Patents Assigned to Chlorine Engineers
  • Patent number: 11608561
    Abstract: An electrolysis device for the electrolytic treatment of liquids has an anode chamber and a cathode chamber which are separated from one another via an ion exchange membrane. The chambers are provided with an inlet opening and an outlet opening for the flowing electrolyte, each with one electrode. The inner space of the anode chamber and/or of the cathode chamber are/is subdivided by webs or ribs extending transversely with respect to the electrodes. The webs or ribs are provided at least regionally with holes or cut outs. The webs or ribs include at least one lower region free of holes or cut outs. The electrolysis device provides sufficient mixing in the upper foam phase in the longitudinal direction and also at the same time the airlift pump effect is maintained by way of ascending gas bubbles in the lower region.
    Type: Grant
    Filed: September 27, 2018
    Date of Patent: March 21, 2023
    Assignee: THYSSENKRUPP UHDE CHLORINE ENGINEERS GMBH
    Inventors: Dmitri Donst, Philipp Hofmann, Dirk Hoormann, Gregor Damian Polcyn, Peter Woltering, Alessandro Fiorucci, Fulvio Federico, Michele Perego
  • Publication number: 20220341049
    Abstract: To provide an electrolysis electrode having a more preferable shape in electrolyzing pure water, an alkali aqueous solution, or an aqueous solution of an alkali metal chloride at a lower voltage than ever before, and an electrolyzer using the same. An electrolysis electrode or the like including: a metal perforated plate having a value of Factor V of 40 or more represented by the formula: Factor V=Rs×Rc×F/100000, in which Rs is a planar direction surface area per unit area 1 dm2 [cm2/dm2], Rc is a thickness direction surface area per unit area 1 dm2 [cm2/dm2], and F is the number of mesh apertures per unit area 1 dm2 (fine degree) [number/dm2].
    Type: Application
    Filed: June 12, 2020
    Publication date: October 27, 2022
    Applicant: THYSSENKRUPP UHDE CHLORINE ENGINEERS GMBH
    Inventors: Terumi HASHIMOTO, Koji KAWANISHI, Takehiro OIWA
  • Patent number: 11479870
    Abstract: An electrolysis cell includes an anode chamber and a cathode chamber separated by an ion-exchange membrane. The electrolysis cell includes an anode, a gas diffusion electrode, and a cathode current distributor. The anode, the ion-exchange membrane, the gas diffusion electrode, and the cathode current distributor are in direct touching contact in the mentioned order. Flexibly resilient holding elements are arranged on the other side of the anode and/or on the other side of the cathode current distributor. The flexibly resilient holding elements exert a contact pressure on the anode and/or on the cathode current distributor. The flexibly resilient holding elements have annular elements, the axis of which is oriented in the height direction of the electrolysis cell. By means of the flexibly resilient and in part also plastically deforming annular elements, effective mechanical contact pressure of the ion-exchange membrane against the oxygen-depolarized cathode is achieved.
    Type: Grant
    Filed: June 12, 2019
    Date of Patent: October 25, 2022
    Assignee: THYSSENKRUPP UHDE CHLORINE ENGINEERS GMBH
    Inventor: Sebastian Austenfeld
  • Patent number: 11473203
    Abstract: Methods for providing at least one product stream, in particular hydrogen, by electrolysis by means of an electrolyzer having a multiplicity of electrolysis cells combined to form at least one framework; wherein electrolyte is discharged from the cells and separated into two phases. The electrolyte is collected upstream of a pump system. At least the functions of discharge and collection are carried out integrally together in a multifunctional collection container or in an integral method step, in particular by means of at least one multifunctional collection container with a regulatable filling level coupled to the cells. This extends the functionality and also provides an advantageous design construction. The invention furthermore relates to a corresponding electrolysis device and to a corresponding multifunctional collection container.
