Patents Assigned to Chinese Petroleum Corp.
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Patent number: 8269049Abstract: The present invention fabricates diethylene-glycol tert-butyl ether (DEGtBE) by using isobutylene and diethylene glycol (DEG) coordinated with an acidic cation exchanged resin as catalyst. Through two stages of vacuum distillations, highly selective and pure DEGtBE is produced. Moreover, a byproduct of diethylene-glycol di-tert-butyl ether (DEGDtBE) can be recycled.Type: GrantFiled: December 31, 2009Date of Patent: September 18, 2012Assignee: Chinese Petroleum Corp.Inventors: Ming-Yu Huang, Jen-Chun Chang, Jann-Chen Lin, Kuen-Hai Lin, Jung-Chung Wu
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Patent number: 7488860Abstract: An exo-tetrahydrodicyclopentadiene is produced from endo-tetrahydrodicyclopentadiene through isomerization reaction. An acidic ionic liquid is used in the isomerization. The isomerization of endo-tetrahydrodicyclopentadiene gives a reaction conversion and a selectivity both higher than 99%. Besides, the ionic liquid used is environmental-friendly and recyclable.Type: GrantFiled: September 13, 2006Date of Patent: February 10, 2009Assignee: Chinese Petroleum Corp.Inventors: Ming-Yu Huang, Jen-Chun Chang, Jann-Chen Lin, Kun-Hai Lin, Jung-Chung Wu
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Publication number: 20080064909Abstract: An exo-tetrahydrodicyclopentadiene is produced from endo-tetrahydrodicyclopentadiene through isomerization reaction. An acidic ionic liquid is used in the isomerization. The isomerization of endo-tetrahydrodicyclopentadiene gives a reaction conversion and a selectivity both higher than 99%. Besides, the ionic liquid used is environmental-friendly and recyclable.Type: ApplicationFiled: September 13, 2006Publication date: March 13, 2008Applicant: CHINESE PETROLEUM CORP.Inventors: Ming-Yu Huang, Jen-Chun Chang, Jann-Chen Lin, Kun-Hai Lin, Jung-Chung Wu
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Patent number: 7253278Abstract: A process for purifying and preparing highly pure acarbose from acarbose-containing fermentation broth. The acarbose is purified through steps of alcohol precipitation, a strongly acidic cation exchanger chromatography and an immobolized enzyme affinity chromatography. Acarbose is generally applied in treating diabetes.Type: GrantFiled: March 2, 2004Date of Patent: August 7, 2007Assignee: Chinese Petroleum CorpInventors: Chung-Liang Lin, Tung-Li Huang, Jeen-Kuan Chen, Chi-Sheng Wu
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Patent number: 6576181Abstract: A process for producing a high gasoline permeation resistant plastic blend container, comprising preparing a modified polyamide by modifying polyamide with a compatibilizer precursor and then laminar blend blow-molding using a cheap conventional blow-molding machine from a composition of a polyolefin incorporated with a modified polyamide (MPA) into a bottle. The invention relates further to a high gasoline permeation resistant container obtained according to the above-described process, characterized in that it consists of a MPA laminar structure within a HDPE matrix, and has a gasoline permeation resistance of less than 5 vol. % of the total gasoline content thereof after storage at 40° C. for one year.Type: GrantFiled: November 27, 2000Date of Patent: June 10, 2003Assignee: Chinese Petroleum Corp.Inventor: Jen-Taut Yeh
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Patent number: 6476238Abstract: A purification method for obtaining high-purity PMDA. The method controls temperatures of cyclone separators in a series to separate PMDA and other by-products of different sublimation temperatures. High-purity PMDA is collected in the first cyclone separator, and no other purification steps are needed.Type: GrantFiled: May 16, 2001Date of Patent: November 5, 2002Assignee: Chinese Petroleum Corp.Inventors: Shiao-Jung Chu, Chien-Liang Hwang
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Patent number: 6458292Abstract: A composition for an anti-scale-forming agent includes oil-based polyalkylenes, amines phosphorous and oxygen in a polymer for providing dispersivity and anti-oxidation and having the following formula: By integrating both characteristics into a single polymer, the anti-scale-forming agent in accordance with the present invention can be used as an anti-scale-forming agent for a manufacturing process in a petroleum refinery plant or the like chemistry factory. R1, R2 and x are defined herein.Type: GrantFiled: October 12, 2000Date of Patent: October 1, 2002Assignee: Chinese Petroleum Corp.Inventors: Jiang-Jen Lin, Jann-Chen Lin, Wen-Hen L{dot over (o)}, Wen-Shwong Hwang, Kun-Hai Lin
