Abstract: Disclosed are polyaminoalkenyl or alkyl succinimides which have been modified by treatment with a compound of the formula: ##STR1## wherein W is oxygen or sulfur; X is oxygen or sulfur; R.sub.4 is an alkylene group of from 2 to 3 carbon atoms or an alkylene group of from 2 to 3 carbon atoms substituted with from 1 to 3 alkyl groups of from 1 to 2 carbon atoms each; and R.sub.5 is hydrogen or alkyl of from 1 to 20 carbon atoms. The modified polyamino alkenyl or alkyl succinimides of this invention have been found to possess dispersancy and detergency in lubricating oils. These modified succinimides are also useful as dispersants and detergents in fuels.
Abstract: A process for dewaxing and stabilizing a hydrocracked bright stock, comprising hydrodenitrification, catalytic dewaxing, and mild hydrofinishing.
Abstract: Disclosed are additives which are useful as dispersants in lubricating oils, gasolines, marine crankcase oils and hydraulic oils. In particular, disclosed are multiply adducted alkenyl or alkyl succinimides which contain carbamate functionalities.
Abstract: Disclosed are additives which are useful as dispersants in lubricating oils, gasolines, marine crankcase oils and hydraulic oils. In particular, disclosed are polyamino alkenyl or alkyl succinimides which contain carbamate functionalities.
Type:
Grant
Filed:
August 27, 1987
Date of Patent:
May 24, 1988
Assignee:
Chevron Research Company
Inventors:
Robert H. Wollenberg, Frank Plavac, Timothy R. Erdman
Abstract: Process for functionalizing saturated hydrocarbons comprising:(a) reacting said saturated hydrocarbons of the formula:R.sub.1 Hwherein H represents a hydrogen atom; and R.sub.1 represents a saturated hydrocarbon radical, with a metal complex of the formula:CpRh[P(R.sub.2).sub.3 ]H.sub.2whereinCp represents a cyclopentadienyl or alkylcyclopentadienyl radical;Rh represents a rhodium atom;P represents a phosphorus atom;R.sub.2 represents a hydrocarbon radical;H represents a hydrogen atom,in the presence of ultraviolet radiation to form a hydridoalkyl complex of the formula:CpRh[P(R.sub.2).sub.3 ](R.sub.1)H(b) reacting said hydridoalkyl complex with an organic halogenating agent such as a tetrahalomethane or a haloform of the formulas:CX'X''X'''X'''' or CHX'X''X'''wherein X', X'', X'", X"" represent halogens selected from bromine, iodine or chlorine atom, at a temperature in the range of about -60.degree. to -17.degree. C. to form the corresponding haloalkyl complex of step (a) having the formula:CpRhPMe.sub.
Type:
Grant
Filed:
February 21, 1985
Date of Patent:
May 24, 1988
Assignee:
Chevron Research Company
Inventors:
Robert G. Bergman, Andrew H. Janowicz, Roy A. Periana
Abstract: Disclosed are additives which are useful as dispersants in marine crankcase oils and hydraulic oils, lubricating oils. In particular, disclosed are hydrocarbyl-substituted polyamines having at least one primary or secondary amino group which have been modified by treatment with a cyclic carbonate.
Abstract: The present invention is an apparatus of mechanically stacked photovoltaic cells having a bottom heat spreader and a top heat spreader, a bottom photovoltaic cell and a top photovoltaic cell, and means for forming the necessary electrical contacts. The heat spreaders are electrically insulated from each other but are thermally connected to each other. The bottom photovoltaic cell has an anode and a cathode and is thermally bonded to the bottom heat spreader and is thermally connected to the top heat spreader. The top photovoltaic cell has an anode and a cathode, is electrically insulated from the bottom photovoltaic cell, and is thermally bonded to the top heat spreader and is thermally connected to the bottom heat spreader.
Type:
Grant
Filed:
December 18, 1986
Date of Patent:
May 24, 1988
Assignee:
Chevron Research Company
Inventors:
Paul S. McLeod, John A. Cape, Lewis M. Fraas, Larry D. Partain
Abstract: The present invention is directed toward a method for preparing Group II metal overbased sulfurized alkylphenols. In particular, the present invention employs a sulfurization catalyst in the preparation of Group II metal overbased sulfurized alkylphenols. Use of a sulfurization catalyst in this preparation results in a product generally characterized as having lower crude sediment, a higher Total Base Number and lower viscosity than a similar product prepared without using a sulfurization catalyst.
Abstract: We disclose a catalyst system which is capable of removing sodium from a hydrocarbon feed having at least 1 ppm oil-soluble sodium. It comprises a catalyst layer characterized as a fixed bed of catalyst particles having a low volume percent of their pore volume percent in the form of macropores above 1000 .ANG. in diameter, high surface area, and high hydrogenation activity. We also disclose a process of using the system.
Abstract: A method for oxidatively degrading an olefinic polymer in the absence of molecular oxygen and utilizing an oxidant mixture of a peroxide and hydroperoxide is disclosed. Lubricating oils containing the products of the oxidation process as well as the products post-reacted with funtional group-containing compounds show improved viscosity index and dispersancy properties.