    Type: Grant
    Filed: May 28, 2019
    Date of Patent: October 18, 2022
    Assignee: THYSSENKRUPP UHDE CHLORINE ENGINEERS GMBH
    Inventors: Stefan Klink, Gregor Damian Polcyn, Florian Baumgard, Jörg Pausch, Klaus Dahlhues, Dominik Bergs
  • Publication number: 20220290319
    Abstract: Processes for alkaline electrolysis of water may involve pumping an electrolyte in a circuit between an anode half-cell and a cathode half-cell so as to keep the electrolyte concentration constant throughout the electrolysis process. One such process may involve supplying electrolyte from a first liquid reservoir to the anode half-cell and supplying an anolyte flowing out of the anode half-cell to an anodic gas separator, where gas is separated from the anolyte. The electrolyte may be supplied from a second liquid reservoir to the cathode half-cell and a catholyte flowing out of the cathode half-cell may be supplied to a cathodic gas separator, where gas is separated from the catholyte. Gas-stripped anolyte from the anodic gas separator may be returned to the second liquid reservoir and gas-stripped catholyte from the cathodic gas separator may be returned to the first liquid reservoir.
    Type: Application
    Filed: August 19, 2020
    Publication date: September 15, 2022
    Applicant: THYSSENKRUPP UHDE CHLORINE ENGINEERS GMBH
    Inventors: Jens Wilhelm KUHLMANN, Dirk HOORMANN, Joerg KOLBE, Lukas LUEKE, Gregor Damian POLCYN
  • Patent number: 11267728
    Abstract: Provided is an alkaline water electrolyzer in which leakage of aqueous alkali solutions is prevented. The alkaline water electrolyzer 10 includes an anode chamber frame 11 defining an anode chamber 12; a cathode chamber frame 17 defining a cathode chamber 18; a porous diaphragm 16 disposed between the anode and cathode chamber frames 11 and 17 and partitioning the anode and cathode chambers 12 and 18; an anode gasket 15 disposed on the anode chamber frame 11; and a cathode gasket 21 disposed on the cathode chamber frame 17, wherein when the anode and cathode chamber frames 11 and 17 are fastened, the porous diaphragm 16 is held between the anode and cathode chamber frames 11 and 17 via the anode and cathode gaskets 15 and 21 and the anode and cathode gaskets 15 and 21 are in contact with each other around the peripheral edge of the porous diaphragm 16 by compressing the anode and cathode gaskets 15 and 21.
    Type: Grant
    Filed: March 28, 2018
    Date of Patent: March 8, 2022
    Assignees: THYSSENKRUPP UHDE CHLORINE ENGINEERS (JAPAN) LTD., KAWASAKI JUKOGYO KABUSHIKI KAISHA
    Inventors: Takehiro Oiwa, Koji Kawanishi, Kenichiro Igashira, Yuji Kamei, Nanase Ishikawa, Akiyoshi Manabe
  • Patent number: 11136677
    Abstract: Method for the gastight and liquid-tight installation of oxygen consuming electrodes in an electrolysis apparatus, and electrolysis apparatus for use in chloralkali electrolysis, in which particular regions are covered with an additional film having a composition comparable to the oxygen-consuming electrodes.
    Type: Grant
    Filed: December 13, 2016
    Date of Patent: October 5, 2021
    Assignees: Covestro Deutschland AG, Thyssenkrupp Uhde Chlorine Engineers (Italia) S.R.L.
    Inventors: Andreas Bulan, Michael Großholz, Randolf Kiefer, Peter Woltering
  • Publication number: 20210222306
    Abstract: An electrolysis cell includes an anode chamber and a cathode chamber separated by an ion-exchange membrane. The electrolysis cell includes an anode, a gas diffusion electrode, and a cathode current distributor. The anode, the ion-exchange membrane, the gas diffusion electrode, and the cathode current distributor are in direct touching contact in the mentioned order. Flexibly resilient holding elements are arranged on the other side of the anode and/or on the other side of the cathode current distributor. The flexibly resilient holding elements exert a contact pressure on the anode and/or on the cathode current distributor. The flexibly resilient holding elements have annular elements, the axis of which is oriented in the height direction of the electrolysis cell. By means of the flexibly resilient and in part also plastically deforming annular elements, effective mechanical contact pressure of the ion-exchange membrane against the oxygen-depolarized cathode is achieved.
