Patents Assigned to Clearwater International, L.L.C.
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Patent number: 8932996Abstract: Methods relate to using phosphate and/or nitrate brines to reduce hydrate formation in flowlines under conditions conducive for hydrate formation in the absence of the phosphate and/or nitrate brine. The phosphate and/or nitrate brines may include compatible anti-corrosion additives.Type: GrantFiled: January 11, 2012Date of Patent: January 13, 2015Assignee: Clearwater International L.L.C.Inventors: Olusegun Matthew Falana, Michael Morrow, Frank G. Zamora
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Patent number: 8562820Abstract: 1,3,5-(2H2,4H2,6H2)tripropanediamine N,N,N?,N?,N?,N? hexamethyl is used to scavenge sulfur compounds from hydrocarbons. A novel method of making the triazine comprises autocondensing (CH3)2NCH2CH2CH2N?CH2.Type: GrantFiled: May 1, 2007Date of Patent: October 22, 2013Assignee: Clearwater International, L.L.C.Inventor: Larry W. Gatlin
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Patent number: 7713435Abstract: Carboxylate salts of amines are used as components of heat exchange fluids. The amines may have a ratio of N to C of 1:0 to 1:12 and the carboxylate anion may be derived from an acid of the formula H(CH2)0-3COOH. A preferred monoamine heat exchange fluid utilizes triethanolamine formate. Lower carboxylate salts of diamines and triamines having the formula R2[N[(CH2)mNR]1-2]R where each R is independently selected from moieties of the formula —CnH2n+1 and moieties of the formula H[O(CH2)1-4]—, each m is independently a number from 1 to 6, and each n is a number from 1 to 4, are disclosed as compounds.Type: GrantFiled: November 18, 2008Date of Patent: May 11, 2010Assignee: Clearwater International, L.L.C.Inventors: Kevin W. Smith, Larry W. Gatlin, John H. Hallman
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Patent number: 7575057Abstract: Coacervate gels having excellent shear viscosities and other properties are made with anionic or cationic polymers, a smaller amount of a surfactant having a charge opposite that of the polymer, and a hydrophobic alcohol. The Zeta Potential of the gel is maintained at an absolute value of at least 20. Optional gel promoting additives include betaines and amine oxides. A preferred gel comprises poly diallyl dimethyl ammonium chloride, a lesser amount of sodium lauryl sulfonate, and lauryl alcohol. The gels are particularly useful in well drilling fluids and well fracturing fluids.Type: GrantFiled: February 19, 2008Date of Patent: August 18, 2009Assignee: Clearwater International, L.L.C.Inventors: Kevin N. Schwartz, Kevin W. Smith, Shih-Ruey T. Chen
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Patent number: 7576038Abstract: Clay is stabilized in the drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid of potassium formate together with a cationic formation control additive.Type: GrantFiled: July 21, 2005Date of Patent: August 18, 2009Assignee: Clearwater International, L.L.C.Inventor: Kevin W. Smith
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Patent number: 7348297Abstract: Compounds of the formula H(CH2)zCOO—[C2H4O]xCyH2y+1 where z is 0-2, x is an integer from 1 to 5 and y is an integer from 4-9 are used as emulsion breakers and defoamers in formation treatment fluids in the recovery of hydrocarbons from subterranean formations. A preferred material has the formula HCOO—[C2H40]3C6H7.Type: GrantFiled: October 5, 2004Date of Patent: March 25, 2008Assignee: Clearwater International, L.L.C.Inventors: Kevin W. Smith, Joseph Miller, Larry W. Gatlin
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Patent number: 7211665Abstract: 1,3,5-(2H2,4H2,6H2) tripropanediamine N,N,N?,N?,N?,N? hexamethyl is used to scavenge sulfur compounds from hydrocarbons. A novel method of making the triazine comprises autocondensing (CH3)2NCH2CH2CH2N?CH2.Type: GrantFiled: November 8, 2002Date of Patent: May 1, 2007Assignee: Clearwater International, L.L.C.Inventor: Larry W. Gatlin
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Patent number: 7060198Abstract: Carboxylate salts of amines are used as components of heat exchange fluids. The amines may have a ratio of N to C of 1:0 to 1:12 and the carboxylate anion may be derived from an acid of the formula H(CH2)0-3COOH. A preferred monoamine heat exchange fluid utilizes triethanolamine formate. Lower carboxylate salts of diamines and triamines having the formula R2[N[(CH2)mNR]1-2]R where each R is independently selected from moieties of the formula —CnH2n+1 and moieties of the formula H[O(CH2)1-4]—, each m is independently a number from 1 to 6, and each n is a number from 1 to 4, are disclosed as compounds.Type: GrantFiled: May 8, 2002Date of Patent: June 13, 2006Assignee: Clearwater International, L.L.C.Inventors: Kevin W. Smith, Larry W. Gatlin, John H. Hallman
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Patent number: 7028771Abstract: Low concentrations, 1–10% of potassium salt, especially potassium formate, are used in a drilling fluid in oil production. Preferably they are used with guar derivatives, most preferably carboxymethyl hydroxypropyl guar. The concentration of potassium formate is maintained at the desired level by adjusting the potassium formate to maintain a desired Zeta potential in the circulating drilling fluid. The potassium formate/guar derivative composition may be used in the substantial absence of hydrophilic clay additive.Type: GrantFiled: May 30, 2002Date of Patent: April 18, 2006Assignee: Clearwater International, L.L.C.Inventors: Kevin W. Smith, Rusty R. Mackey, John H. Hallman
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Patent number: 6921742Abstract: Clay is stabilized in the drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid fluid of potassium formate together with a cationic formation control additive.Type: GrantFiled: August 19, 2002Date of Patent: July 26, 2005Assignee: Clearwater International, L.L.C.Inventor: Kevin W. Smith
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Patent number: 6893582Abstract: A heat transfer fluid comprising potassium formate is used to good effect in line heaters for heating natural gas in gas transmission lines, and for other uses. The solution is heated in a liquid heat transfer medium in a fluid heating zone and transferred to a gas heating zone.Type: GrantFiled: February 16, 2001Date of Patent: May 17, 2005Assignee: Clearwater International, L.L.C.Inventors: Kevin W. Smith, John H. Hallman, Lori Acor, Joseph Miller
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Patent number: 6689204Abstract: Roadbed material is stabilized by the addition of a small amount of potassium formate, preferably together with a water-soluble polymer which is preferably a cationic polymer.Type: GrantFiled: February 15, 2002Date of Patent: February 10, 2004Assignee: Clearwater International, L.L.C.Inventor: Mark E. Stanley
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Patent number: 6666906Abstract: Potassium or other alkali metal formate solution is used to absorb moisture from gas through a membrane. The membrane may be supported on permeable tubes, and the potassium or other alkali metal formate may be regenerated for reuse, preferably by a cavitation regenerator. The potassium or other alkali metal formate should be present as a 40-80% solution, most preferably 70-76%. The process is especially useful for the dehydration of natural gas.Type: GrantFiled: November 6, 2001Date of Patent: December 23, 2003Assignee: Clearwater International, L.L.C.Inventor: John H. Hallman
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Patent number: 6659123Abstract: Fire hydrants are protected from freezing by including potassium formate, preferably at least 10% by weight, in the water enclosed in them during nonuse.Type: GrantFiled: August 24, 2001Date of Patent: December 9, 2003Assignee: Clearwater International, L.L.C.Inventors: William Hyland, John H. Hallman