Patents Assigned to Ciba Speciality Chemicals Corporation
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Patent number: 7687657Abstract: The invention relates to a process for the preparation of (bis)acylphosphanes of formula I, wherein n and m are each independently of the other 1 or 2; R1 if n=1, is e.g. unsubstituted or substituted C1-C18alkyl or C2-C18alkenyl, or phenyl, R1 if n=2, is e.g. a divalent radical of the monovalent radical defined above; R2 is e.g. C1-C18alkyl, C3-C12cycloalkyl, C2-C18alkenyl, mesityl, phenyl, naphthyl; R3 is one of the radicals defined under R1; the process comprises the steps a) contacting e.g.Type: GrantFiled: November 14, 2005Date of Patent: March 30, 2010Assignee: Ciba Speciality Chemicals CorporationInventors: Peter Murer, Jean-Pierre Wolf, Stephan Burkhardt, Hansjörg Grützmacher, Daniel Stein, Kurt Dietliker
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Patent number: 7435473Abstract: The invention refers to a printed substrate comprising a substrate with an oleophilic surface having a Gurley-Hill permeance value bigger than 5000 s/100 ml, the ink printed on the substrate having an IGT ink set-off value bigger than 0.60 print density units at 30 s delay time. The invention also refers to a printing method performed in at least one printing unit under use of following substrate/ink combination: the substrate has an oleophilic surface and is non-porous, i.e. has a Gurley-Hill permenace value bigger than 5000 s/100 ml, the pigment carrier/ink has an IGT ink set-off value larger than 0.60 print density units at 30 s delay time.Type: GrantFiled: December 23, 2004Date of Patent: October 14, 2008Assignees: UPM-KYMMENE OYJ, Ciba Speciality Chemical CorporationInventors: Mika Anttila, Olli Hakkila, Markku Merilahti, Anna-Liisa Tammi, Pertti Ahonen
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Patent number: 6616711Abstract: This invention relates to a process for printing hydrophobic fiber materials with disperse dyes, which comprises 1) dyeing or printing the fiber materials overall with a disperse dye, and 2) printing the fiber materials in areas with a printing paste, which comprises as component (A), at least one cationic assistant, as component (B), at least one polyethylene glycol, as component (C), at least one nonionogenic detergent and, optionally, as component (D), at least one disperse dye, it being possible for steps 1) and 2) to be carried out in any sequence and for step 2) to be carried out repeatedly without using any dye, or using different dyes, and, if necessary, drying the fiber material thus treated and then fixing the dye on the fiber material by heat treatment. The novel process affords multicolored prints having sharp contours and very good fastness to hot light.Type: GrantFiled: December 15, 2000Date of Patent: September 9, 2003Assignee: Ciba Speciality Chemicals CorporationInventors: Alex Känzig, Claudius Brinkmann
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Patent number: 6537332Abstract: Dyes of formula (1) wherein R1 and R2 are each independently of the other hydrogen or C1-C4alkyl, and D1 and D2 are each independently of the other a radical of formula (2) wherein (R3)0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy, nitro and sulfo, and X1 is a radical of formula (3a), (3b), (3c), (3d), (3e) or (3f) —SO2—Z (3a), —NH—CO—(CH2)m—SO2—Z (3b), —CONH—(CH2)n—SO2—Z (3c), —NH—CO—CH(Hal)-CH2-Hal (3d), —NH—CO—C(Hal)=CH2 (3e) or wherein Y is halogen, T independently thereof has a meaning given for Y or is a non-fiber-reactive substituent or is a fiber-reactive radical of formula (4a), (4b), (4c), (4d) or (4e) —NH—(CH2)2-3—SO2—Z (4a), —NH—(CH2)Type: GrantFiled: January 24, 2001Date of Patent: March 25, 2003Assignee: Ciba Speciality Chemicals CorporationInventors: Athanassios Tzikas, Herbert Klier
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Patent number: 6528556Abstract: A process for biocidally finishing plastic materials selected from the group consisting of polyolefin, polystyrene, a halogen-containing polymer, polyacrylate or polymethacrylate, a polymer derived from unsaturated alcohols and amines or from their acyl derivatives or acetals, a homo- or copolymer of cyclic ethers, polyacetal, polyphenylene oxide or polyphenylene sulfide, polyurethane, polyamide or copolyamide, saturated or unsaturated polyester, polycarbonate, a phenol-formaldehyde resin, an epoxy resin or an aminoplastic resin, which process comprises adding a) either during the processing of the plastic materials or, b) in the case of plastic materials prepared via a radical polymerisation, already during the polymerisation or during the processing or, c) in the case of duroplasts prepared from a phenol-formaldehyde resin, epoxy resin or an aminoplastic resin, during the crosslinking reaction, at least one compound selected from the group consisting of 2-methylthio-4-cyclopropylamino-6-(&agr;,&bgr;-dimeType: GrantFiled: May 18, 2000Date of Patent: March 4, 2003Assignee: Ciba Speciality Chemicals CorporationInventors: Heinz Herbst, Nadi Ergenc, Wolfgang Voigt
