Abstract: The present invention relates to a process for producing a composite material and also the composite material itself. The composite material contains a bismuth-molybdenum-nickel mixed oxide or a bismuth-molybdenum-cobalt mixed oxide and a specific SiO2 as pore former. The present invention also relates to the use of the composite material according to the invention for producing a washcoat suspension and also a process for producing a coated catalyst using the composite material according to the invention. Furthermore, the present invention also relates to a coated catalyst which has a catalytically active shell comprising the composite material according to the invention on a support body. The coated catalyst according to the invention is used for preparing [alpha],[beta]-unsaturated aldehydes from olefins.
Type:
Application
Filed:
April 24, 2018
Publication date:
January 24, 2019
Applicant:
Clariant International Ltd.
Inventors:
Inga WALZEL, Gerhard MESTL, Silvia NEUMANN, Magdalena PRITZL, Gabriele DONABAUER, Robert K. GRASSELLI
Abstract: N-methyl-N-acylglucamines are suitable as thickening agents in aqueous surfactant solutions containing one or more anionic surfactants of the group including alkyl ether sulfates and alkyl sulfates, the N-methyl-N-acylglucamines containing at least 60 wt.-% of N-methyl-N-acylglucamines that have a C12-, C14-acyl group or an unsaturated C18-acyl group and at the same time less than 5 wt.-% of N-methyl-N-acylglucamines that contain an acyl group <C12. The surfactant solutions are particularly used in cosmetic compositions.
Abstract: The invention relates to a polymer composition that can be obtained by means of the free radical polymerisation of A) 95-40 wt. % of alkyl (meth)acrylate containing Ai) 20-95 wt. % of at least one alkyl (meth)acrylate with 16 to 40 C-atoms in the alcohol group, and Aii) 5-80 wt. % of at least one (meth)acrylic acid ester of a C8-C22 alcohol carrying a C6-C20 alkyl group in the 2-position relative to the hydroxyl group, in the presence of B) 5-60 wt. % ethylene copolymer. The invention also relates to a method for producing same and to the use of same as a flow improver for mineral oils and mineral oil distillates.
Type:
Application
Filed:
December 1, 2016
Publication date:
January 3, 2019
Applicant:
Clariant International Ltd.
Inventors:
Michael FEUSTEL, Matthias KRULL, Bettina SIGGELKOW, Michael MÖRSCHER, Ingo GREGER, Sebastian HAFERKAMP
Abstract: The invention relates inter alia to cosmetic compositions comprising an oligoester ammonium salt (OAS) and a cosmetically component (F), where the OAS is obtained by: (i) heating a mixture of the following components (a) to (d) under continuously removing of reaction water: (a) a certain a diethanolamine compound; (b) a certain dicarboxylic acid; (c) a certain organic triol; and a monocarboxylic acid of formula R1—COOH (d), wherein R1 is linear or branched C12-C24-alkyl; (ii) reacting the oligoester of step (i) with a quarternization agent.
Type:
Application
Filed:
December 7, 2016
Publication date:
December 27, 2018
Applicant:
Clariant International Ltd.
Inventors:
Katarzyna KITA-TOKARCZYK, Hannah BENSON, Dirk LEINWEBER, Henrike NEUHOFF, Steffen ROMANSKI, Nadine ZOUMPOULAKIS
Abstract: The invention relates inter alia to cosmetic compositions comprising an oligoester ammonium salt (OAS) and a cosmetically component (F), where the OAS is obtained by: (i) heating a mixture of the following components (a) to (d) under continuously removing of reaction water: (a) a certain diethanolamine compound; (b) a certain dicarboxylic acid; (c) a certain organic triol; and a monocarboxylic acid of formula R1—COOH (d), wherein R1 is linear or branched C12-C24-alkyl; (ii) reacting the oligoester of step (i) with a quarternization agent.
Type:
Application
Filed:
December 7, 2016
Publication date:
December 20, 2018
Applicant:
Clariant International Ltd.
