Abstract: The present invention relates to a process for the recovery and refining of rhodium starting from a mixture containing rhodium and other transition metals, including those of the platinum Group, as well as metals of the main Groups, said process comprising the following passages: a) formation of an adduct between rhodium trichloride and a halide of a metal selected from metals of Groups IIA, IIIA, IVA, IVB, VB and VIB; b) carbonylation of the precipitated adduct, deriving from passage a) with the formation of rhodium halogen carbonyls and c) sublimation of the carbonylated product obtained in the previous passage. The main advantage of the above process consists in the production of an extremely pure product, with excellent yields.

Abstract: The present invention relates to an electrolytic gold and silver refining cell for extracting gold and silver contained in a material. The cell is part of a plurality of cells arranged in at least one common vessel provided with a solution feeding inlet, an exhausted solution outlet, and a stirrer. The cell is also provided with a plate cathode consisting of an acid-proof material and a plate anode consisting of the abovementioned material containing Au and Ag. The material is introduced into a filtering bag. The cathode and anode electrodes are suspended parallel to each other within the common vessel and are inserted in parallel in a d.c. supplied network. The invention is characterized by the fact that the vessel, housing a plurality of side by side cells, is provided with a hopper bottom with an outlet conduit controlled by a first normally open valve and connected to a larger conduit provided at its end with a second normally closed valve.