Abstract: A process for the recovery of sulfur from a hydrogen sulfide containing gas, comprising oxidizing hydrogen sulfide with oxygen, and then reacting the product gas of this oxidation further by using at least two catalytic stages. The H.sub.2 S concentration in the gas leaving the last catalytic stage is controlled to have a value ranging between 0.8 and 3% by volume by reducing the quantity of combustion or oxidation air passed to the oxidation stage and/or causing a portion of the hydrogen sulfide-containing feedstock gas to bypass the oxidation stage and to be added to the gas flowing to a catalytic stage. The gas leaving the last catalytic stage is introduced into a heat exchanger having a wall temperature below the solidification point of sulfur and above the dew point of water, wherein the sulfur deposits on the heat exchanger wall and is removed with the aid of gravity.
Abstract: The invention relates to a catalyst on support for the selective oxidation of sulfur-containing compounds to elemental sulfur, comprising at least one catalytically active material applied to a support material, this catalyst being obtainable by applying the catalytically active material to a support material which comprises at least one alkali metal promotor.
Type:
Grant
Filed:
June 18, 1996
Date of Patent:
September 29, 1998
Assignees:
Gastec N.V., Comprimo B.V.
Inventors:
Robert Johan Andreas Maria Terorde, John Wilhelm Geus
Abstract: The invention relates to a process for removing elemental sulfur which is present in a gas in the form of vapor and/or entrained particles, in which process the gas to be treated is cooled. The gas to be treated is introduced into a heat exchanger at the lower end thereof and with the aid of the temperature and/or the flow velocity of the cooling medium it is ensured that the wall of the heat exchanger has a temperature below the solidification point of sulfur and above the dew point of water, if any, present in the gas. The deposited sulfur is removed under the influence of gravity countercurrent to the gas to be treated.
Abstract: The invention is directed to a catalyst for the selective oxidation of sulphur-containing compounds to elemental sulphur, comprising at least one catalytically active material and optionally a carrier, the catalyst having a specific surface area of more than 20 m.sup.2 /g and an average pore radius of at least 25 .ANG., while under the reaction conditions the catalyst exhibits no substantial activity towards the Claus reaction.
Abstract: The invention is directed to a catalyst for the selective oxidation of sulphur-containing compounds to elemental sulphur, comprising at least one catalytically active material and optionally a carrier, the catalyst having a specific surface area of more than 20 m.sup.2 /g and an average pore radius of at least 25 .ANG., while under the reaction conditions the catalyst exhibits no substantial activity towards the Claus reaction.
Abstract: The claimed invention relates to a catalytic process for the selective oxidation of sulfur-containing compounds, in particular hydrogen sulfide, to form elemental sulfur. The catalyst includes a carrier of which the surface exposed to the gaseous phase does not exhibit alkaline properties under the reaction conditions, and a catalytically active material applied thereto or formed thereon. The specific surface area of the catalyst is less than 20 m.sup.2 /g catalyst, with less than 10% of the total pore volume having a pore radius between 5 and 500 .ANG.. A process for preparing the catalyst is also disclosed.
Abstract: A process is described for converting carbon oxylsulfide and/or carbon disulfide, possibly in combination with hydrogen cyanide, O.sub.2 and/or SO.sub.2 in a reducing CO containing gas stream by the catalytic hydrolysis of COS and CS.sub.2, followed by the removal of H.sub.2 S, present and formed, from the gas stream. According to the invention, the process is characterized by(a) a first stage comprising converting a portion of the CO present with water in the presence of a catalyst with simultaneous or subsequent hydrogenation of any O.sub.2 and/or SO.sub.2 that may be present;(b) a second stage comprising catalytically hydrolysing COS and/or C.sub.
Abstract: The invention relates to a catalyst for the selective oxidation of sulfur-containing compounds, in particular hydrogen sulfide, to form elemental sulfur, comprising a carrier of which the surface exposed to the gaseous phase does not exhibit alkaline properties under the reaction conditions, and a catalytically active material applied thereto or formed thereon. According to the invention the catalyst is characterized in that the specific surface area of the catalyst is less than 20 m.sup.2 /g catalyst, with less than 10% of the total pore volume having a pore radius between 5 and 500 .ANG.. The invention also relates to a process for preparing the catalyst, and to processes using it.
Abstract: Hydrogen sulphide and ammonia are removed from gaseous streams comprising these compounds by combustion of ammonia into nitrogen and water vapor and partial combustion of hydrogen sulphide into sulphur dioxide, whereby hydrogen sulphide reacts with the sulphur dioxide formed in a molar ratio of 2:1 under formation of elementary sulphur and water, by mixing all gases which are to be combusted before causing them to enter at least one burner. Preferably the combustion air required for the ammonia containing gas stream and the combustion air required for the hydrogen sulphide rich gas stream are controlled separately, after which both air streams are united.