Patents Assigned to Corning S.A.
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Patent number: 6013682Abstract: Described is a method of making a silicone in water emulsion. The method comprises mixing (I) a composition containing at least one polysiloxane, at least one organosilicon material that reacts with said polysiloxane by a chain extension reaction and a metal containing catalyst for said chain extension reaction, (II) at least one surfactant and (III) water to form a mixture. The mixture is emulsified to form an emulsion which can have a wide variety of silicone volume fractions, a broad range of mono-disperse particle sizes and a wide variety of molecular weight polymers.Type: GrantFiled: April 20, 1998Date of Patent: January 11, 2000Assignee: Dow Corning S. A.Inventors: Frederic Dalle, Leon Marteaux
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Patent number: 6005026Abstract: An epoxy and polyurethane-based sizing composition for fibers used in the reinforcement of engineered thermoplastic molded composites, which exhibits improved hydrolytic stability and reduced discoloration.Type: GrantFiled: March 15, 1999Date of Patent: December 21, 1999Assignee: N.V.Owens-Corning S.A.Inventors: Willy H. Piret, Nadia Masson
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Patent number: 5968660Abstract: This invention relates to a coated substrate obtained by a method comprising (I) applying a silicone emulsion composition to the surface of a substrate wherein the silicone emulsion composition comprises (a) an alkenylated silicone resin, (b) an alkenyl polydiorganosiloxane, (c) a silicone resin having SiH groups, (d) water, (e) a polyorganohydrogensiloxane, (f) an unsaturated organic monomer, (g) a hydrosilylation catalyst, and (h) an emulsifying agent. Separation of a laminate formed from a substrate coated with said emulsion release coating composition and a adhesive coated article requires a relatively high delamination force.Type: GrantFiled: January 23, 1998Date of Patent: October 19, 1999Assignee: Dow Corning S.A.Inventors: Stephen Armstrong, Andre Detrembleur
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Patent number: 5948854Abstract: Alkoxy-functional room temperature vulcanizing (RTV) compositions, curable in the presence of moisture, comprising polymers containing on average at least 1.2 alkoxysilyl chain terminations per molecule, a tetraalkoxytitanium compound containing on average greater than 90 mole percent of the alkoxy groups as tertiary amyloxy groups, a filler, and an alkoxysilane. The addition of these components in amounts to satisfy defined molar ratios provide alkoxy-functional RTV compositions having both improved storage stability and improved green strength upon curing.Type: GrantFiled: September 25, 1997Date of Patent: September 7, 1999Assignees: Dow Corning S.A., Dow Corning CorporationInventors: Francois de Buyl, Robert H. Krahnke, Timothy B. Lueder, Richard A. Palmer
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Patent number: 5928724Abstract: An improved method of making glass building elements filled with cured polydiorganosiloxane compositions. The method comprises first coating the interior surfaces of a hollow glass block with a first curable polydiorganosiloxane composition. This first composition is then cured. Next, the block is charged with a quantity of a second curable polydiorganosiloxane composition. This second composition is then cured to form the building element. The resultant element has improved aesthetics because of the decreased quantity of entrapped bubbles.Type: GrantFiled: March 25, 1998Date of Patent: July 27, 1999Assignee: Dow Corning S.A.Inventors: Pierre Descamps, Martin Harvey
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Patent number: 5908909Abstract: A composition curable in presence of atmospheric moisture to an elastomeric body, comprising (A) the product formed by mixing a polymeric material having at least two groups bonded to silicon which are hydroxyl or alkoxy group and an alkoxysilane curative and (B) a titanium compound according to the general formula Ti(OR).sub.x (OR').sub.y (OR*).sub.z where x is 0 to 0.4 inclusive, y is 0 to 3.9, z is 0.1 to 4, x+y+z=4, R* is 2,4-dimethyl-3-pentyl, R' represents a monovalent tertiary aliphatic hydrocarbon group, and JR represents a monovalent linear aliphatic hydrocarbon group having 1 to 6 carbon atoms. The compositions cure quickly and do not yellow.Type: GrantFiled: September 26, 1997Date of Patent: June 1, 1999Assignee: Dow Corning S. A.Inventors: Francois De Buyl, Patrick Leempoel
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Patent number: 5861453Abstract: The present invention relates to a silicone composition prepared by reacting a mixture comprising (i) mineral oil, (ii) a polyorganosiloxane, (iii) a silicon compound, and (iv) a catalytic amount of a catalyst. The compositions of this invention are resistant to phase separation and are useful as foam control compositions in foam producing systems.Type: GrantFiled: January 28, 1997Date of Patent: January 19, 1999Assignees: Dow Corning Corporation, Dow Corning S.A.Inventors: Teresa Lynn Datz-Siegel, Kenneth Christopher Fey, Jacqueline L'Hostis, Franck A Renauld