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Patent number: 6454818Abstract: The present invention is one kind of gasoline additives. The compounds consist of tertiary amine, amide and poly(oxybutylene) backbone in the same molecule. The process of making this type of products required an initiator containing primary amine and tertiary amine as the starting diamines. The primary amine will be converted into amide, while the tertiary amine remained intact. Then the amide is converted into butoxylates through butoxylation at CON—H position. The preparation therefore involved two steps: (1) amidation of diamines containing primary/tertiary amines with ethyl acetate to form amidoamines, and (2) butoxylation of this amidoamines to poly(oxybutylene)amidoamine. The product is gasoline soluble and can be used as additive having good performance of detergency and octane requirement reduction.Type: GrantFiled: August 28, 2000Date of Patent: September 24, 2002Assignee: Chinese Petroleum Corp.Inventors: Jiang-Jen Lin, Wei-Shiun Ku, Che-Nan Lee, Yung-Sheng Ho, Kun-Hai Lin, Kuo-Min Wei
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Patent number: 6319486Abstract: The present invention relates to a method for synthesizing mesoporous aluminosilicate or pure-silica molecular sieves with newly hierarchical morphologies by adding suitable amount of alcohol. There are hollow sphere, hollow sphere with a pillar in it and solid sphere by adjusting the Al2O3/SiO2 and tetraethylorthosilicate/SiO2 ratio. The wall of the micron-sized spherical structure consisted of well-ordered cylindrical pores of nanometer size. The dimensions and the morphologies of the mesoporous structure are adjustable by varying the reaction components as the water content, the silicon/surfactant ratio and the reaction and the hydrothermal temperature.Type: GrantFiled: September 22, 1999Date of Patent: November 20, 2001Assignee: Chinese Petroleum Corp.Inventors: Chung-Yuan Mou, Hong-Ping Lin
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Patent number: 6291554Abstract: Disclosed is an anionic, self-emulsified aqueous epoxy resin dispersion prepared through the semi-esterification reaction between a dicarboxylic acid anhydride and the secondary hydroxy group of an epoxy resin, followed by neutralization of the carboxylic acid thus introduced into the epoxy resin with a tertiary amine and then adding only water, without the need of any emulsifier, to the resulting hydrophilic amine salt of the carboxylic acid. The stable aqueous epoxy resin contains both carboxyl and epoxy groups which are reactive functional groups. Also disclosed is a “single-pack” curable aqueous epoxy resin system “cross-linkable” at normal temperature prepared by adding a compound containing polyaziridine as a cross-linking agent into the aqueous epoxy resin dispersion. Upon drying, the liberated carboxyl group in the aqueous epoxy resin reacts with the polyaziridine to form an amino ester via a ring opening reaction.Type: GrantFiled: October 29, 1999Date of Patent: September 18, 2001Assignee: Chinese Petroleum Corp.Inventors: Tsorng-Wen Chen, Jen-Taut Yeh, Kan-Nan Chen, Yun-Shan Lin
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Patent number: 6228790Abstract: A novel dinuclear metallocene complex is disclosed, which is represented by the following formula (I): wherein M1 and M2 are the same or different and are independently selected from the group consisting of Group IIIB, Group IVB and Group VB transition metals; each X is the same or different and is indepedently an anionic ligand with −1 valence, which is selected from the group consisting H, C1-20 hydrocarbyl, halogen, C1-20 alkoxy, C1-20 aryloxy, NH2, NHR11, NR11R12, —(C═O)NH2, —(C═O)NHR13, and —(C═O)NR13R14, wherein R11, R12, R13 and R14 are C1-20 alkyl; i is an integer from 1 to 3; j is an integer from 1 to 3, R1, R2, R3, R4, R5, R6, R7, and R8 are the same or different and are independently H, a C1-20 linear, branched or cyclic hydrocarbyl group, or a C2-4 cyclic hydrocarbylene group which forms a C4-6 fused ring system; Y1 and Y2 are the same or different and each is an electron-donating group independently selected from a Group 15 or Group 16 elemType: GrantFiled: June 29, 1998Date of Patent: May 8, 2001Assignees: Industrial Technology Research Institute, Chinese Petroleum Corp., Taiwan Synthetic Rubber CorporationInventors: Ching Ting, Sung-Song Hua, Jing-Cherng Tsai, Bor-Ping Wang
