Abstract: Nanoparticles that can be used as hydrosilylation and dehydrogenative silylation catalysts. The nanoparticles have at least one transition metal with an oxidation state of 0, chosen from the metals of columns 8, 9 and 10 of the periodic table, and at least one carbonyl ligand, preferably a silicide.
Type:
Application
Filed:
January 11, 2019
Publication date:
November 12, 2020
Applicants:
Elkem Silicones France SAS, Universite Claude Bernard Lyon I, CPE Lyon Formation Continue et Recherche - CPE Lyon FCR, Centre National de la Recherche Scientifique - CNRS
Abstract: The invention relates to a method for metathesis of one or several reagents comprising a linear or branched hydrocarbon chain containing a double olefinic bond Csp2?Csp2 consisting in reacting said reagent or reagents with a supported metal compound comprising an aluminum oxide-based support to which a tungsten hydride is grafted. Typically, each said reagent or reagents comprises from 2 to 30 carbon atoms. The reagent can be embodied in the form of olefin. The inventive method can be used, for example for producing propylene from ethylene and butane.
Type:
Grant
Filed:
July 1, 2005
Date of Patent:
December 22, 2009
Assignee:
CPE Lyon Formation Continue ET Recherche-CPE Lyon FCR
Inventors:
Jean-Marie Basset, Jean Thivolle-Cazat, Mostafa Taoufik, Erwan Le Roux, Christophe Coperet