Abstract: A process for the solid phase continuous polymerization of polyester in order to achieve a molecular weight increase, measurable by the intrinsic viscosity IV increase of the polyester, wherein the use of at least a reactor (15) is provided, the reactor (15) being cylindrical, rotary around its own central axis (S), substantially horizontal, slightly inclined so as to produce the polymerization of the polyester granules passing through the reactor by gravity thanks to the inclination and the rotation of the reactor (15), inside the reactor there being produced a purge gas flow having the same or the opposite direction with respect to the flow of the polyester granules.
Abstract: Compositions suitable for preparing transparent articles comprising an aromatic polyester resin selected from a copolyalkylene terephthalate containing from 3 to 15% by moles of units derived from isophtalic acid and/or a naphtalene dicarboxylic acid and a polyxylylene amide, preferably poly (m.xylylene adipamide), in which the polymide is dispersed in the polyester resin as domains with average numeral size of 30 to 200 nm. The compositions are obtained by premelt-mixing the polyester with a dianhydride of a tetracarboxylic acid prior mixing the polyxylylene amide using melt viscosity ration between the polyester resin and the polyxylylene amide higher that 1.5:1, preferably from 3:1 to 8:1.
Abstract: A method for purifying polyethyleneterephthalate reins by contacting the resins with an atmosphere containing carbon dioxide under supercritical conditions.
Abstract: A method of treating PET preforms and bottles consists of subjecting the preforms or the bottles to a carbon dioxide atmosphere at a higher temperature than the critical temperature of carbon dioxide, a higher pressure than ambient pressure, and for a set time period. The treatment reduces the acetaldehyde concentration in the head of the treated bottles or in the bottles obtained from the treated preforms by stretch-blowing, and also reduces the permeability of gases through the bottle walls.