    Type: Application
    Filed: June 12, 2019
    Publication date: July 22, 2021
    Applicant: ThyssenKrupp Uhde Chlorine Engineers GmbH
    Inventor: Sebastian AUSTENFELD
  • Publication number: 20210156036
    Abstract: Methods for providing at least one product stream, in particular hydrogen, by electrolysis by means of an electrolyzer having a multiplicity of electrolysis cells combined to form at least one framework; wherein electrolyte is discharged from the cells and separated into two phases. The electrolyte is collected upstream of a pump system. At least the functions of discharge and collection are carried out integrally together in a multifunctional collection container or in an integral method step, in particular by means of at least one multifunctional collection container with a regulatable filling level coupled to the cells. This extends the functionality and also provides an advantageous design construction. The invention furthermore relates to a corresponding electrolysis device and to a corresponding multifunctional collection container.
    Type: Application
    Filed: May 28, 2019
    Publication date: May 27, 2021
    Applicant: THYSSENKRUPP UHDE CHLORINE ENGINEERS GMBH
    Inventors: Stefan KLINK, Gregor Damian POLCYN, Florian BAUMGARD, Jörg PAUSCH, Klaus DAHLHUES, Dominik BERGS
  • Patent number: 10988848
    Abstract: An electrolytic cell that prevents, or at least minimizes, damage to a membrane and reduces electrolytic voltage may include an elastic member attached to an electrolytic partition wall within an anode chamber and/or a cathode chamber. The elastic member comprises a spring retaining part and a bonding part that is bonded to the electrolytic partition wall, parallel first support parts extending from the bonding part away from the electrolytic partition wall, a second support part connecting the first support parts, and two parallel spring rows. Each spring row may include first flat spring-like bodies, which originate from the first support part and extend toward the opposite direction of the electrolytic partition wall, and second flat spring-like bodies, which originate from the second support part and extend toward the opposite direction of the electrolytic partition wall.
    Type: Grant
    Filed: June 13, 2017
    Date of Patent: April 27, 2021
    Assignee: THYSSENKRUPP UHDE CHLORINE ENGINEERS GMBH
    Inventors: Koji Kawanishi, Takehiro Oiwa, Shinichiro Yamamoto, Masaki Watanabe
  • Publication number: 20210115574
    Abstract: A sealed coupling between at least two pipes may be mountable on one another in an electrolysis facility. The sealed coupling may be formed on at least one overlapping pipe pair by lateral surfaces abutting one another. The pipes may be mounted/mountable one inside the other in a floating manner relative to one another in an axial direction. A deformation point may be formed at a circumferential position having an axial length on a free end of the outer pipe in the overlap region. The deformation point may define a region for deformation of the outer pipe. A lateral surface of an inner lateral surface of the outer pipe and an outer lateral surface of the inner pipe may define a sealing surface that overlaps the deformation point in the axial direction. In addition to high operational reliability, this also enables a simplification of the installation procedure.
    Type: Application
    Filed: April 27, 2018
    Publication date: April 22, 2021
    Applicant: THYSSENKRUPP UHDE CHLORINE ENGINEERS GMBH
    Inventors: Jörg KOLBE, Dmitri DONST, Sebastian AUSTENFELD, Peter TOROS
  • Patent number: 10914014
    Abstract: A diaphragm includes a porous supporting body and a polymer porous membrane. When one of surfaces of the porous membrane is defined as a surface A, the other surface opposite to the surface A is defined as a surface B, a section of the porous membrane parallel to the surfaces A and B is defined as a section C, an average pore diameter on the surface A is defined as an average pore diameter DA, an average pore diameter on the surface B is defined as an average pore diameter DB, and an average pore diameter on the section C is defined as an average pore diameter DC, the average pore diameters DA and DB are substantially equal to each other, and the average pore diameter DC is larger than each of the average pore diameters DA and DB.
    Type: Grant
    Filed: May 16, 2016
    Date of Patent: February 9, 2021
    Assignees: KAWASAKI JUKOGYO KABUSHIKI KAISHA, DE NORA PERMELEC LTD, THYSSENKRUPPP UHDE CHLORINE ENGINEERS (JAPAN) LTD.
    Inventors: Takafumi Ito, Ikuo Shimomura, Yuji Kamei, Akiyoshi Manabe, Akihiro Kato, Terumi Hashimoto
  • Publication number: 20200283919
    Abstract: An electrolysis device for the electrolytic treatment of liquids has an anode chamber and a cathode chamber which are separated from one another via an ion exchange membrane. The chambers are provided with an inlet opening and an outlet opening for the flowing electrolyte, each with one electrode. The inner space of the anode chamber and/or of the cathode chamber are/is subdivided by webs or ribs extending transversely with respect to the electrodes. The webs or ribs are provided at least regionally with holes or cut outs. The webs or ribs include at least one lower region free of holes or cut outs. The electrolysis device provides sufficient mixing in the upper foam phase in the longitudinal direction and also at the same time the airlift pump effect is maintained by way of ascending gas bubbles in the lower region.