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Patent number: 5861368Abstract: A method of providing a foam control agent with 1 to 30 parts of a silicone antifoam and 70 to 99 parts of a zeolite carrier, with the ability to release some of the antifoam within 10 minutes of being dispersed in an aqueous surfactant solution, by deposition 5 to 70% of the antifoam of an organo-polysiloxane polyoxyalkylene copolymer, onto the zeolite carrier not later than depositing the silicone antifoam. Also claimed is the use of the copolymer to achieve that end and compositions where the antifoam is branched or high viscosity. Also claimed is encapsulated agents.Type: GrantFiled: January 18, 1997Date of Patent: January 19, 1999Assignee: Dow Corning S. A.Inventors: Leonidas Kolaitis, Bertrand Louis Julien Lenoble
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Patent number: 5844038Abstract: The present invention discloses the use of a polymer chain having at least one carboxylic acid anhydride group as a consistency stabilizer in the base part of a two-part silicone sealant. The base part consists essentially of the consistency stabilizer, 100 parts by weight of a polymeric material having not less than two groups bonded to silicon which are hydroxyl or hydrolysable groups, 5 to 150 parts by weight of filler and, optionally, pigments and/or plasticizers.Type: GrantFiled: January 27, 1997Date of Patent: December 1, 1998Assignee: Dow Corning S. A.Inventors: Dominique Culot, Patrick Deglasse, Sesto Di Marco, Jean Iker
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Patent number: 5833798Abstract: A moisture curable composition comprises a mixture and/or a reaction product of a polymeric material having not less than two groups bonded to silicon which are hydroxyl or hydrolyzable groups, an alkoxysilane curative, an adhesion promoter and catalyst material for catalyzing the condensation reaction between the polymeric material and the alkoxysilane curative. The adhesion promoter comprises a silicone-organic copolymer consisting of units (I) according to the general formula R.sub.a SiO.sub.(4-a)/2 and units (ii) according to the general formula R.sub.b R'SiO.sub.(3-b)/2 where R represents a monovalent hydrocarbon group and R' represents an oxyalkylene chain R.sup.6 (C.sub.2 H.sub.4 O).sub.x (C.sub.3 H.sub.6 O).sub.y Z in which R.sup.6 represents a hydrocarbon linkage to a silicon atom, Z represents H or a carboxylic acid residue.Type: GrantFiled: April 2, 1997Date of Patent: November 10, 1998Assignee: Dow Corning S. A.Inventor: Patrick Leempoel
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Patent number: 5819614Abstract: A method for dispensing reinforcement fibers to make a preform or laminate includes winding a continuous length of a reinforcement fiber into coils around a form having a longitudinal axis, moving the coils axially with respect to the form to engage a cutter, cutting the coils to form discrete length reinforcement fibers, and dispensing the discrete length reinforcement fibers.Type: GrantFiled: December 19, 1996Date of Patent: October 13, 1998Assignee: N.V. Owens-Corning S.A.Inventor: Michael H. Jander
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Patent number: 5822675Abstract: Disclosed is a heating element having improved performance, particularly at high power densities and high temperatures. The heating element comprises a substrate having a first layer comprising a silicon based electrically insulating material on its surface. On a surface of the first layer is a second layer comprising a silicon based electrically resistive material. Attached to the second layer are at least two separate areas of silicon based electrically conductive material. Each of these separate areas are suitable for connection to a power supply.Type: GrantFiled: February 12, 1997Date of Patent: October 13, 1998Assignee: Dow Corning S.A.Inventors: Rene Paquet, Eric Vanlathem
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Patent number: 5807009Abstract: A mechanical coupling comprises an input member, an output member a chamber associated therewith, within the chamber a charge of cured silicone composition in crumb form and a spring biased piston for compressing the charge to an extent sufficient to permit the compressed silicone to convey rotational motion from the input member to the output member.Type: GrantFiled: December 12, 1994Date of Patent: September 15, 1998Assignee: Dow Corning S. A.Inventors: Robert John Michael, Rene Louis Mathieu Andre Paquet
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Patent number: 5806387Abstract: A method for dispensing reinforcement fibers to make a preform or laminate includes winding a continuous length of a reinforcement fiber into coils around a form having a longitudinal axis, moving the coils axially with respect to the form to engage a cutter, cutting the coils to form discrete length reinforcement fibers, applying a resinous material to the discrete fibers, and dispensing the discrete length reinforcement fibers.Type: GrantFiled: June 7, 1996Date of Patent: September 15, 1998Assignee: N.V. Owens-Corning S.A.Inventor: Michael H. Jander
