Patents Assigned to Columbia Chemical Corporation
  • Patent number: 6830674
    Abstract: An aqueous alkaline non-cyanide zinc electroplating bath containing zinc ions for producing bright electrodeposits of zinc and a brightening agent comprising a polymeric quaternary amine and a reducing sugar, and a compound that forms a reducing sugar upon hydrolysis.
    Type: Grant
    Filed: November 5, 2002
    Date of Patent: December 14, 2004
    Assignee: Columbia Chemical Corporation
    Inventors: Robert J. Ludwig, William E. Rosenberg
  • Publication number: 20040170848
    Abstract: A corrosion inhibiting composition for coating an article or substrate such as a metal, metal coating, chromated metal coating, and the like comprises a film-forming compound such as a wax or a polymer, and a sulfide salt or thio compound or a derivative of a thio compound.
    Type: Application
    Filed: February 28, 2003
    Publication date: September 2, 2004
    Applicant: COLUMBIA CHEMICAL CORPORATION
    Inventors: Robert J. Ludwig, Shane F. Lofland, William E. Rosenberg,
  • Publication number: 20040084322
    Abstract: An aqueous alkaline non-cyanide zinc electroplating bath containing zinc ions for producing bright electrodeposits of zinc and a brightening agent comprising a polymeric quaternary amine and a reducing sugar, and a compound that forms a reducing sugar upon hydrolysis.
    Type: Application
    Filed: November 5, 2002
    Publication date: May 6, 2004
    Applicant: COLUMBIA CHEMICAL CORPORATION
    Inventors: Robert J. Ludwig, William E. Rosenberg
  • Patent number: 4545870
    Abstract: A tin brightener for an electroplating bath contains various trialkoxybenzaldehydes for producing uniform desposits over a very broad current density range.
    Type: Grant
    Filed: August 27, 1984
    Date of Patent: October 8, 1985
    Assignee: Columbia Chemical Corporation
    Inventor: William E. Rosenberg
  • Patent number: 4530741
    Abstract: A tin brightener composition and plating bath utilizes a disubstituted naphthalene having at least one substituted aldehyde group thereon.
    Type: Grant
    Filed: July 12, 1984
    Date of Patent: July 23, 1985
    Assignee: Columbia Chemical Corporation
    Inventor: William E. Rosenberg
  • Patent number: 4417957
    Abstract: A tin brightener mixture for plating baths comprises chlorinated acetophenones, emulsifying agents, and acrylic or methacrylic acid. Additionally, aromatic aldehydes can be utilized. The tin brightener yields semibright to bright deposits from 0 to over 150 amps per square foot.
    Type: Grant
    Filed: September 3, 1982
    Date of Patent: November 29, 1983
    Assignee: Columbia Chemical Corporation
    Inventor: William E. Rosenberg
  • Patent number: 4251331
    Abstract: A brightening agent is provided for the electrodeposition of zinc from an aqueous acid plating bath. The brightening agent is composed of an alpha-amino aliphatic carboxylic acid, a nonionic surface active compound and a carbonyl compound. The brightening agent may be added to an electroplating bath containing zinc ions, chloride ions, and boric acid. The use of the brightening agent eliminates the use of ammonium chloride as a bath constituent, and unexpectedly produces bright electrodeposits at extremely high current densities.
    Type: Grant
    Filed: January 17, 1980
    Date of Patent: February 17, 1981
    Assignee: Columbia Chemical Corporation
    Inventor: William E. Rosenberg
  • Patent number: 4100040
    Abstract: A zinc brightener additive compises a polymeric amine selected from the class consisting of a linear aliphatic amine polymer, an aminated polyepichlorohydrin, a polyethylenimine, and combinations thereof, a propylene oxide-ethylene oxide block copolymer prepared by the sequential addition of propylenene oxide followed by ethylene oxide, or vice versa, to a residue of an organic compound containing active hydrogen atoms such as propylene glycol or an amine base, and an aliphatic ketone. Additionally, an aqueous acid electroplating bath containing the polymeric amine compound in combination with the propylene oxide-ethylene oxide block copolymer and an aliphatic ketone provides bright, lustous electrodepositions of zinc.
