Abstract: A ligand based chromium catalyst and application in catalyzing ethylene oligomerization are disclosed. The chromium catalyst is formed by a chromium compound and an organic ligand containing P and/or N. The substituents on N and P of the ligand can be replaced, whereby selective ethylene trimerization and tetramerization can be realized so as to produce 1-hexene and 1-octene at the same time.
Type:
Grant
Filed:
October 19, 2016
Date of Patent:
January 15, 2019
Assignees:
CHINA PETROLEUM & CHEIMCAL CORPORATION, XIAMEN UNIVERSITY, SHANGHAI RESEARCH INSTITUTE OF CHEMICAL INDUSTRY