Abstract: A composition useful for crosslinking phosphate esters in hydrocarbon gels used in formation fracturing performs especially well in cold temperatures, such as temperatures lower than (?)20° C. Methods of making the crosslinking composition and the gel are described; also methods of fracturing subterranean formations. Specific forms of ferric sulfate and ferric ammonium citrate are useful as ingredients of the crosslinking composition.
Type:
Grant
Filed:
July 2, 2010
Date of Patent:
August 20, 2013
Assignee:
Conlen Surfactant Technology, Inc.
Inventors:
Larry W. Gatlin, Glen E. Walden, Ernest McMillan, Richard A. Gatlin