Patents Assigned to Chevron Phillips Chemical Company, LP
  • Patent number: 12252558
    Abstract: Apparatuses and processes that produce multimodal polyolefins, and in particular, polyethylene resins, are disclosed herein. This is accomplished by using two reactors in series, where one of the reactors is a multi-zone circulating reactor that can circulate polyolefin particles through two polymerization zones optionally having two different flow regimes so that the final multimodal polyolefin has improved product properties and improved product homogeneity.
    Type: Grant
    Filed: November 3, 2023
    Date of Patent: March 18, 2025
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Joseph A. Curren, Rebecca A. Gonzales, Scott E. Kufeld, Joel A. Mutchler, Eric J. Netemeyer, Jamie N. Sutherland, Paul J. Deslauriers, Jeffrey S. Fodor
  • Publication number: 20250084327
    Abstract: Described are new processes for making sustainable jet fuels and components thereof, based upon generating bio-ethylene by dehydration of biomass ethanol or a bio-syngas ethanol, and subsequently employing a tailored selection of oligomerization, cyclization, and hydrogenation reactions to generate each class of compounds which can be used as components in a sustainable aviation fuel. For example bio-ethylene oligomerization can provide olefin oligomers which can be hydrogenated to linear and branched paraffins, these paraffins can be cyclized to form bio-sourced aromatic compounds which subsequently can be hydrogenated to form cycloparaffins or naphthenes. These compounds can be blended to provide sustainable products in the kerosene jet fuel range (C8-C16) or wide-cut jet fuel range (C5-C15 or C4-C16).
    Type: Application
    Filed: September 7, 2023
    Publication date: March 13, 2025
    Applicant: Chevron Phillips Chemical Company LP
    Inventors: Reza KHANKAL, Michael S. WEBSTER-GARDINER, James HILLIER, Jared FERN
  • Publication number: 20250084331
    Abstract: Process for making sustainable aviation fuel (SAF) from specific bio-ethylene oligomerization reactions producing a C4-C8 alpha-olefin and a by-product mixture of C10 olefins. This mixed decene stream is upgraded by further oligomerizing with at least one C4-C6 alpha-olefin to provide a C16? olefin stream, which is hydrogenated to C16? paraffins which is used to form a SAF. Employing bio-ethylene to produce the mixed decene stream, which is relatively low-value due in part to its non-selectivity, leverages that non-selectivity into a desirable sustainable aviation fuel product where the low selectivity is preferable. These and other embodiments and aspects are described herein.
    Type: Application
    Filed: September 7, 2023
    Publication date: March 13, 2025
    Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP
    Inventors: Michael S. Webster-Gardiner, James Hiller, Reza Khankal, Jared Fern
  • Patent number: 12246312
    Abstract: Disclosed herein are methods for preparing fluorided solid oxides by contacting an acidic fluorine-containing compound with an inorganic base to form an aqueous mixture having a pH of at least 4, followed by contacting a solid oxide with the aqueous mixture to produce the fluorided solid oxide. Also disclosed are methods for preparing fluorided solid oxides by contacting an acidic fluorine-containing compound with a solid oxide to produce a mixture, followed by contacting the mixture with a inorganic base to produce the fluorided solid oxide at a pH of at least about 4. The fluorided solid oxide can be used as an activator component in a catalyst system for the polymerization of olefins.
    Type: Grant
    Filed: April 18, 2024
    Date of Patent: March 11, 2025
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Max P. McDaniel, Kathy S. Clear, Qing Yang, Tony R. Crain
  • Patent number: 12240964
    Abstract: Disclosed herein are ethylene-based polymers generally characterized by a melt index of less than 15 g/10 min, a density from 0.91 to 0.945 g/cm3, a CY-a parameter at 190° C. from 0.2 to 0.6, an average number of long chain branches per 1,000,000 total carbon atoms of the polymer in a molecular weight range of 500,000 to 2,000,000 g/mol of less than 5, and a maximum ratio of ??/3? at an extensional rate of 0.03 sec?1 in a range from 3 to 15. The ethylene polymers have substantially no long chain branching in the high molecular weight fraction of the polymer, but instead have significant long chain branching in the lower molecular weight fraction, such that polymer melt strength and bubble stability are maintained for the fabrication of blown films and other articles of manufacture.
