Abstract: Suggested is a novel coated particle of active ingredients with controlled release properties at pH-values from 10 to 14, wherein the active ingredient is selected from one or more construction chemical additives for the control of inorganic binders, characterized in that the coating comprises shellac, a process for its manufacture and the use thereof as an additive for mortars, dry mortars, cement slurries and/or concretes.
Type:
Grant
Filed:
November 22, 2012
Date of Patent:
August 16, 2016
Assignee:
Construction Research & Technology GmbH
Inventors:
Wolfgang Seidl, Dawid Marczewski, Sascha Raspl, Steffen Wache, Michael Schinabeck, Stefan Friedrich
Abstract: The invention concerns a process for the preparation of a hardening accelerator composition by reaction of a water-soluble calcium compound with a water-soluble silicate compound, said reaction being carried out in the presence of an aqueous solution which contains a water-soluble comb polymer suitable as a plasticizer for hydraulic binders, wherein the water-soluble comb polymer is present as a copolymer which is produced by free radical polymerization in the presence of a phosphorylated monomer and a (meth)acrylic acid ester based polyether macromonomer.
Type:
Grant
Filed:
August 12, 2013
Date of Patent:
July 12, 2016
Assignee:
Construction Research & Technology GmbH
Inventors:
Luc Nicoleau, Torben Gädt, Harald Grassl
Abstract: Fibers with crystallization seeds attached to its surface, method of making such composite fibers by surface treatment of fibers followed by either treating such fibers with premade crystallization seeds or by precipitation and direct crystallization of seeds onto pretreated fibers. Controlling and tuning the properties of inorganic binder compositions with fiber-bound crystallization seeds and thereby generating inorganic binder compositions with tailor-made characteristics.
Type:
Application
Filed:
August 21, 2014
Publication date:
July 7, 2016
Applicant:
Construction Research & Technology GMBH
Inventors:
Radoslaw KIERAT, Bernhard FEICHTENSCHLAGER, Christoph HESSE, Dunja HIRSEMANN
Abstract: The invention provides a process for preparing a thixotropic agent based on a urea derivative, in which the components ?) comprising at least one amine and ?) comprising at least one isocyanate, are supplied separately to a mixing means and are mixed with one another, the reaction mixture being discharged by spraying or squirting from the mixing means. Further disclosed is the use of the thixotropic agent in a fluid system. The process is especially suitable for preparing adhesives and sealants.
Type:
Grant
Filed:
June 10, 2011
Date of Patent:
June 28, 2016
Assignee:
Construction Research & Technology GmbH
Inventors:
Burkhard Walther, Helmut Mack, Tobias Austermann
Abstract: A freeze-thaw damage resistance and scaling damage resistance admixture for a cementitious composition including an aqueous slurry comprising a water insoluble superabsorbent polymer and expandable polymeric microspheres. A method for preparing a freeze-thaw damage resistant and scaling damage resistant cementitious composition including forming a mixture of a hydraulic cement and an admixture including an aqueous slurry of a water insoluble superabsorbent polymer and expanded polymeric microspheres.
Type:
Grant
Filed:
March 15, 2013
Date of Patent:
June 14, 2016
Assignee:
Construction Research & Technology GmbH
Inventors:
Frank Shaode Ong, James C. Smith, Raymond Fete, Rick Paponetti
Abstract: The invention relates to a monomer-based condensation product, wherein the monomers comprising at least one monomer having an aldehyde moiety and at least one monomer having a ketone moiety, which is carrying at least one non-aromatic moiety and the condensation product comprises at least one moiety from the series of phosphono, sulphino, sulpho, sulphamido, sulphoxy, sulphoalkyloxy, sulphinoalkyloxy and phosphonooxy groups and/or salts thereof, wherein the monomers further comprising gallic acid. Additionally disclosed are the preparation and the use of these condensation products in chemical products for the construction industry.
Abstract: The present invention relates to an additive for hydraulically setting compositions, comprising an aqueous, colloidally disperse preparation of at least one salt of a polyvalent metal cation and of at least one polymeric dispersant which comprises anionic and/or anionogenic groups and polyether side chains. The additive is suitable particularly as a slump retainer.