Inventors:
Katarzyna KITA-TOKARCZYK, Hannah BENSON, Dirk LEINWEBER, Tobias PLATEN, Anton KRATZ
Abstract: The invention relates to a catalyst arrangement for preparing phthalic anhydride by gas-phase oxidation of aromatic hydrocarbons, which comprises a reactor having a gas inlet end for a feed gas and a gas outlet end for a product gas and also a first catalyst zone made up of catalyst bodies and at least one second catalyst zone made up of catalyst bodies, where the first catalyst zone is arranged at the gas inlet end and the second catalyst zone is arranged downstream of the first catalyst zone in the gas flow direction and the length of the first catalyst zone in the gas flow direction is less than the length of the second catalyst zone in the gas flow direction, characterized in that the first catalyst zone has a higher gap content compared to the second catalyst zone.
Type:
Grant
Filed:
April 23, 2015
Date of Patent:
December 18, 2018
Assignee:
Clariant International Ltd.
Inventors:
Oliver Richter, Gerhard Mestl, David Lesser, Robert Marx, Nadine Fromm, Felix Schulz, Peter Schinke, Werner Pitschi
Abstract: A shampoo composition comprising at least one oligoester ammonium salt The present invention relates inter alia to shampoo compositions comprising an oligoester ammonium salt (OAS) and a cosmetically component (F), where the OAS is obtained by: (i) heating a mixture of the following components (a) to (d) under continuously removing of reaction water: (a) a certain a diethanolamine compound; (b) a certain dicarboxylic acid; (c) a certain organic triol; and a monocarboxylic acid of formula R1—COON (d), wherein R1 is linear or branched C12-C24-alkyl; (ii) reacting the oligoester of step (i) with a quarternization agent.
Abstract: The invention relates to: a catalytic composition that is active in the selective catalytic reduction of nitric oxides, containing an iron-containing MFI-type zeolite and an iron-containing BEA-type zeolite, wherein the weight average particle size d50 of the MFI-type zeolite and the BEA-type zeolite is different; a method for producing an SCR catalyst; and the SCR catalyst produced in this way. The adhesion of the coating is improved in that the weight average particle sizes of the MFI-type and BEA-type zeolites are different.
Type:
Grant
Filed:
February 24, 2016
Date of Patent:
December 11, 2018
Assignee:
Clariant International Ltd.
Inventors:
Markus Reichinger, Gerd Maletz, Andreas Bentele, Martin Schneider, Klaus Wanninger, Kristof Eisert
Abstract: The invention relates to metal dispersions comprising 50 to 80 wt % of silver nanoparticles, 15 to 45 wt % of water and a dispersant, wherein the dispersant comprises copolymers comprising 1-99 wt % of structural units of formula (1), where R is hydrogen or C1-C6 alkyl, A is C2-C4 alkylene group and B is C2-C4 alkylene group with the proviso that A and B are different and m, n are each independently an integer of 1-200, and 1-99 wt % of structural units of formula (2), where Xa is an aromatic or aliphatic radical having 1 to 30 carbon atoms which optionally comprises one or more, for example 1, 2, or 3, heteroatoms N, O and S, Za is H or (C1-C4)-alkyl, Zb is H or (C1-C4)-alkyl and Zc is H or (C1-C4)-alkyl.
Abstract: The invention relates to the use of one or more alkoxylated vegetable oil derivatives for reducing the drift during the application of plant treatment agents, wherein these alkoxylated vegetable oil derivatives contain structural units resulting from a) vegetable oil, and b) alkylene oxide, wherein alkylene oxide represents ethylene oxide, propylene oxide, butylene oxide or mixtures of ethylene oxide and propylene oxide or mixtures of ethylene oxide and butylene oxide, and c) one or more monocarboxylic acids according to formula (I): R1-COOH, in which R1 represents unbranched or branched, saturated alkyl with 1 to 29 carbon atoms or unbranched or branched, mono- or polyunsaturated alkenyl with 2 to 29 carbon atoms.
Type:
Application
Filed:
December 3, 2015
Publication date:
November 22, 2018
Applicant:
Clariant International Ltd.