    Type: Grant
    Filed: May 14, 2024
    Date of Patent: March 4, 2025
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Errun Ding, Chung Ching Tso, Max P. McDaniel, Ashish M. Sukhadia, Youlu Yu, Randall S. Muninger, Aaron M. Osborn, Christopher E. Wittner
  • Patent number: 12240933
    Abstract: Methods for preparing a metallocene-based catalyst composition that can impact the long chain branching of ethylene homopolymers and copolymers produced using the catalyst composition are described. The catalyst composition can be prepared by contacting a metallocene compound, a hydrocarbon solvent, and a first organoaluminum compound for a first period of time to form a metallocene solution, and then contacting the metallocene solution with an activator-support and a second organoaluminum compound for a second period of time to form the catalyst composition.
    Type: Grant
    Filed: February 23, 2024
    Date of Patent: March 4, 2025
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Qing Yang, Max P. McDaniel, Tony R. Crain
  • Patent number: 12234348
    Abstract: Ethylene-based polymers having a density of 0.952 to 0.965 g/cm3, a high load melt index (HLMI) from 5 to 25 g/10 min, a weight-average molecular weight from 275,000 to 450,000 g/mol, a number-average molecular weight from 15,000 to 40,000 g/mol, a viscosity at HLMI from 1400 to 4000 Pa-sec, and a tangent delta at 0.1 sec?1 from 0.65 to 0.98 degrees. These polymers have the processability of chromium-based resins, but with improved stress crack resistance, and can be used in large-part blow molding applications.
    Type: Grant
    Filed: May 17, 2022
    Date of Patent: February 25, 2025
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Carlos A. Cruz, Yongwoo Inn, Justin Lumbley, Brandy Rutledge-Ryal, John R. Rathman, Jennifer L Hicks, Jay M. Chaffin
  • Publication number: 20250050323
    Abstract: Methods of improving metal dispersion of a catalyst, such as by contacting a spent catalyst and a stream including chlorine gas, and a stream including oxygen gas to form a regenerated catalyst. The regenerated catalyst may be used to catalyze a chemical reaction, and, after the chemical reaction, be regenerated one or more additional times.
    Type: Application
    Filed: August 11, 2023
    Publication date: February 13, 2025
    Applicant: Chevron Phillips Chemical Company LP
    Inventors: Gabriela D. ALVEZ, Joseph J. BERGMEISTER, Cori DEMMELMAIER-CHANG
  • Publication number: 20250043036
    Abstract: Chain transfer agent compositions that can include mixed mercaptans. Emulsion polymerization reaction mixtures that can include a chain transfer agent composition, one or more monomers, and one or more polymerization initiators. Methods of polymerization, which can include providing an emulsion polymerization reaction mixture, and isolating a polymer product from the emulsion polymerization reaction mixture.
    Type: Application
    Filed: July 24, 2024
    Publication date: February 6, 2025
    Applicant: Chevron Phillips Chemical Company LP
    Inventors: Jason L. Kreider, Dale M. Solaas, Kenneth M. Lassen, Rodney S. Childress
  • Patent number: 12209063
    Abstract: Processes for removing carbon disulfide from product streams containing a sulfide compound are performed by contacting the product stream with an alkanolamine and converting the carbon disulfide to a higher boiling point product, thereby reducing or eliminating carbon disulfide from the product stream. Subsequent removal of the higher boiling point product via distillation can lead to a purified sulfide stream with high purity.
    Type: Grant
    Filed: November 14, 2023
    Date of Patent: January 28, 2025
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Kenneth M. Lassen, Michael S. Matson, Daniel M. Hasenberg, Dave C. Schwierman
  • Patent number: 12202914
    Abstract: Processes for activating chromium polymerization catalysts, which can use lower maximum activation temperatures and shorter activation times than conventional activation methods, and provide polyethylenes with high melt indices, broader molecular weight distributions, and lower long chain branching content. The activation process can comprise heating a supported chromium catalyst in an inert atmosphere to a first temperature (T1) for a first hold time (tH1), followed by allowing the chromium catalyst to attain a second temperature (T2) in the inert atmosphere, then contacting the chromium catalyst with an oxidative atmosphere for a second hold time (tH2), in which T2 can be less than or equal to T1. Additional activation treatments and conditioning steps are disclosed which can be used to enhance the melt index potential of Phillips (Cr/silica) catalysts.