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Patent number: 6084109Abstract: The present invention relates to a process for preparing pyromellitic dianhydride via an oxidation in gas phase under normal pressure. The process is characterized in that a catalyst system is used, which catalyst system comprises a catalyst which is a mixture of vanadium and tungsten oxides; a catalyst support comprising rutile and at least one material selected from the group consisting of tungsten carbide, silicon carbide and a mixture thereof; and a cocatalyst comprising oxides of manganese, antimony, bismuth, phosphorus, copper, aluminum, titanium or a mixture thereof, an oxide of an element of the VIIIB group of the periodic table, and an oxide of an alkali metal and/or alkaline earth metal. In this process, pyromellitic dianhydride is produced from a feedstream containing 1,2,4,5-tetraalkylbenzene in a gas flow rate of 4,000.about.12,000 hr.sup.-1 via a selective oxidation at 300.about.450.degree. C. in the presence of air which acts as an oxidant.Type: GrantFiled: April 16, 1999Date of Patent: July 4, 2000Assignee: Chinese Petroleum Corp.Inventors: Shiao-Jung Chu, Chian-Liang Hwang
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Patent number: 5498353Abstract: A semi-synthetic two-stroke engine oil formulation which comprises a base oil consisting of a high-viscosity mineral oil, a medium-viscosity mineral oil, a solvent and a mixture of three polyisobutylenes with different molecular weights, and appropriate detergents and dispersants. This semi-synthetic two-stroke engine has both high lubricity and high detergency, and also meets the requirements of low smoke and low exhaust system blocking.Type: GrantFiled: November 22, 1994Date of Patent: March 12, 1996Assignee: Chinese Petroleum Corp.Inventors: Ron-Sheng Lin, Chen-Yi Lin, Tsae-Shycm Lee, Chi-Chung Chen, Su-Terng Chang, Kuo-Min Wei
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Patent number: 5130285Abstract: The present invention is related to a process of fuel oil hydrodesulfurization and hydrodenitrogenation, wherein cobalt-molybdenum catalysts are utilized, which are supported on a carrier of titanium-zirconium-molybdenum mixed oxides.Type: GrantFiled: January 8, 1991Date of Patent: July 14, 1992Assignee: Chinese Petroleum Corp.Inventors: Ikai Wang, Jung-Chung Wu
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Patent number: 5032253Abstract: The present invention is related to a process of fuel oil hydrodesulfurization and hydrodenitrogenation, wherein a cobalt-Molybdenum catalyst is prepared on a carrier of titanium-zirconium-vanadium mixed oxides, and the reaction is carried out in a fixed-bed reactor under reaction conditions. The present invention discloses the operating conditions of desulfurization and denitrogenation reactions, and the optimal compositions of said catalysts as well as its preparation method.Type: GrantFiled: February 22, 1990Date of Patent: July 16, 1991Assignee: Chinese Petroleum Corp.Inventors: Ikai Wang, Jung-Chung Wu
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Patent number: 4673454Abstract: An improved bipolar membrane, a precursor for said membrane and a process for preparing bipolar membranes and precursors are described. In the process a precursor is formed by laminating at least two polymeric layers at least one of which is non-ionic. After the formation of the precursor, the non-ionic layer or layers are chemically treated to form a stable bipolar membrane having high permselectivity and low potential drop. The novel bipolar membrane contains an interfacial layer having anionic and cationic domains.Type: GrantFiled: September 9, 1985Date of Patent: June 16, 1987Assignee: Chinese Petroleum Corp.Inventors: Kang-Jen Liu, Ho-Lun Lee
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Patent number: 4584246Abstract: An improved bipolar membrane, a precursor for said membrane and a process for preparing bipolar membranes and precursors are described. In the process a precursor is formed by laminating at least two polymeric layers at least one of which is non-ionic. After the formation of the precursor, the non-ionic layer or layers are chemically treated to form a stable bipolar membrane having high permselectivity and low potential drop. The novel bipolar membrane contains an interfacial layer having anionic and cationic domains.Type: GrantFiled: November 23, 1983Date of Patent: April 22, 1986Assignee: Chinese Petroleum Corp.Inventors: Kang-Jen Liu, Ho-Lun Lee