Inventors:
Peter BAUR, Martin BAUER, Stephanie GIESSLER, Siegfried STAIGER
Abstract: The invention relates to a composition comprising a) at least one N-methyl-N-acylglucamine of formula (I), wherein R1 represents a linear or branched, saturated or unsaturated hydrocarbon chain with 7 to 21 carbon atoms, one or more organic acids of formula (II) and/or the salts thereof, R2—COOM, wherein R2 represents a linear or branched alkyl group or a linear or branched mono- or poly-unsaturated alkenyl group with 5 to 29 carbon atoms, and M represents hydrogen or one or more cations, wherein the cations are present in charge-equalizing amounts, and c) one or more alkanolamines of formula (III), wherein NR1R2R3R1, R2 and R3 represent hydrogen, a linear or branched alkyl group with 1 to 4 carbon atoms, a cycloalkyl group with 5 to 7 carbon atoms, a linear or branched hydroxyalkyl group with 2 to 5 carbon atoms and 1 or 2 hydroxy groups or a hydroxyether group with 2 to 6 carbon atoms, with the provision that at least one of the groups is a hydroxyalkyl group or a hydroxyether group.
Type:
Grant
Filed:
February 26, 2015
Date of Patent:
November 20, 2018
Assignee:
Clariant International Ltd.
Inventors:
Peter Klug, Rainer Kupfer, Steffen Fleischer
Abstract: The invention relates to a continuous method for producing a tenside, containing a compound of the formula (1), wherein R2 is a fatty acid alkyl residue and R1 is a linear or branched C1 to C12 hydrocarbon residue, and x is in the range from 1 to 15 by conversion of fatty acid alkyl esters or fatty acid triglycerides having an N-n-alkylized polyhydroxy compound in the presence of an alkali catalyst or a catalyst selected from hydroxides or alcoholates of the 2nd and 4th secondary group of the periodic system at a temperature in the range from 40 to 300° C.
Type:
Grant
Filed:
November 9, 2015
Date of Patent:
October 30, 2018
Assignee:
CLARIANT INTERNATIONAL LTD.
Inventors:
Jörg Appel, Dennis Heitmann, Sarah Werner
Abstract: The present invention is directed to a novel and advantageous process for the purification of biomass hydrolysate as well as the purified hydrolysate produced after the inventive process and the use of the purified hydrolysate as a fermentation medium.
Type:
Application
Filed:
August 19, 2016
Publication date:
October 25, 2018
Applicant:
Clariant International Ltd.
Inventors:
Michael ZAVREL, Danielle DENNEWALD, Philip HOFFMANN
Abstract: The invention relates to a printing ink system containing glycosidic polymers and polyolefin- and/or Fischer-Tropsch-waxes and/or amide waxes and/or bio-based waxes and optionally pigments, binders and/or solvents. The glycosidic polymer has a specific surface area according to BET from a minimum 0.45 m2/g and a particle size distribution having an uniformity coefficient (D60/D10) to a maximum of 3.5.
Abstract: The invention relates to mixtures of at least one dialkylphosphinic acid of the formula (I) in which R1, R2 are the same or different and are each independently C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl, C7-C18-alkylaryl, with at least one alkylphosphonic acid of the formula (II) in which R3 is C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl or C7-C18-alkylaryl; to a process for preparation thereof and to the use thereof.
Type:
Grant
Filed:
December 8, 2012
Date of Patent:
October 23, 2018
Assignee:
Clariant International Ltd.
Inventors:
Fabian Schneider, Frank Osterod, Harald Bauer, Martin Sicken
Abstract: The instant invention relates to a composition in form of a stable aqueous emulsion comprising a) 1-50 wt.-% of at least one water insoluble thionocarbamate collector selected from the group consisting of dialkyl thionocarbamates, alkyl alkoxycarbonyl thionocarbamates and alkyl allyl thionocarbamates, b) 1-50 wt.-% of one or a mixture of surface active agents of the general formula wherein R1 is a saturated or unsaturated, branched or linear C3 to C30 aliphatic or aromatic hydrocarbon group, R2 and R3 are independently from each other hydrogen or a C1 to C4 alkyl group, R4 is hydrogen or —CH2—COOX where X is hydrogen or sodium salt or potassium salt or ammonium salt, and n and m are independently from each other 0 to 50, c) 0.1-20 wt.-% of a mixture of at least one alcohol and at least one ether and/or ester, e) 1-90 wt.-% of water.
