Abstract: The present invention relates to a method for producing a supported catalyst, a catalyst which is obtainable using the method, and use thereof for the partial oxidation or ammoxidation of olefins, in particular for the oxidation of propene to acrolein, of isobutene to methacrolein, and/or the ammoxidation of propene to acrylonitrile. The method according to the invention includes the following steps: a) providing a solution in which precursor compounds of the catalytically active component are essentially completely dissolved in a suitable solvent; b) bringing the solution obtained in step a) into contact with a (chemically) inert, porous support having a specific surface of 1 to 500 m2/g; c) heat treatment of the material obtained in step b), in which the precursor compounds of the catalytically active component are converted to their oxides.
Type:
Grant
Filed:
April 11, 2014
Date of Patent:
November 27, 2018
Assignee:
Clariant Corpoation
Inventors:
Valery Sokolovskii, David Michael Lowe, Deepti Machiraju, Hongyi C. Hou, Gerhard Mestl, Claus G. Lugmair, Aaron B. Miller, Anthony F. Volpe, Jr.
Abstract: The present invention relates to solid phosphoric acid (SPA) catalysts, processes for making the catalysts, and processes for conversion of hydrocarbons using the catalysts, such as oligomerization of propylene. In an exemplary embodiment, the catalyst comprises a calcined extrudate of phosphoric acid, diatomaceous earth, and niobic acid. Methods for converting hydrocarbons to olefins comprise contacting a hydrocarbon feedstock with the catalyst at hydrocarbon conversion conditions.