    Type: Grant
    Filed: September 20, 2021
    Date of Patent: January 21, 2025
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Max P. McDaniel, Kathy S. Clear, William C. Ellis, Deloris R. Gagan, Ted H. Cymbaluk
  • Patent number: 12203701
    Abstract: A hydrocarbon recovery system is integrated with a fluff transfer system. The hydrocarbon recovery system is configured for contacting a wet polymer fluff with a purge gas to provide a purged polymer fluff and an overhead stream, and separating a solids stream, a recovered hydrocarbon stream, and a recovered purge gas from the overhead stream. The polymer fluff transfer system is configured to receive the purged polymer fluff from the hydrocarbon recovery system and transport the purged polymer fluff in the fluff transfer system via circulation of a fluff transfer gas. The hydrocarbon recovery system and the fluff transfer system are integrated by utilizing at least a portion of the recovered purge gas from the hydrocarbon recovery system in the fluff transfer system as the fluff transfer gas and optionally utilizing fluff transfer gas from the fluff transfer system as the purge gas in the hydrocarbon recovery system.
    Type: Grant
    Filed: September 15, 2023
    Date of Patent: January 21, 2025
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Reza Khankal, Enrique Mancillas, Kamaljeet Kaur, Hetian Li
  • Patent number: 12195562
    Abstract: Polymerization processes and reactor systems for producing multimodal ethylene polymers are disclosed in which at least one loop reactor and at least one fluidized bed reactor are utilized. Configurations include a loop reactor in series with a fluidized bed reactor and two loop reactors in series with a fluidized bed reactor.
    Type: Grant
    Filed: November 1, 2023
    Date of Patent: January 14, 2025
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Joel A. Mutchler, Eric J. Netemeyer, Joseph A. Curren, Michael H. Treptau, Kenneth A. Dooley, Jeffrey S. Lowell, Jeffrey S. Fodor, Scott E. Kufeld
  • Patent number: 12173094
    Abstract: Disclosed is a process for operating a flashline heater and a flashline separation system. In the process and system, heat is supplied to the flashline heater by a first steam stage followed by a second steam stage. The steam pressure is controlled by a steam control system such that the pressure in the first steam stage is not equal to the pressure in the second steam stage. Also disclosed is a process for retrofitting a steam control system in a flashline separation system of an olefin polymerization system at least by changing the number of steam stages in the flashline separation system to include a first steam stage followed by a second steam stage, and changing the stream pressure control scheme such that the pressure in the first steam stage is independently controlled to be not equal to the pressure in the second steam stage.
    Type: Grant
    Filed: August 21, 2023
    Date of Patent: December 24, 2024
    Assignee: Chevron Phillips Chemical Company LP
    Inventor: Hetian Li
  • Patent number: 12173136
    Abstract: Polymer compositions containing an ethylene polymer, 50-1500 ppm by weight of a glycerol stearate, and 250-7500 ppm by weight of an antioxidant selected from a phenolic antioxidant, a phosphite antioxidant, a thioester antioxidant, or any combination thereof, are described. These polymer compositions have improved initial color, improved color after long-term aging, or improved color after multi-pass extrusion processing.