Type:
Grant
Filed:
April 22, 2015
Date of Patent:
October 23, 2018
Assignees:
CLARIANT INTERNATIONAL LTD., CLARIANT S.A, CLARIANT (CHILE) LTDA.
Inventors:
Antonio Pedro De Oliveira Filho, Jesus Pitarch López, Wagner Claudio Da Silva, Gunter Lipowsky, Jacques Collin Bezuidenhout, Jaime Osvaldo Gomez Becerra, Rodrigo Alexis Caris Andrade, Franco Aurelio Constanzo Yanez
Abstract: The invention relates to a process for preparing a shaped Cu—Al catalyst body for the hydrogenation of organic compounds containing a carbonyl function. More particularly, the shaped catalyst body is suitable for the hydrogenation of aldehydes, ketones and of carboxylic acids or esters thereof, specifically of fatty acids or esters thereof, such as fatty acid methyl esters, to the corresponding alcohols such as butanediol. The present invention further relates to Cu—Al catalysts obtainable by the preparation process.
Type:
Application
Filed:
March 7, 2018
Publication date:
October 18, 2018
Applicant:
Clariant International Ltd.
Inventors:
Martin PAULUS, Frank GROSSMANN, Karl-Heinz STADLER
Abstract: The present invention contains methods, of making a cashew nutshell liquid alkoxylate sulfate surfactant by alkoxylation of a natural alkylphenol using propylene oxide (PO) and/or ethylene oxide (EO) followed by a sulfation reaction. The cashew nutshell liquid alkoxylate sulfate surfactant of the present invention is made by a facile and cost effective method. The natural hydrophobe surfactant of the present invention find uses in EOR applications where it is used for solubilization and mobilization of oil optionally containing asphaltene, wax, naphtenate, and for environmental cleanup. Further, the unsulfated version of the natural hydrophobe cardanol alkoxylate surfactant of the present invention can be used as ultra-high molecular weight non-ionic surfactant. Another advantage is that the composition is a renewable based surfactant that is non-toxic and biodegradable.
Type:
Application
Filed:
October 7, 2016
Publication date:
October 11, 2018
Applicant:
Clariant International Ltd.
Inventors:
Dirk LEINWEBER, Anton KAISER, Jonathan WYLDE, Corinna KRUEGER, Hadi SHAMSI JAZEYI
Abstract: The present invention provides a method of demulsifying an emulsion comprising water and oil, the method comprising adding an effective amount of a composition comprising a) an esterquat surfactant of the following formula (1) wherein R1 is a C5-C29 aliphatic hydrocarbon group, R2 is —C2H4OH or —C2H4OCOR1, R3 is —C2H4OH or —C2H4OCOR1 or a C1-C10 aliphatic hydrocarbon group R4 is a C1-C10 aliphatic hydrocarbon group X is an anion, b) water, at least one organic solvent or both to the emulsion.
Type:
Application
Filed:
April 22, 2016
Publication date:
October 11, 2018
Applicant:
Clariant International, Ltd.
Inventors:
Anton KAISER, Jonathan WYLDE, Alan WHITE
Abstract: The invention relates to aqueous binder-free pigment dispersions containing (A) at least one organic and/or inorganic pigment, (B) one or more dispersing agents and/or surfactants, (C) at least one base of formula (I), where R1 is H, C1-C4-alkyl, CH2CH2OH or CH2CH(CH3)OH, (D) optionally, one or more polyalkylene glycols, (E) optionally, other additives commonly used for making aqueous pigment dispersions, and (F) water.
Type:
Application
Filed:
September 15, 2016
Publication date:
October 11, 2018
Applicant:
Clariant International Ltd.
Inventors:
Rainer KUPFER, Christoph SÖFFING, Jörg RÜGER