    Type: Application
    Filed: September 27, 2018
    Publication date: September 10, 2020
    Applicant: ThyssenKrupp Uhde Chlorine Engineers GmbH
    Inventors: Dmitri DONST, Philipp HOFMANN, Dirk HOORMANN, Gregor Damian POLCYN, Peter WOLTERING, Alessandro FIORUCCI, Federico FULVIO, Michele PEREGO
  • Publication number: 20200039848
    Abstract: Provided is an alkaline water electrolyzer in which leakage of aqueous alkali solutions is prevented. The alkaline water electrolyzer 10 includes an anode chamber frame 11 defining an anode chamber 12; a cathode chamber frame 17 defining a cathode chamber 18; a porous diaphragm 16 disposed between the anode and cathode chamber frames 11 and 17 and partitioning the anode and cathode chambers 12 and 18; an anode gasket 15 disposed on the anode chamber frame 11; and a cathode gasket 21 disposed on the cathode chamber frame 17, wherein when the anode and cathode chamber frames 11 and 17 are fastened, the porous diaphragm 16 is held between the anode and cathode chamber frames 11 and 17 via the anode and cathode gaskets 15 and 21 and the anode and cathode gaskets 15 and 21 are in contact with each other around the peripheral edge of the porous diaphragm 16 by compressing the anode and cathode gaskets 15 and 21.
    Type: Application
    Filed: March 28, 2018
    Publication date: February 6, 2020
    Applicants: thyssenkrupp Uhde Chlorine Engineers (Japan) Ltd., KAWASAKI JUKOGYO KABUSHIKI KAISHA
    Inventors: Takehiro OIWA, Koji KAWANISHI, Kenichiro IGASHIRA, Yuji KAMEI, Nanase ISHIKAWA, Akiyoshi MANABE
  • Patent number: 10472723
    Abstract: Provided is a method of preventing reverse current flow through an ion exchange membrane electrolyzer, which method is capable of preventing a reverse current from being generated after stopping operation of the ion exchange membrane electrolyzer. A method of preventing reverse current flow through an ion exchange membrane electrolyzer 100, the ion exchange membrane electrolyzer 100 having an anode chamber 107 housing an anode, a cathode chamber 110 housing a cathode, an anode solution-supplying manifold 121 to feed anode solution to the anode chamber 107, and a cathode solution-supplying manifold 124 to feed cathode solution to the cathode chamber 110.
    Type: Grant
    Filed: January 6, 2015
    Date of Patent: November 12, 2019
    Assignee: THYSSENKRUPP UHDE CHLORINE ENGINEERS (JAPAN) LTD.
    Inventors: Kazuyuki Arai, Yoshinari Take, Terumi Hashimoto, Takaaki Matsuo, Toshikazu Hayashida
  • Publication number: 20190226100
    Abstract: An electrolytic cell that prevents, or at least minimizes, damage to a membrane and reduces electrolytic voltage may include an elastic member attached to an electrolytic partition wall within an anode chamber and/or a cathode chamber. The elastic member comprises a spring retaining part and a bonding part that is bonded to the electrolytic partition wall, parallel first support parts extending from the bonding part away from the electrolytic partition wall, a second support part connecting the first support parts, and two parallel spring rows. Each spring row may include first flat spring-like bodies, which originate from the first support part and extend toward the opposite direction of the electrolytic partition wall, and second flat spring-like bodies, which originate from the second support part and extend toward the opposite direction of the electrolytic partition wall.