Abstract: We disclose a catalyst system which is capable of removing calcium from a hydrocarbon feed having at least 1 ppm oil-soluble calcium. It comprises a catalyst layer characterized as a fixed bed of catalyst particles, a high volume percent of their pore volume in the form of macropores above 1000 .ANG. in diameter, low surface area, and low hydrogenation activity. We also disclose a process of using the system.
Abstract: Cupric, lithium, and magnesium salts of trans-substituted 2-[1-(3-chloroallyloxyimino)alkylidene]-cyclohexane-1,3-dione and derivatives thereof. The compounds generally exhibit improved stability and enhanced shelf-life while retaining excellent pre-emergence and post-emergence grassy weed phytotoxicity. The compounds are useful as selective herbicides and at low dosages as plant growth regulating agents.
Abstract: A process for removing residual sulfur from a hydrotreated naphtha feedstock is disclosed. The feedstock is contacted with molecular hydrogen under reforming conditions in the presence of a less sulfur sensitive reforming catalyst, thereby converting trace sulfur compounds to H.sub.2 S, and forming a first effluent. The first effluent is contacted with a solid sulfur sorbent, removing the H.sub.2 S and forming a second effluent. The second effluent is contacted with a highly selective reforming catalyst under severe reforming conditions.
Type:
Grant
Filed:
October 31, 1984
Date of Patent:
May 3, 1988
Assignee:
Chevron Research Company
Inventors:
Richard C. Robinson, Robert L. Jacobson, Leslie A. Field
Abstract: Apparatus for increasing the overall efficiency of fluidized catalytic cracking (FCC) with crystalline zeolitic catalysts is disclosed. Separated or spent cracking catalyst after reaction with hydrocarbonaceous material is first stripped and then subjected to an additional period of time in the presence of steam in the dense phase before the catalyst is returned to a regenerator. In a preferred form the spent catalyst after normal steam stripping is subjected to an additional period from 1/2 to 30 minutes at elevated temperature. This time is from 6 to 900 times the reaction time of the catalyst and hydrocarbonaceous mixture in an FCC reactor riser pipe. Such additional contact time for steam to react with the spent catalyst and/or coke produces significant beneficial results in FCC performance.
Abstract: This invention relates to the preparation of small spheroidal solid agglomerates. More particularly, the process produces strong solid spheroidal agglomerates containing alumina or a mixture of alumina and at least one other inorganic material, which process comprises:(a) mixing at high speed a portion of alumina or a mixture of alumina and at least one other inorganic material in the form of hydrophilic micron-sized particles in a water-immiscible liquid thereby forming a dispersion;(b) gradually adding to the dispersion an aqueous acidic phase while continuing the high-speed mixing until substantially spherical micro-agglomerates form within the water-immiscible liquid;(c) subjecting the micro-agglomerates to agitation in a vessel having a hydrophobic inner surface at a speed low enough to achieve substantially uniformly sized spheroidal agglomerates;(d) drying the agglomerates to produce hardened spheroidal uniformly sized agglomerates; and(e) optionally further separating the agglomerates by size.
Abstract: In accordance with the present invention, a constraint dependent control method and system for a large scale refinery, chemical process or the like, is provided that allows on-line optimization of one and preferably two plant inputs without need for optimal set points, through iterative generation of a constraint dependent control code normalized to present time t for "driving" the optimized plant inputs rapidly toward optimization but without destabilizing the plant. The generation of such control code includes evaluation of certain key components associated with elements of an optimizing and stabilizing control vector (OSC) from which the code is derived.
Abstract: Disclosed are Bis-Mannich base deposit inhibitors; lubricating oil compositions containing these inhibitors and a process for preparing these inhibitors.
Abstract: Disclosed is a catalytic process for the production of higher molecular weight hydrocarbons from lower molecular weight hydrocarbons. More particularly, disclosed is a catalytic process for the conversion of methane to C.sub.2 + hydrocarbons, particularly hydrocarbons rich in ethylene or benzene, or both. The process utilizes a metal-containing catalyst, high reaction temperature of greater than 1000.degree. C., and a high gas hourly space velocity of greater than 3200 hr.sup.-1.
Abstract: Compounds of the formula ##STR1## wherein Het is a 5- or 6-membered aromatic heterocyclic ring containing 1 to 2 ring nitrogen atoms and the remaining ring atoms carbon atoms optionally substituted with 1 to 2 substituents independently selected from halo, nitro, trihalomethyl, lower alkyl of 1 to 3 carbon atoms, or lower alkoxy of 1 to 3 carbon atoms; R is alkyl of 1 to 7 carbon atoms; R.sup.1 is aryl of 6 to 10 carbon atoms, lower alkyl of 1 to 6 carbon atoms, cycloalkyl of 3 to 8 carbon atoms, all optionally substituted with 1 to 3 halogen atoms; and a is 0 or 1 are fungicidal and insecticidal, with the proviso that a ring nitrogen is not bonded to the hydroxamic acid ##STR2## moiety.
Abstract: A punch tool is disclosed for puncturing the walls of heat exchanger tubes when they become worn in order that the tubes may be repaired. Said tool comprises a hardened, longitudinally drilled, steel rod that is able to fit within the heat exchanger tube. A piston with a cutting bit is fit within a milled slot that communicates with the longitudinally drilled hole of the hardened rod. Once the tool is inserted into a tube to be repaired hydraulic pressure is applied and the piston is forced outward thereby puncturing the tube.