Type:
Grant
Filed:
July 19, 2013
Date of Patent:
April 19, 2016
Assignee:
Construction Research & Technology GmbH
Inventors:
Torben Gädt, Harald Grassl, Alexander Kraus
Abstract: The present invention suggests 2-oxo-1,3-dioxolane-4-carboxamides of formula (I), in which R2 can be, inter alia, an n-valent radical (n>1) which is substituted with n?1 further 2-oxo-1,3-dioxolane-4-carboxamide groups of general formula (II), to processes for the preparation of these 2-oxo-1,3-dioxolane-4-carboxamides, to processes for the preparation of the 2-oxo-1,3-dioxolane-4-carboxylic acids of formula (III), which are suitable starting materials for the above processes, and to the use of said 2-oxo-1,3-dioxolane-4-carboxamides for the preparation of (poly)hydroxyurethanes, -hydroxycarbonates and -hydroxysulfanylformates, and also as end groups for the blocking of amines.
Type:
Grant
Filed:
November 14, 2012
Date of Patent:
April 12, 2016
Assignee:
Construction Research & Technology GmbH
Inventors:
Heimo Woelfle, Burkhard Walther, Maximilian Köhler, Sophie Putzien
Abstract: A polyurethane prepolymer comprising the reaction product of a reactant formulation comprising a polyol entirely derived from a natural oil; a natural oil-petroleum blend polyol; an isocyanate, at least one catalyst, drying agent, and plasticizer, wherein the prepolymer has a bio-based content of from about 15% to about 75% by weight. The prepolymer may be used in adhesive, or sealant compositions.
Type:
Grant
Filed:
July 18, 2011
Date of Patent:
April 12, 2016
Assignee:
Construction Research & Technology GmbH
Inventors:
Jyothi Thazhakuzhy Varkey, Jayesh Neginbhai-Patel, Robert Louis Ferenz, Patrick Knoll
Abstract: The invention relates to a composition comprising, based on the dry weight of said composition, (A) 10 to 70% by weight of one or more hydraulic binder and (B) 20 to 85% by weight of one or more filler, wherein the composition contains 0.05 to 5% by weight, based on the amount of the hydraulic binder, of at least one terpenoid alcohol, wherein the terpenoid alcohol is not terpineol or borneol. Additionally disclosed is a hardened product made by the composition and the use of at least one terpenoid alcohol in a composition, comprising hydraulic binder and filler, to reduce the shrinkage of the wet composition during curing.
Type:
Grant
Filed:
September 23, 2013
Date of Patent:
March 29, 2016
Assignee:
Construction Research & Technology GmbH
Inventors:
Alessandro Dal Bo, Gianmaria Marinello, Maurizio Pietrobon, Alan Tommasi
Abstract: The present invention relates to a process for the continuous preparation of polymers in a polymerization apparatus, where the starting materials comprise at least one olefinically unsaturated polyether macromonomer and at least one olefinically unsaturated acid monomer and at least one free-radical initiator and the polymerization is carried out at temperatures in the range from ?20 to +120° C., wherein the polymerization apparatus comprises at least one loop reactor which has at least one feed line for the starting materials and at least one outlet, where the loop reactor comprises at least one reaction zone which comprises internal cooling and mixing elements and which has a volume-based heat removal power of at least 10 kW/m3·K. Furthermore, the use of the polymer of the invention as dispersant for hydraulic binders is disclosed.
Type:
Grant
Filed:
December 9, 2013
Date of Patent:
March 15, 2016
Assignee:
Construction Research & Technology GmbH
Inventors:
Christian Schwede, Günter Kaiser, Andreas Brodhagen, Mario Vierle
Abstract: We herewith propose the use of at least one nitrogen-containing organic compound and/or a salt thereof in combination with at least one aromatic carboxylic acid and/or a salt thereof for improving the freeze-thaw stability of an alkali-activated aluminosilicate binder, and a preferred alkali-activated aluminosilicate binder comprising ?-caprolactam and sodium benzoate as freeze-thaw stabilizers.
Type:
Grant
Filed:
September 26, 2013
Date of Patent:
January 26, 2016
Assignee:
Construction Research & Technology GmbH
Inventors:
Samuele Beraldo, Nicola Montagner, Alessandro Dal Bo
Abstract: A cementitious composition containing hydraulic cement, water, and a hyper-branched polyether surfactant. An aqueous admixture composition for cementitious compositions including a hyper-branched polyether surfactant, optionally a dispersant, optionally an additional surfactant or defoamer, and optionally a stabilizing agent. A method of making a cementitious composition including mixing cementitious material, water, a hyper-branched polyether surfactant, optionally a dispersant for cementitious compositions, optionally an additional surfactant or defoamer, and optionally a stabilizing agent.
