of an anti-blocking agent. Additionally, their production and use as well as (animal) hygiene items and chemico-technical products are disclosed which comprise these polymer compositions or absorbent compositions.
    Type: Grant
    Filed: January 26, 1996
    Date of Patent: February 24, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Helmut Bruggemann, Uwe Gunther, Helmut Klimmek
  • Patent number: 5712316
    Abstract: The present invention relates to powdery, water-swellable, cross-linked polymers having a high absorption capacity for aqueous liquids, in particular body fluids, under load, which polymers are formed of:a) 55-99.9%-wt. acid-groups-containing monomers which are neutralized to the extent of at least 50 mole-%,b) 0-40%-wt. of monomers which are copolymerizable with a),c) 0.1-5.0%-wt. of at least one cross-linking agent,d) 0-30%-wt. of a water-soluble polymer.The cations of the salts according to a) are Li.sup.+, Na.sup.+, preferably K.sup.+, Cs.sup.+, Rb.sup.+, as well as primary, secondary, and tertiary methyl ammonium ions, either alone or in combination. The polymers are manufactured in that a blowing agent based on carbon dioxide is added to the monomers, followed by polymerization, that the polymer is dried and then heated to a temperature of 100.degree.-300.degree. C. with one or several compounds which are reactive for surface cross-linkage.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: January 27, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Kurt Dahmen, Edgar Herrmann, Klaus Pfluger
  • Patent number: 5686555
    Abstract: The present invention relates to absorbents for aqueous acids or lyes comprising cross-linked, polycationic homopolymers and topolymers of quaternized, monoethylenically unsaturated carboxylic acid amino esters and/or carboxylic acid amides of the formula?CH.sub.2 =C(--R.sub.1)--CO--X--(CH.sub.2).sub.n --C(--R.sub.2, --R.sub.3)--CH.sub.2 --N(--R.sub.4,--R.sub.5,--R.sub.6)!.sup..sym. Y,(A),whereinR.sub.1 represents hydrogen or the methyl group,R.sub.2 and R.sub.3 represent hydrogen or the same or different alkyl groups having 1 to 4 C-atoms,R.sub.4, R.sub.5 and R.sub.6 represent the same or different alkyl groups having 1 to 4 C-atoms,n stands for 0 or 1,X stands for --O-- or --NH--, andY represents an anionic acid residue.
    Type: Grant
    Filed: April 7, 1995
    Date of Patent: November 11, 1997
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Kurt Dahmen, Reinmar Peppmoller, Uwe Gunther
  • Patent number: 5686011
    Abstract: A process is disclosed for waterproofing materials having a fibrous structure, such as leather, persian leather or leather replacement materials, by using waterproofing agents containing sulfosuccinic acid esters. Also disclosed are waterproofing agents used to carry out this process. The sulfosuccinic acid esters are prepared by reacting maleic anhydride with monohydric or polyhydric alcohols, then by sulfitizing them. Reactive siloxanes may also be used as polyhydric alcohols.
    Type: Grant
    Filed: February 8, 1995
    Date of Patent: November 11, 1997
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Helmut Lohmann, Manfred Kaussen, Leonardus Strijbos, Waldemar Inger
  • Patent number: 5672633
    Abstract: The present invention relates to powdery, insoluble, water-swellable, cross-linked polymers absorbing water, aqueous or serous liquids, which are formed ofa) 55-99.9%-wt. polymerized unsaturated, polymerizable acid-groups--comprising monomers which are neutralized to the extent of at least 25 mol-%,b) 0-40%-wt. polymerized unsaturated monomers which are co-polymerizable with a),c) 0.1-5.0%-wt. of a cross-linking agent, andd) 0-30%-wt. of a water-soluble polymer,with the weight amounts of a) to d) being relative to anhydrous polymer, and the polymer powder is heated with an at least bifunctional compound reactive with acid groups to a temperature of 150.degree. C.-250.degree. C. under cross-linkage of the surface, and the polymer powder that is thus already surface-cross-linked is subjected to a repeated surface-cross-linking treatment using an at least bifunctional compound reactive with acid groups at a temperature of 150.degree. to 250.degree. C.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: September 30, 1997
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Helmut Brehm, Hans-Georg Hartan
  • Patent number: 5658484
    Abstract: The present invention relates to anhydrous and water-containing agents for waterproofing leathers and furs, which comprise a silicone and as emulsifier an alkyl polyalkylol ether carboxylic acid and/or an alkylaryl polyalkylol ether carboxylic acid and/or one of their alkali, alkaline earth, ammonia, amine, or alkanolamine salts. The present invention further relates to the use of these agents for waterproofing, preferably in retanning or afterwards. Subsequent to the waterproofing, an aftertreatment using metallic salts of bito tetravalent cations may be carried out.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: August 19, 1997
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Helmut Lohmann, Wolfgang Hubner, Leonardus Strijbos, Waldemar Inger
  • Patent number: 5656177
    Abstract: The present invention relates to oil-in-water emulsions for the prevention of slime formation and for the reduction of microbial growth in water carrying systems. The emulsions comprise as component of the oil phase at least one of the following active substances:a saturated or unsaturated, open-chain normal or isomeric hydrocarbon having 8-30 carbon atoms.The emulsions have a proportion of the oil phase of 1 to 90 %-wt. and are used in an amount of 1 to 200 ppm and are free of toxic microbiocides.
    Type: Grant
    Filed: November 30, 1994
    Date of Patent: August 12, 1997
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventor: Joachim Werres
  • Patent number: 5610220
    Abstract: The invention relates to powdery cross-linked polymers (superabsorbers) capable of absorbing aqueous liquids and blood, which are formed of 55-99.9%-wt. polymerized unsaturated, polymerizable acid-groups-comprising monomers which are neutralized to the extent of at least 25 mol-%, b) 0-40%-wt. polymerized unsaturated monomers copolymerizable with a), c) 0.1-5.0%-wt. of a cross-linking agent, d) 0-30%-wt. of a water-soluble polymer, whereby the weight amounts of a) to d) relate to anhydrous polymers, characterized in that 100 parts of the particle-shaped polymers have been mixed with an aqueous solution consisting of a maximum of 10 parts of an at least 10% phosphoric acid and a) 0.05-0.3 parts of a compound capable of reacting with at least two carboxyl groups and not comprising an alkali-salt-forming group in the molecule, and/or b) 0.
    Type: Grant
    Filed: June 30, 1995
    Date of Patent: March 11, 1997
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Helmut Klimmek, Helmut Brehm
  • Patent number: 5580941
    Abstract: The present invention relates to water-soluble, acid-groups-containing graft copolymers which are at least partially biodegradable and are based on sugars and monoethylenically unsaturated carboxylic acids, sulfonic acids and/or phosphonic acids or the salts of said acids as well as optional further monomers. The present invention further relates to a process for producing the graft copolymers at temperatures of up to 200.degree. C. by means of radical polymerization initiators, in that a total mixture of 5-60 %-wt. mono-, di- and oligosaccharides, the derivatives thereof or the mixtures thereof, and 95-40 %-wt. of a monomer mixture comprising at least one monoethylenically unsaturated carboxylic acid, at least one monoethylenically unsaturated sulfonic acid, one monoethylenically unsaturated sulfuric acid ester and/or vinylphosphonic acid or the salts of said acids with monovalent cations, as well as optional further monomers is polymerized.
    Type: Grant
    Filed: December 29, 1994
    Date of Patent: December 3, 1996
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Frank Krause, Helmut Klimmek