Abstract: A collector agent for use in froth flotation processes to recover metal values of sulphide ores is disclosed which agent comprises the reaction product resulting from mixing and reacting in the presence of visible light, heat, or both, a mixture of:(i) a mixture of hydrocarbons having from 5 to 10 (inclusive) carbon atoms,(ii) methyl isobutyl carbinol (MIBC),(iii) ethyl xanthyl ethylformic ester (EEF), and(iv) elemental sulphur (S).