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Patent number: 6420562Abstract: Hindered amines substituted on the N-atom with an —O—E—OH moiety are particularly effective in stabilizing polyolefin and automotive coating compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not attainable by the use of normal —O—E moieties.Type: GrantFiled: February 21, 2001Date of Patent: July 16, 2002Assignee: Ciba Speciality Chemicals CorporationInventors: James P. Galbo, Gerald A. Capocci, Nancy N. Cliff, Robert E. Detlefsen, Michael P. DiFazio, Ramanathan Ravichandran, Peter Solera
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Patent number: 6063182Abstract: A stir-in pigment composition for coloring high-molecular-weight material, particularly coatings and ink systems, comprises 85 to 99.5 parts by weight of a pigment and 0.5 to 15 parts by weight of an additive comprising a vinylpyrrolidone polymer or copolymer. The stir-in pigment composition is in the form of microgranules and is obtainable by spray drying a high solids content aqueous pigment dispersion containing the pigment and the additive. The new pigment composition powders are easily handled, easily wetted and disperse rapidly to form homogeneous aqueous pigment dispersions which are practically free of larger pigment aggregates and can readily be incorporated into aqueous ink and paint systems as stir-in pigments without a dispersion step in a bead mill.Type: GrantFiled: December 16, 1998Date of Patent: May 16, 2000Assignee: Ciba Speciality Chemicals CorporationInventor: Fridolin Babler
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Patent number: 5989298Abstract: Dye mixtures, which comprise at least one reactive dye of formulae (1) and (2) wherein B, D.sub.1, D.sub.2, (R.sub.1).sub.0-2, R.sub.3, R.sub.4, (R.sub.5).sub.0-2, (R.sub.6).sub.0-2, (R.sub.7).sub.0-2, p, q, V, X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5, X.sub.6, X.sub.7, Y.sub.1 and Y.sub.3 have the meanings defined in claim 1, give dyeings of good fastness properties on nitrogen-containing or hydroxyl group-containing fiber materials.Type: GrantFiled: September 18, 1998Date of Patent: November 23, 1999Assignee: Ciba Speciality Chemicals CorporationInventor: Urs Lehmann
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Patent number: 5925696Abstract: A stabilizer combination, mainly for PVC, is described, comprisingA) at least one compound of formula I ##STR1## wherein R*.sub.1 and R*.sub.2 are each independently of the other C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.6 lkenyl, C.sub.5 -C.sub.8 cycloalkyl that is unsubstituted or substituted by from 1 to 3 C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.5 -C.sub.8 cycloalkyl or by hydroxy groups or by chlorine atoms, or C.sub.7 -C.sub.9 phenylalkyl that is unsubstituted or substituted at the phenyl ring by from 1 to 3 C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.5 -C.sub.8 cycloalkyl or by hydroxy groups or chlorine atoms,and R*.sub.1 and R*.sub.2 may additionally be hydrogen and C.sub.1 -C.sub.Type: GrantFiled: October 10, 1996Date of Patent: July 20, 1999Assignee: Ciba Speciality Chemicals CorporationInventors: Wolfgang Wehner, Hans-Helmut Friedrich, Kornelia Malzacher, Hans-Ludwig Mehner, Rolf Drewes
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Patent number: 5859102Abstract: Plastic mixtures, in particular recycled plastic mixtures, comprising predominantly polyolefins and 0.05-20% by weight of PVDC can be stabilized against thermo-oxidative degradation by addition of a combination of an organic phosphite or phosphonite and a metal salt of a fatty acid.Type: GrantFiled: June 20, 1996Date of Patent: January 12, 1999Assignee: Ciba Speciality Chemicals CorporationInventors: Rudolf Pfaendner, Heinz Herbst, Kurt Hoffmann
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Patent number: 5811543Abstract: Compounds of the formulaA(B).sub.x (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the phthalocyanine series, which radical contains x B groups attached to N-atoms, preferably with at least one directly adjacent to or conjugated with a carbonyl group,B is a group of the formula ##STR1## and, if x is 2,3 or 4, may also be one, two or three hydrogen atoms, wherein the symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, Y, Z, m and n, are as defined in the disclosureThese carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.Type: GrantFiled: July 9, 1996Date of Patent: September 22, 1998Assignee: Ciba Speciality Chemicals CorporationInventors: Zhimin Hao, John S. Zambounis, Abul Iqbal
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Patent number: 5714442Abstract: A description is given of compounds of the formula I, and mixtures thereof, ##STR1## (I), in which Y and Z independently of one another are a radical of the formula ##STR2## (III) R and R.sub.1 independently of one another are hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.4 alkyl-substituted C.sub.5 -C.sub.8 cycloalkyl, phenyl or C.sub.1 -C.sub.4 alkyl-substituted phenyl,R.sub.2 is C.sub.2 -C.sub.20 alkylene, C.sub.5 -C.sub.8 cycloalkylene, a radical of the formula ##STR3## The compounds/mixtures are particularly suitable as metal deactivators for use in lubricants.Type: GrantFiled: April 8, 1996Date of Patent: February 3, 1998Assignee: Ciba Speciality Chemicals CorporationInventor: Jean-Pierre Wolf