    Type: Grant
    Filed: October 7, 2022
    Date of Patent: December 24, 2024
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Justin W. Kamplain, Elizabeth M. Lanier
  • Patent number: 12168754
    Abstract: A pyrolysis oil fractionation system for treating a pyrolysis oil feed includes a fractionation column, at least one treatment catalyst bed, and a plurality of distillation trays. The system further includes a condenser to receive a light fraction and produce a condensed gasoline product and a vapor, a receiver coupled to the condenser, a knockout drum, and a distillate stripper coupled to the fractionation column. A method for treating a pyrolysis oil feed includes, in a fractionating column, dehydrohalogenating, decontaminating, and/or dehydrating a pyrolysis oil feed in at least one treatment catalyst bed, and distilling the treated pyrolysis oil feed into a light fraction, a middle fraction, a heavy fraction, and a bottom fraction. The method further includes condensing the light fraction and producing a condensed gasoline product and a vapor, separating a fuel gas product from the vapor, and stripping the middle fraction to produce a distillate product.
    Type: Grant
    Filed: March 16, 2022
    Date of Patent: December 17, 2024
    Assignee: Chevron Phillips Chemical Company LP
    Inventor: Steven R. Horlacher
  • Patent number: 12161997
    Abstract: Methods for synthesizing a water-soluble titanium-silicon complex are disclosed herein. The titanium-silicon complex can be utilized to produce titanated solid oxide supports and titanated chromium supported catalysts. The titanated chromium supported catalysts subsequently can be used to polymerize olefins to produce, for example, ethylene based homopolymer and copolymers.
    Type: Grant
    Filed: November 29, 2023
    Date of Patent: December 10, 2024
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Max P. McDaniel, Kathy S. Clear, Eric D. Schwerdtfeger, Jeremy M. Praetorius
  • Patent number: 12162829
    Abstract: Catalysts and catalytic processes for the synthesis of acrylic acid and other ?,?-unsaturated carboxylic acids and their salts, which are carried out in a diluent or in the absence of a diluent. In an aspect, ethylene and CO2 can be contacted with a Group 8-11 transition metal precursor compound or a Group 8-11 transition metal metalalactone compound in the presence of a metal-treated chemically-modified solid oxide (MT-CMSO) or a metal-treated solid oxide (MT-SO), to form a metal acrylate. As the catalytic activity wanes in either the presence or absence of a diluent, pressure cycling—that is, pressurizing the reaction system with CO2 and an olefin such as ethylene for a time period, releasing the pressure, then re-pressurizing with CO2 and ethylene—can rejuvenate the catalyst and restore its declining catalytic activity.
    Type: Grant
    Filed: December 16, 2021
    Date of Patent: December 10, 2024
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Pasquale Iacono, Jamie N. Sutherland, Carlton E. Ash, Anand Ramanathan
  • Patent number: 12157109
    Abstract: Methods for making a supported chromium catalyst are disclosed, and can comprise contacting a silica-coated alumina containing at least 30 wt. % silica with a chromium-containing compound in a liquid, drying, and calcining in an oxidizing atmosphere at a peak temperature of at least 650° C. to form the supported chromium catalyst. The supported chromium catalyst can contain from 0.01 to 20 wt. % chromium, and typically can have a pore volume from 0.5 to 2 mL/g and a BET surface area from 275 to 550 m2/g. The supported chromium catalyst subsequently can be used to polymerize olefins to produce, for example, ethylene-based homopolymers and copolymers having high molecular weights and broad molecular weight distributions.
    Type: Grant
    Filed: May 3, 2023
    Date of Patent: December 3, 2024
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Max P. McDaniel, Kathy S. Clear
  • Publication number: 20240392119
    Abstract: A method of operating a polyethylene reactor system includes feeding ethylene, an optional first comonomer, a diluent, and a chromium-based catalyst to a first polymerization reactor. The method further includes contacting ethylene and the comonomer with the catalyst in the first polymerization reactor to form a first product including a first polyethylene. The method further includes feeding the first product from the first polymerization reactor to a second polymerization reactor. The method further includes contacting ethylene and a second optional comonomer with catalyst from the first reactor in the second polymerization reactor to form a second product including the first polyethylene and a second polyethylene. The method further includes controlling one or both of a molecular weight or a breadth of molecular weight distribution of the second product by adjusting a rate of hydrogen fed to one or both of the first polymerization reactor or the second polymerization reactor.
    Type: Application
    Filed: August 7, 2024
    Publication date: November 28, 2024
    Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP
    Inventors: Daniel G. Hert, Bryan G. Kubsch