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Patent number: 5767053Abstract: A method of making a particulate foam control agent comprising 0.001 to 30 parts of silicone antifoam, 45 to 99 parts of a zeolite and 0 to 30 parts of a binder, preferably of a polycarboxylate-type, able to release at least some antifoam from the zeolite in the first 10 minutes of a washing cycle comprises depositing from 0.1 to 500% of the silicone antifoam of an organic surfactant onto the zeolite not later than depositing the silicone antifoam, at least 1 part of surfactant being used per 100 parts of the foam control agent. Also covered are detergent compositions and some foam control agents.Type: GrantFiled: December 20, 1995Date of Patent: June 16, 1998Assignee: Dow Corning S. A.Inventors: Pierre Andre Georges Gustave Germain, Bernhard Ernst Gold, Jan Sybren Hoogland, Bertrand Louis Julien Lenoble, Mark Prince
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Patent number: 5767760Abstract: Prior to winding wire in a coil around a foil, the foil is coated on a least one surface side with a tacky silicone composition. A composition on the foil exerts a retaining force on the wires discouraging said wires from sliding away from an original or intended position.Type: GrantFiled: December 19, 1996Date of Patent: June 16, 1998Assignee: Dow Corning S. A.Inventors: Jean-Paul Mollie, Michael Ortner
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Patent number: 5741439Abstract: An emulsion composition is described which comprises (a) an alkenylated silicone resin, (b) an alkenyl polydiorganosiloxane, (c) a silicone resin bearing SiH groups and (d) water. The emulsion composition may be combined with a precious metal catalyst to provide an emulsion release coating composition. The emulsion release coating composition may be applied to a substrate, for example paper, and cured thereon to provide an adhesive coating. Separation of a laminate formed from a substrate coated with said emulsion release coating composition and a adhesive coated article requires a relatively high delamination force.Type: GrantFiled: November 22, 1996Date of Patent: April 21, 1998Assignee: Dow Corning S. A.Inventors: Stephen Armstrong, Andre Detrembleur
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Patent number: 5733996Abstract: The specification describes and claims a composition curable in presence of atmospheric moisture to an elastomeric body, comprising (A) the product formed by mixing a polymeric material having at least two groups bonded to silicon which are hydroxyl or hydrolysable (eg alkoxy) groups and an alkoxysilane curative and (B) a compound according to the general formula M?OR!.sub.x ?OR'!.sub.y where M represents a metal having a valency of 4 selected from Group IVB of the Periodic Table and is preferably titanium, x has a value from 0 to 1, y has a value from 3 to 4 and (x+y)=4, R' represents a monovalent tertiary aliphatic hydrocarbon group and R represents a monovalent linear aliphatic hydrocarbon group having 1 to 6 carbon atoms which is different from R'. Preferred compounds (B) are those in which R' represents C(R.sup.2 R.sup.3 R.sup.4) in which each of R.sup.2, R.sup.3 and R.sup.Type: GrantFiled: June 4, 1996Date of Patent: March 31, 1998Assignee: Dow Corning S.A.Inventors: Francois De Buyl, Patrick Leempoel
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Patent number: 5712036Abstract: A high solubility size composition is provided which may be applied to glass fibers useful for reinforcing polymeric materials. The size composition includes: a first film former comprising a polyester-based thermoplastic polyurethane derived from a saturated, non-crosslinkable polyester; a second film former comprising at least one ingredient selected from i) a vinyl acetate glycidyl methacrylate copolymer and ii) a mixture of a vinyl acetate glycidyl methacrylate copolymer and a vinyl acetate homopolymer; a silane coupling agent; and water. Using glass fibers coated with the high solubility size composition allows the advantageous production of low-pigmented or non-pigmented molded parts having enhanced surface appearance and color uniformity.Type: GrantFiled: May 8, 1996Date of Patent: January 27, 1998Assignee: N.V. Owens-Corning S.A.Inventor: Willy H. Piret
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Patent number: 5693256Abstract: A foam control agent comprising 100 parts by weight of a water-insoluble organic liquid, from 0.1 to 20 parts by weight of a first hydrophobic filler with a size of no more than 20 .mu.m, preferably silica, and from 0.1 to 20 parts by weight of a second hydrophobic filler having a size of at least 30 .mu.m, preferably an organopolysiloxane resin, said fillers being insoluble in the organic liquid. The foam control agent is particularly useful as an antifoam in detergent compositions, paper pulp manufacture, textile dyeing or cutting oils.Type: GrantFiled: June 1, 1995Date of Patent: December 2, 1997Assignee: Dow Corning S.A.Inventors: George Christopher Sawicki, Frank Andre Daniel Renauld, Jacqueline L'Hostis