    Type: Grant
    Filed: September 14, 1977
    Date of Patent: July 11, 1978
    Assignee: Columbia Chemical Corporation
    Inventor: William E. Rosenberg
  • Patent number: 4072582
    Abstract: An aqueous acid tin electroplating bath contains as a brightening agent certain dialkoxy benzaldehydes, an emulsifying agent, as well as alpha, beta unsaturated carboxylic acids, amides, and esters to give extremely bright electrodeposits.
    Type: Grant
    Filed: December 27, 1976
    Date of Patent: February 7, 1978
    Assignee: Columbia Chemical Corporation
    Inventor: William E. Rosenberg
  • Patent number: 4061547
    Abstract: An aqueous acid tin electroplating bath contains as a brightening agent compounds having the formula: ##STR1## where O is oxygen and A is selected from the class consisting of hydrogen, hydroxy alkyl, polyalkoxy, and 3-sulfopropyl, certain emulsifying agents and certain synergistically acting carboxylic acids, amides and esters to give extremely bright electrodeposits.
    Type: Grant
    Filed: July 21, 1976
    Date of Patent: December 6, 1977
    Assignee: Columbia Chemical Corporation
    Inventor: William E. Rosenberg
  • Patent number: 4049510
    Abstract: A zinc brightener additive comprises a polymeric amine selected from the class consisting of a linear aliphatic amine polymer, an aminated polyepichlorohydrin, a polyethylenimine, and combinations thereof, and a propylene oxide-ethylene oxide block copolymer prepared by the sequential addition of propylene oxide followed by ethylene oxide, or vice versa, to a residue of an organic compound containing active hydrogen atoms such as propylene glycol or an amine base. Additionally, an aqueous acid electroplating bath containing the polymeric amine compound in combination with the propylene oxide-ethylene oxide and block copolymer provides bright, lustrous electrodepositions of zinc. Moreover, aromatic aldehydes and ketones may be utilized to provide extremely bright electrodepositions of zinc.
    Type: Grant
    Filed: October 26, 1976
    Date of Patent: September 20, 1977
    Assignee: Columbia Chemical Corporation
    Inventor: William E. Rosenberg
  • Patent number: 4007098
    Abstract: It has been found that a linear aliphatic amine polymer obtained from the reaction of a linear aliphatic polyamine and an epihalohydrin results in an acid zinc electroplating bath brightener.Additionally, when dissolved in an aqueous, acid zinc electroplating bath, the linear aliphatic amine polymer reaction product acts synergistically with polyoxyethylene condensates and aromatic aldehydes and ketones to provide extremely bright electrodeposits of zinc.
    Type: Grant
    Filed: September 4, 1975
    Date of Patent: February 8, 1977
    Assignee: Columbia Chemical Corporation
    Inventor: William E. Rosenberg
  • Patent number: 3988219
    Abstract: It has been found that aminated polyepichlorohydrins prepared by reacting polyepichlorohydrin with an amine selected from the group consisting of secondary aliphatic amines and secondary alicyclic amines result in a zinc electroplating bath brightener. Additionally, an aqueous, acid electroplating bath containing the aminated polyepichlorohydrin as well as polyoxyethylene condensates, and aromatic aldehydes and ketones act synergistically to provide bright, lustrous electrodeposits of zinc.
    Type: Grant
    Filed: July 7, 1975
    Date of Patent: October 26, 1976
    Assignee: Columbia Chemical Corporation
    Inventor: William E. Rosenberg
  • Patent number: 3977949
    Abstract: An aqueous acid tin electroplating bath contains as a brightening agent an alkoxy naphthalene carboxaldehyde, certain emulsifying agents and certain synergistically acting carboxylic acids, amides, and esters to give extremely bright electrodeposits.
    Type: Grant
    Filed: July 7, 1975
    Date of Patent: August 31, 1976
    Assignee: Columbia Chemical Corporation
    Inventor: William E. Rosenberg