Type:
Grant
Filed:
February 20, 2012
Date of Patent:
December 15, 2015
Assignee:
Construction Research & Technology, GmbH
Inventors:
Jeffrey R. Bury, Thomas M. Vickers, Jr.
Abstract: Disclosed is an exterior finish system for building structures that includes a water pervious adhesive for securing an insulation layer to a water resistive barrier applied to a building wall substrate. Also disclosed is a building structure such as a building column or wall that includes the finish system and a method of using the finish system to assemble a building structure such as a column or wall.
Type:
Grant
Filed:
April 24, 2015
Date of Patent:
November 24, 2015
Assignee:
Construction Research & Technology GmbH
Inventors:
William F. Egan, Eric S. Auman, Steffen Wache, Kevin Brands, Lea Cruz, Sandra R. Sprouts
Abstract: The invention relates to a method for grinding an inorganic solid from the series cement clinker, pozzolan and/or raw material for cement production, where a grinding additive is added before or during grinding, and the grinding additive, based on the dry mass, comprises 6% to 80% by weight of caprolactam and 1.5% to 30% by weight of aminocaproic acid, where, based in each case on the dry mass, 0.002% to 2% by weight of the grinding additive is used, based on the total solid. Further claimed are a grinding additive and the use thereof for increasing the compressive strength of the cured product produced therewith.
Type:
Grant
Filed:
April 22, 2013
Date of Patent:
November 10, 2015
Assignee:
Construction Research & Technology GmbH
Inventors:
Madalina Andreea Stefan, Torsten Freund, Lorenzo Ambrosini, Attilio Camplone, Stijn Brughmans, Jürgen Faderl
Abstract: The invention relates to a method for producing a hydraulic binder, comprising contacting a composition comprising cement clinker, before, during or after the grinding procedure, with (a) a defoaming agent and (b) 0.0005% to 2% by weight, based on the total composition, of at least one air-introducing compound, the defoaming agent (a) comprising 0.0001% to 0.5% by weight, based on the total composition, of at least one defoaming agent of the formula R10—(CmH2m—O—)x—(CdH2d—O—)c—H and the ratio of (a) to (b) being between 1:1 to 1:200.
Type:
Grant
Filed:
April 22, 2013
Date of Patent:
October 20, 2015
Assignee:
Construction Research & Technology, GmbH
Inventors:
Mario Vierle, Martin Ernst, Madalina Andreea Stefan
Abstract: The invention relates to a process for the preparation of a phosphated polycondensate, at least one sulphonic acid being used as catalyst, and to the use of the phosphated polycondensate obtained as an admixture for aqueous suspensions of hydraulic and/or latently hydraulic binders.
Type:
Grant
Filed:
September 7, 2009
Date of Patent:
October 13, 2015
Assignee:
Construction Research & Technology GmbH
Inventors:
Alexander Kraus, Frank Dierschke, Fabian Becker, Thomas Schuhbeck, Harald Grassl, Karin Groess
Abstract: A method of expanding expandable polymeric microspheres including contacting an aqueous slurry including unexpanded, expandable polymeric microspheres with steam in-situ during manufacture of a cementitious composition or article, wherein the aqueous slurry optionally further includes an admixture therefor. A method of manufacturing a cementitious composition or article includes: (i) contacting an aqueous slurry of unexpanded, expandable polymeric microspheres with steam proximate to and/or during said manufacturing of the cementitious composition to create expanded polymeric microspheres; (ii) pre-wetting the expanded polymeric microspheres; and (iii) mixing the pre-wetted, expanded polymeric microspheres with cement and water to form the cementitious composition, wherein the aqueous slurry optionally further comprises an admixture therefor.
Type:
Grant
Filed:
March 15, 2013
Date of Patent:
October 6, 2015
Assignee:
Construction Research & Technology, GmbH
Inventors:
Frank Shaode Ong, Stefan Müssig, Darren Gambatesa, James C. Smith, Raymond Fete, Rick Paponetti, Mark A. Bury
Abstract: A cementitious composition including at least one cementitious and/or pozzolanic material and at least one desugared molasses. A method of preparing a cementitious composition including forming a mixture of water, at least one cementitious and/or pozzolanic material and at least one desugared molasses. An admixture for cementitious compositions including: (i) at least one desugared molasses; and (ii) at least one alkanolamine and/or at least one polyhydroxyalkylamine.