Abstract: This invention relates to polymers having enhanced hydrophilicity and thermal regulative properties. Exemplary polymers include aliphatic polyamide polymers and polyester polymers. The polymer has bonded thereto a hydrophilic polysiloxane having an affinity for the polymer and having a molecular weight greater than about 1000 g/mol preferably greater than about 2000 g/mol, and preferably greater than about 4000 g/mol. The polymer has substantially no polymerization with the hydrophilic polysiloxane. Alternatively, an aliphatic polyamide polymer is provided having enhanced hydrophilicity and thermal regulative properties. The polymer has bonded thereto an anionic hydrophilic polysiloxane having an affinity for the aliphatic polyamide polymer. The aliphatic polyamide polymer has substantially no polymerization with the anionic hydrophilic siloxane.