    Type: Application
    Filed: June 13, 2017
    Publication date: July 25, 2019
    Applicant: THYSSENKRUPP UHDE CHLORINE ENGINEERS GMBH
    Inventors: Koji KAWANISHI, Takehiro OIWA, Shinichiro YAMAMOTO, Masaki Watanabe
  • Patent number: 10344386
    Abstract: Provided are an elastic cushion member and an ion exchange membrane electrolyzer using the same, which elastic cushion member can be installed even in an ion exchange membrane electrolyzer having such a small gap between an electrode and an electrode current collecting plate that a conventional elastic cushion member cannot be arranged therein. An elastic cushion member (10) has a pair of corrosion-resistant metal thin plates (11) arranged at a distance in parallel fashion and a fixing member (12) which fixes the pair of corrosion-resistant metal thin plates (11) and comprises a metal elastic body (13) wound between the pair of corrosion-resistant metal thin plates (11). The fixing member (12) is attached to the pair of corrosion-resistant metal thin plates (11) in a manner that enables detachment of the fixing member therefrom. The metal elastic body (13) is preferred to be a metal coil body.
    Type: Grant
    Filed: May 30, 2013
    Date of Patent: July 9, 2019
    Assignee: thyssenkrupp Uhde Chlorine Engineers (Japan) Ltd.
    Inventors: Yoshiyuki Kodama, Koji Kawanishi
  • Publication number: 20180171494
    Abstract: A diaphragm includes a porous supporting body and a polymer porous membrane. When one of surfaces of the porous membrane is defined as a surface A, the other surface opposite to the surface A is defined as a surface B, a section of the porous membrane parallel to the surfaces A and B is defined as a section C, an average pore diameter on the surface A is defined as an average pore diameter DA, an average pore diameter on the surface B is defined as an average pore diameter DB, and an average pore diameter on the section C is defined as an average pore diameter DC, the average pore diameters DA and DB are substantially equal to each other, and the average pore diameter DC is larger than each of the average pore diameters DA and DB.
    Type: Application
    Filed: May 16, 2016
    Publication date: June 21, 2018
    Applicants: KAWASAKI JUKOGYO KABUSHIKI KAISHA, DE NORA PERMELEC LTD, THYSSENKRUPP UHDE CHLORINE ENGINEERS (JAPAN) LTD.
    Inventors: Takafumi ITO, Ikuo SHIMOMURA, Yuji KAMEI, Akiyoshi MANABE, Akihiro KATO, Terumi HASHIMOTO
  • Patent number: 9903027
    Abstract: The invention provides a process for producing chlorine, alkaline metal hydroxide, and hydrogen which comprises the following steps: (a) preparing a brine by dissolving an alkaline metal chloride source in water; (b) removing alkaline precipitates from the brine prepared in step (a) in the presence of hydrogen peroxide by means of a filter of active carbon, and recovering the resulting brine; (c) subjecting at least part of the resulting brine as obtained in step (b) to an ion-exchange step; (d) subjecting at least part of the brine as obtained in step (c) to a membrane electrolysis step; (e) recovering at least part of the chlorine, alkaline metal hydroxide, hydrogen, and brine as obtained in step (d); (f) subjecting at least part of the brine as recovered in step (e) to a dechlorination step; and (g) recycling at least part of the dechlorinated brine obtained in step (f) to step (a).
    Type: Grant
    Filed: December 14, 2009
    Date of Patent: February 27, 2018
    Assignee: THYSSENKRUPP UHDE CHLORINE ENGINEERS (ITALIA) S.R.
    Inventors: Antonius Jacobus Gerardus Manders, Jacoba Cornelia Petronella Adriana Oonincx, Sami Petteri Pelkonen, Massimo Giosafatte Borghesi
  • Patent number: 9828684
    Abstract: Provided is a cell for ion exchange membrane electrolysis obtained by improving the performance in electrolysis of an existing bipolar cell for ion exchange membrane electrolysis, in which a cathode partition wall and a rigid cathode being connected together by a plurality of intermediating V-shaped springs, by a simple method. It is a cell for ion exchange membrane electrolysis which is separated by an ion exchange membrane (7) into an anode chamber (1) having a rigid anode (1a) and an anode partition wall (1b) and a cathode chamber (2) having a rigid cathode (2a) and a cathode partition wall (2b), the rigid cathode (2a) and the cathode partition wall (2b) being connected together by a plurality of intermediating V-shaped springs (3).
    Type: Grant
    Filed: April 23, 2013
    Date of Patent: November 28, 2017
    Assignee: thyssenkrupp Uhde Chlorine Engineers (Japan) Ltd.
    Inventors: Kiyohito Asaumi, Koichi Hirashima, Zhengkan Huang, Mitsumasa Okamoto, Koji Yoshimura